2-chloro-1,2,3,4,4a,5,8,8a-octahydro-1,4;5,8-dimethano-naphthalene | 3439-92-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2-chloro-1,2,3,4,4a,5,8,8a-octahydro-1,4;5,8-dimethano-naphthalene
• 英文别名: 2-Chlor-1,2,3,4,4a,5,8,8a-octahydro-1,4;5,8-dimethano-naphthalin；2-Chlor-1,2,3,4,4a,5,8,8a-octahydro-1,4:5,8-dimethano-naphthalin；2-Chloro-1,2,3,4,4a,5,8,8a-octahydro-1,4:5,8-dimethanonaphthalene；9-chlorotetracyclo[6.2.1.13,6.02,7]dodec-4-ene
• CAS: 3439-92-7
• 化学式: C₁₂H₁₅Cl
• 分子量: 194.704
• InChiKey: JAUWSFRBDNDALH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  氯乙烯 、 环戊二烯 生成 2-chloro-1,2,3,4,4a,5,8,8a-octahydro-1,4;5,8-dimethano-naphthalene 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Alder; Rickert, Justus Liebigs Annalen der Chemie, 1940, vol. 543, p. 1,21

  摘要：

  DOI：

文献信息

• Ethylene (co) polymer and its use
  申请人：Takahashi Mamoru

  公开号：US20060047096A1

  公开（公告）日：2006-03-02

  An ethylene (co)polymer of the present invention is a (co)polymer with excellent moldability and mechanical properties and either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 4 to 20 carbon atoms. The (co)polymer has methyl branches measured by 13 C-NMR less than 0.1 in number per 1,000 carbon atoms and Mw/Mn measured by GPC not lower than 1.8 and lower than 4.5. The (co)polymer is either an ethylene homopolymer or a copolymer of ethylene and an α-olefin of 3 to 20 carbon atoms. The melt tension (MT) and the swell ratio (SR) satisfy the relation; log(MT)>12.9−7.15×SR; and the intrinsic viscosity ([η]) and the melt flow rate (MFR) satisfy the relation; [η]>1.85×MFR −0.192 in the case of MFR<1 and the relation; [η]>1.85×MFR −0.213 in the case of MFR≧1. Such an ethylene (co)polymer can be usable for various molding applications and especially suitable for pipes.

  本发明的乙烯(co)聚合物是一种具有优异的成型性和机械性能的(co)聚合物，可以是乙烯均聚物或乙烯和4至20个碳原子的α-烯烃的共聚物。该(co)聚合物在13C-NMR下测量，每1,000个碳原子的甲基支链少于0.1个，并且在GPC下测量的Mw/Mn不低于1.8且低于4.5。该(co)聚合物可以是乙烯均聚物或乙烯和3至20个碳原子的α-烯烃的共聚物。熔融张力(MT)和膨胀比(SR)满足关系式; log(MT)>12.9−7.15×SR; 内禀粘度([η])和熔体流动速率(MFR)满足关系式; 当MFR<1时，[η]>1.85×MFR−0.192，当MFR≧1时，[η]>1.85×MFR−0.213。这种乙烯(co)聚合物可用于各种成型应用，特别适用于管道。
• Optical resin lens and production method for optical resin material
  申请人：Nakamura Kazuaki

  公开号：US20090189127A1

  公开（公告）日：2009-07-30

  An optical resin lens characterized in comprising a polymer prepared employing a production method including a process which polymerizes olefin employing titanium halide and a catalyst comprised of the organic aluminum represented by Formula R n AlX 3-n (wherein 1

  一种光学树脂镜片，其特点在于包括一种聚合物，其制备方法包括使用钛卤化物聚合烯烃的过程以及使用有机铝催化剂的过程，该有机铝催化剂由式RnAlX3-n表示（其中1
• Random copolymer
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0156464A1

  公开（公告）日：1985-10-02

  A random copolymer composed of ethylene, a 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene and optionally an alpha-olefin having at least three carbon atoms or cycloolefin. The mole ratio of polymerized units from the 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene to polymerized units from ethylene is from 3:97 to 95:5 and the 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene is incorporated in the polymer chain as polymerized units without ring-opening. The copolymer is prepared by copolymerizing ethylene, optionally the alpha-olefin of at least 3 carbon atoms or cycloolefin, with the 1,4,5,8-dimethano-1,2,3,4,4a,5,8,8a-octahydronaphthalene in a hydrocarbon medium in the presence of a catalyst formed from a vanadium compound and an organoaluminum compound which are soluble in the hydrocarbon medium. The copolymer has excellent transparency and a well balanced-combination of heat resistance, heat aging resistance, chemical and solvent resistance, dielectric properties and mechanical properties such as rigidity.

  一种无规共聚物，由乙烯、1,4,5,8-二甲烷基-1,2,3,4,4a,5,8,8a-八氢萘和一种具有至少三个碳原子的α-烯烃或环烯烃组成。1,4,5,8-二甲桥-1,2,3,4,4a,5,8,8a-八氢萘的聚合单元与乙烯的聚合单元的摩尔比为 3:97 至 95:5，1,4,5,8-二甲桥-1,2,3,4,4a,5,8,8a-八氢萘作为聚合单元加入聚合物链中，不需要开环。 共聚物的制备方法是：在烃介质中，在由钒化合物和有机铝化合物（可溶于烃介质）组成的催化剂的存在下，将乙烯、至少 3 个碳原子的α-烯烃或环烯烃、1,4,5,8-二甲烷基-1,2,3,4,4a,5,8,8a-八氢萘共聚。 这种共聚物具有极佳的透明度，并在耐热性、耐热老化性、耐化学性和耐溶剂性、介电性能和机械性能（如刚性）方面具有良好的平衡组合。
• Random copolymer and process for production thereof
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0203799A1

  公开（公告）日：1986-12-03

  A random copolymer is characterized in that (A) the copolymer comprises polymerized ethylene units and polymerized units of at least one cycloolefin, - (B) the mole ratio of the polymerized cycloolefin units to the polymerized ethylene units is from 3:97 to 60:40, (C) the cycloolefin is incorporated in the polymer chain without ring opening, (D) the copolymer has an intrinsic viscosity of 0.01 to 20 dl/g, (E) the copolymer has a molecular weight distribution ( Mw/ Mn) of not more than 4, and (F) the copolymer has a crystallinity of 0 to 10%. A monomer selected from (a) alpha, beta-unsaturated carboxylic acids and/or their derivatives, (b) styrenes, (c) organic silicon compounds having an olefinically unsaturated bond and a hydrolyzable group, or (d) unsaturated epoxy monomers may be grafted on to the random copolymer. The random copolymer is produced by continuously copolymerizing ethylene with at least one cycloolefin in a hydrocarbon medium in the presence of a catalyst formed from a soluble vanadium compound and an organoaluminum compound while maintaining the atom ratio of aluminum atoms to vanadium atoms in the reaction system, AI:V at 2 or more:1.

  一种无规共聚物，其特征在于：(A)共聚物包括聚合乙烯单元和至少一种环烯烃的聚合单元，-(B)聚合环烯烃单元与聚合乙烯单元的摩尔比为3:97至60:40，(C)环烯烃并入聚合物链中而不开环，(D)共聚物的固有粘度为0.01至20 dl/g，(E)共聚物的分子量分布( Mw/ Mn)不超过4，(F)共聚物的结晶度为0至10%。无规共聚物上可接枝选自以下物质的单体：(a) α、β-不饱和羧酸和/或其衍生物；(b) 苯乙烯；(c) 具有烯烃不饱和键和可水解基团的有机硅化合物；或 (d) 不饱和环氧单体。无规共聚物是在烃介质中，在由可溶性钒化合物和有机铝化合物组成的催化剂存在下，通过乙烯与至少一种环烯烃连续共聚而制得的，同时保持反应体系中铝原子与钒原子的原子比 AI:V 为 2 或更多:1。
• Metathesis polymerized cross-linked halogen-containing copolymer
  申请人：HERCULES INCORPORATED

  公开号：EP0283719A2

  公开（公告）日：1988-09-28

  A cross-linked copolymer containing repeating units derived from dicyclopentadiene and metathesis polymerizable halogen-containing cycloalkenes, a process for producing the copolymer, a process for producing a molded article from the copolymer and a polymerizable composition therefor.

  一种交联共聚物，其含有由双环戊二烯和可偏聚的含卤环烯衍生的重复单元；一种生产该共聚物的工艺；一种用该共聚物和可聚合组合物生产模塑制品的工艺。