(Z)-0-undecenoic acid methyl ester | 54299-07-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (Z)-0-undecenoic acid methyl ester
• 英文别名: Methyl-cis-9-undecenoat；Methyl cis-9-undecenoate；methyl (Z)-undec-9-enoate
• CAS: 54299-07-9
• 化学式: C₁₂H₂₂O₂
• 分子量: 198.305
• InChiKey: RHRCWCJKYPOGNT-ARJAWSKDSA-N

物化性质

• 沸点：
  252.8±19.0 °C(Predicted)
• 密度：
  0.886±0.06 g/cm3(Predicted)
• 物理描述：
  colourless to pale straw-yellow, oily liquid
• 溶解度：
  insoluble in water; soluble in alcohol
• 折光率：
  1.435-1.441

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (Z)-0-undecenoic acid methyl ester 在 lithium aluminium tetrahydride 、 臭氧 、 sodium amide 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 6.0h， 生成 (9Z)-9-十六碳烯-1-醇
  参考文献：
  名称：

  Narasimhan, S.; Mohan, H., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1995, vol. 34, # 11, p. 950 - 953

  摘要：

  DOI：
• 作为产物：
  描述：

  10,11-dibromo-undecanoic acid 在 Pd-BaSO₄ 喹啉 、 氢氧化钾 、 氢气 、 对甲苯磺酸 、 PEG 400 作用下， 以 正己烷 为溶剂， 反应 12.5h， 生成 (Z)-0-undecenoic acid methyl ester
  参考文献：
  名称：

  Narasimhan, S.; Mohan, H., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1995, vol. 34, # 11, p. 950 - 953

  摘要：

  DOI：

文献信息

• ANTIMICROBIAL COMPOSITIONS, METHODS AND SYSTEMS
  申请人：Elevance Renewable Sciences, Inc.

  公开号：EP2007199A2

  公开（公告）日：2008-12-31
• SYNTHESIS OF TERMINAL ALKENES FROM INTERNAL ALKENES VIA OLEFIN METATHESIS
  申请人：Elevance Renewable Sciences, Inc.

  公开号：EP2076484A2

  公开（公告）日：2009-07-08
• Surface coating compositions and methods
  申请人：Zullo Louise Jill

  公开号：US20070227400A1

  公开（公告）日：2007-10-04

  The invention provides surface coating compositions comprising a preservative comprising 9-decenoic acid, salts of 9-decenoic acid, esters of 9-decenoic acid, or combinations thereof. The surface coating compositions may be water-based coatings (e.g., a latex paint) or solvent-based coatings (e.g., a solvent-based paint). The surface coating compositions may be paints, stains, varnishes, concrete coatings, anti-graffiti coatings, and the like. Methods for protecting a surface coating composition from in-can spoilage and protecting a coating of the surface coating composition from deterioration by the action of microorganisms are also described.
• Antimicrobial compositions, methods and systems
  申请人：Zullo Louise Jill

  公开号：US20080033026A1

  公开（公告）日：2008-02-07

  The invention provides methods for treating a surface, the method including steps of applying a surface treatment composition to a surface, wherein the surface treatment composition includes a substantially phenol-free cleansing agent and an antimicrobial agent, the antimicrobial agent comprising 9-decenoic acid, a salt of 9-decenoic acid, an ester of 9-decenoic acid, or a combination thereof, wherein the antimicrobial agent is present in an amount sufficient to control microbial growth. Also described are methods for treating a surface that include the step of applying a surface treatment composition having a pH in the range of 4.1 to 8.5 to a surface, wherein the surface treatment composition includes a cleansing agent and an antimicrobial agent, the antimicrobial agent comprising 9-decenoic acid, a salt of 9-decenoic acid, an ester of 9-decenoic acid, or a combination thereof, wherein the antimicrobial agent is present in an amount sufficient to control microbial growth. Also described are surface treatment compositions including the antimicrobial agents.
• Synthesis of Terminal Alkenes From Internal Alkenes Via Olefin Metathesis
  申请人：Schrodi Yann

  公开号：US20100145086A1

  公开（公告）日：2010-06-10

  This disclosure relates generally to olefin metathesis, and more particularly relates to the synthesis of terminal alkenes from internal alkenes using a cross-metathesis reaction catalyzed by an olefin metathesis catalyst. According to one aspect, for example, a method is provided for synthesizing a terminal olefin, the method comprising contacting, in the presence of a ruthenium alkylidene metathesis catalyst, an olefinic substrate comprised of at least one internal olefin with a cross metathesis partner comprised of an alpha olefinic reactant, under reaction conditions effective to allow cross-metathesis to occur, wherein the reaction conditions include a reaction temperature of at least 35° C. The methods, compositions, reactions and reaction systems herein disclosed have utility in the fields of catalysis, organic synthesis, and industrial chemistry.