trimethyl-5-methyl-2-(1-methylethylphenoxysilane) | 55012-80-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: trimethyl-5-methyl-2-(1-methylethylphenoxysilane)
• 英文别名: (5-methyl-2-i-propylphenoxy)trimethylsilane；2-isopropyl-5-methylphenoxytrimethylsilane；trimethylsilyl ether of thymol；thymol-TMS；trimethyl-(5-methyl-2-propan-2-ylphenoxy)silane
• CAS: 55012-80-1
• 化学式: C₁₃H₂₂OSi
• 分子量: 222.403
• InChiKey: UTGMDFONUNJYQP-UHFFFAOYSA-N

物化性质

• 沸点：
  255.2±19.0 °C(Predicted)
• 密度：
  0.894±0.06 g/cm3(Predicted)
• 保留指数：
  1312;1310;1310;1301;1312

计算性质

• 辛醇/水分配系数(LogP)：
  4.33
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  2,4-diferrocenyl-1,3-dithiadiphosphetane-2,4-disulfide 、 trimethyl-5-methyl-2-(1-methylethylphenoxysilane) 以 苯 为溶剂， 反应 2.0h， 以44%的产率得到O-(2-isopropyl-5-methylphenyl) S-trimethylsilyl (ferrocenyl)dithiophosphonate
  参考文献：
  名称：

  Dithiophosphorylation of trimethylsilyl ethers of carvacrol and thymol

  摘要：

  Carvacrol trimethylsilyl ether when reacting with P4S10 forms S-trimethylsilyl ester of O,O-bis(5-isopropyl-2-methylphenyl)dithiophosphoric acid. The reactions of 2,4-diorganyl-1,3,2,4-dithiadiphosphetane-2,4-disulfides with carvacrol (thymol) trimethylsilyl ether yield the S-trimethylsilyl esters of the corresponding dithiophosphoric acids.

  DOI：

  10.1134/s1070363216030117
• 作为产物：
  描述：

  百里酚 生成 trimethyl-5-methyl-2-(1-methylethylphenoxysilane)
  参考文献：
  名称：

  LAUTERBUCH, MANFRED;JUGER, GUNTER;JANCKE, HARALD;LEHMANN, ANDREAS;ZIMMERM+, CHEM. TECHN. , 42,(1990) N, C. 264-268

  摘要：

  DOI：

文献信息

• Highly atom economical uncatalysed and I2-catalysed silylation of phenols, alcohols and carbohydrates, using HMDS under solvent-free reaction conditions (SFRC)
  作者：Marjan Jereb

  DOI：10.1016/j.tet.2012.03.040

  日期：2012.5

  An uncatalysed silylation of phenols, regardless on the aggregate state and nature of the substituents with 0.55 equiv of HMDS under solvent-free reaction conditions (SFRC) at room temperature is reported. Sterically hindered phenols, carbohydrates and most of the alcohols additionally required a catalytic amount (up to 2 mol%) of iodine. The reaction protocol is very simple; obtaining a pure product, particularly of uncatalysed reactions, was frequently a completely solvent-free process. (C) 2012 Elsevier Ltd. All rights reserved.
• Mishra; Singh, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2001, vol. 40, # 7, p. 772 - 774
  作者：Mishra、Singh

  DOI：——

  日期：——
• Dithiophosphorylation of trimethylsilyl ethers of carvacrol and thymol
  作者：I. S. Nizamov、D. A. Terenzhev、I. D. Nizamov、G. G. Shumatbaev、E. S. Batyeva、R. A. Cherkasov

  DOI：10.1134/s1070363216030117

  日期：2016.3

  Carvacrol trimethylsilyl ether when reacting with P4S10 forms S-trimethylsilyl ester of O,O-bis(5-isopropyl-2-methylphenyl)dithiophosphoric acid. The reactions of 2,4-diorganyl-1,3,2,4-dithiadiphosphetane-2,4-disulfides with carvacrol (thymol) trimethylsilyl ether yield the S-trimethylsilyl esters of the corresponding dithiophosphoric acids.
• LAUTERBUCH, MANFRED;JUGER, GUNTER;JANCKE, HARALD;LEHMANN, ANDREAS;ZIMMERM+, CHEM. TECHN. , 42,(1990) N, C. 264-268
  作者：LAUTERBUCH, MANFRED、JUGER, GUNTER、JANCKE, HARALD、LEHMANN, ANDREAS、ZIMMERM+

  DOI：——

  日期：——

表征谱图