3-(mesityl(p-tolyl)methyl)-2,5-dimethylfuran | 1011800-85-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 3-(mesityl(p-tolyl)methyl)-2,5-dimethylfuran
• 英文别名: 2,5-Dimethyl-3-[(4-methylphenyl)-(2,4,6-trimethylphenyl)methyl]furan
• CAS: 1011800-85-3
• 化学式: C₂₃H₂₆O
• 分子量: 318.459
• InChiKey: KSADRKKPBFLXFB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  13.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2,5-二甲基呋喃 、 [(4-Methylphenyl)-(2,4,6-trimethylphenyl)methyl] acetate 在 三氯化铁 作用下， 以 二氯甲烷 为溶剂， 生成 3-(mesityl(p-tolyl)methyl)-2,5-dimethylfuran
  参考文献：
  名称：

  A simple access to triarylmethane derivatives from aromatic aldehydes and electron-rich arenes catalyzed by FeCl3

  摘要：

  Under 'open-flask' and mild conditions, arenes condense smoothly with aromatic aldehydes in the presence of catalytic amount of FeCl3. The reaction tolerated a variety of substitutions and functional groups. This method provides a facile and direct access to symmetrical and unsymmetrical triarylmethane derivatives. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2007.11.080

文献信息

• A simple access to triarylmethane derivatives from aromatic aldehydes and electron-rich arenes catalyzed by FeCl3
  作者：Zhongxian Li、Zheng Duan、Jianxun Kang、Huaiqiu Wang、Liujian Yu、Yangjie Wu

  DOI：10.1016/j.tet.2007.11.080

  日期：2008.2

  Under 'open-flask' and mild conditions, arenes condense smoothly with aromatic aldehydes in the presence of catalytic amount of FeCl3. The reaction tolerated a variety of substitutions and functional groups. This method provides a facile and direct access to symmetrical and unsymmetrical triarylmethane derivatives. (C) 2007 Elsevier Ltd. All rights reserved.