2',5'-dimethyl-4,4''-bis(benzimidazol-2-yl)-p-terphenyl | 1234837-39-8

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物
• 英文名称: 2',5'-dimethyl-4,4''-bis(benzimidazol-2-yl)-p-terphenyl
• CAS: 1234837-39-8
• 化学式: C₃₄H₂₆N₄
• 分子量: 490.607
• InChiKey: RDROURTWZBUWIV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.72
• 重原子数：
  38.0
• 可旋转键数：
  4.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  57.36
• 氢给体数：
  2.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  4-氰基苯硼酸 在 四(三苯基膦)钯 、 磷酸 、 sodium carbonate 作用下， 以 四氢呋喃 为溶剂， 反应 30.0h， 生成 2',5'-dimethyl-4,4''-bis(benzimidazol-2-yl)-p-terphenyl
  参考文献：
  名称：

  Synthesis and photophysical properties of a series of thermally stable terphenyl-bridged bisbenzimidazoles

  摘要：

  Nine novel terphenyl-bridged bisbenzimidazoles were synthesized in high yield by the condensation of o-phenylenediamines and teiphenyl dinitriles in the presence of polyphosphoric acid The bisbenzimidazoles are thermally robust with high decomposition temperatures (>346 C) and high melting transitions and emit blue light at 410 nm with fluorescence quantum yield >0 4 in solution Electrochemical studies indicate that the novel bisbenzimidazoles have a formal reduction potential in the range of -144 to -155 V and estimated electron affinities (lowest unoccupied molecular orbital levels) of 3 09-3 24 eV The results indicate their potential use as blue emitting materials in organic light-emitting diodes (C) 2010 Elsevier Ltd All rights reserved

  DOI：

  10.1016/j.dyepig.2010.07.006