聚(丙烯腈-丁二烯-苯乙烯) | 9003-56-9

• 物质功能分类: 催化剂及助剂 - 聚合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 聚(丙烯腈-丁二烯-苯乙烯)
• 中文别名: 丙烯腈-丁二烯-苯乙烯的共聚物；丙烯腈-丁二烯-苯乙烯；工程塑料；2-丙烯腈与1,3-丁二烯和乙烯基苯的聚合物；丙烯腈-丁二烯-苯乙烯共聚物；丙烯腈与丁二烯和苯乙烯的三元共聚物；丙烯腈-丁二烯-苯乙烯棒材；聚(丙烯腈-co-丁二烯-co-苯乙烯)；丙烯腈-丁二烯-苯乙烯三元共聚物(阻燃)；ABS树脂；ABS
• 英文名称: Acrylonitrile butadiene styrene
• 英文别名: buta-1,3-diene;prop-2-enenitrile;styrene
• CAS: 9003-56-9
• 化学式: C15H17N
• 分子量: 211.3
• InChiKey: XECAHXYUAAWDEL-UHFFFAOYSA-N

物化性质

• 熔点：
  58.54（±0.5）℃
• 密度：
  1.05 g/mL at 25 °C
• 溶解度：
  可溶于丙酮、MEK 和 DMF
• 分解：
  When heated to decomposition it emits toxic vapors of NOx
• 稳定性/保质期：
  遵照规定使用和储存，则不会发生分解。

计算性质

• 辛醇/水分配系数(LogP)：
  4.38
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

ADMET

毒理性

• 毒性总结

识别和使用：ABS树脂是一种由丙烯腈、丁二烯和苯乙烯制成的塑料材料。它用于管道、汽车部件、家电部件、商业机器部件、电话和电气及电子设备、管道配件、娱乐车辆部件。丙烯腈-丁二烯-苯乙烯共聚物的其他用途包括包装；行李箱和箱子；玩具和体育用品；以及家具。自1977年9月以来，不允许使用丙烯腈-丁二烯-苯乙烯共聚物制造饮料容器。人类暴露和毒性：在台湾进行的一项流行病学研究发现，ABS塑料注塑成型过程可能会加剧工人的嗅觉功能下降。值得注意的是，这种效应降低了嗅觉阈值评分，而不是气味识别评分。动物研究：ABS降解产品的急性毒性被发现与其他常见聚合物材料的热分解产物的毒性相当。大鼠暴露于热氧化降解产物会导致肝脏和肾脏组织中还原型谷胱甘肽浓度降低，但肺部不会。在三天暴露期间，肝脏和大脑中的超氧化物歧化酶活性增加。在两周的暴露后，肝脏的活性达到了对照组的值，但大脑的活性显著低于对照组。在豚鼠中，反复暴露会导致感官刺激、咳嗽、呼吸道收缩和死亡，并且有累积性呼吸道影响的证据，幸存者的恢复较慢。在老鼠中，从ABS树脂烟雾暴露中恢复的速度比从用作比较的道格拉斯冷杉木片烟雾暴露中恢复的速度慢。

IDENTIFICATION AND USE: ABS resin is a plastic material made from acrylonitrile, butadiene and styrene. It is used in piping, automotive components, appliance components, components of business machines, telephones and electrical and electronic equipment, pipe fittings, recreational vehicle components. Other uses of acrylonitrile-butadiene-styrene copolymers include packaging; luggage and cases; toys and sporting goods; and furniture. Since September 1977, acrylonitrile-butadiene-styrene copolymers are no longer permitted in the fabrication of beverage containers. HUMAN EXPOSURE AND TOXICITY: The findings of epidemiology study conducted in Taiwan implied the ABS plastic injection-moulding process may worsen olfactory function among workers. Notably, this effect decreased olfactory threshold scores, not odor identification scores. ANIMAL STUDIES: The acute toxicity of ABS degradation products was found to be comparable with the toxicity of the thermal decomposition products of other common polymeric materials. Rats exposure to thermo-oxidation degradation products produced a decrease in tissue reduced glutathione concentration in liver and kidney but not in lung. Superoxide dismutase activity increased in liver and brain during the three-day exposure. In liver the activity reached the control value after the two-week exposure but the cerebral activity was significantly lower than in controls. In guinea pigs repeated exposure resulted in sensory irritation, coughing, and airways constriction and deaths, and there was evidence of cumulative respiratory effects, and slower recoveries among survivors. In mice recovery from the effects of exposure to ABS resin smoke was slower than recovery from exposure to smoke from Douglas fir chips, which was used as a comparison.

来源:Hazardous Substances Data Bank (HSDB)

毒理性

• 相互作用

安大略省劳工部职业健康分局于1978年开始对丙烯腈（AN）暴露相关的健康风险进行评估研究。在十四个工厂进行了详细的卫生和医疗调查，以评估各种工业过程中AN的暴露情况。还研究了四家与混合化学暴露有关的公司，涉及丙烯纤维、腈橡胶、ABS树脂和丙烯乳液的生产。由于二甲基甲酰胺、苯乙烯和丁二烯具有相似的药代动力学和可能的协同作用，因此审查了AN和其他共存化学暴露之间的可能相互作用。丙烯纤维生产中的暴露可能是协同的和致癌的。空气监测的结果表明，在大多数情况下，AN的暴露水平低于2 ppm（平均加权浓度）。对其他共存化学物质进行了评估。医疗检测结果表示，在当前暴露的工人中，胸部X光片或肝功能测试没有显著异常。

The Occupational Health Branch of the Ontario Ministry of Labour began a study in 1978 for the evaluation of health risks associated with acrylonitrile (AN) exposure. Detailed hygiene and medical investigations were conducted in fourteen plants for evaluating AN exposure in various industrial processes. Four companies were also studied in relation to mixed chemical exposure representing acrylic fibres, nitrile rubber, ABS-resin, and acrylic emulsions production. The possible interaction between AN and other coexisting chemical exposures was reviewed since dimethyl formamide, styrene, and butadiene have similar pharmacokinetics and possible synergistic effects. Exposure in acrylic fibre production may be synergistic and carcinogenic. Results of air monitoring indicated exposure levels to AN below 2 ppm (TWA) in most cases. Exposure to other co-existing chemicals was evaluated. Results of medical tests indicated no significant abnormalities in chest x-rays or liver function tests in currently exposed workers.

来源:Hazardous Substances Data Bank (HSDB)

毒理性

• 解毒与急救

/SRP:/ 立即急救：确保已经进行了充分的中和。如果患者停止呼吸，请开始人工呼吸，最好使用需求阀复苏器、袋阀面罩装置或口袋面罩，按训练操作。如有必要，执行心肺复苏。立即用缓慢流动的水冲洗受污染的眼睛。不要催吐。如果发生呕吐，让患者前倾或将其置于左侧（如果可能的话，头部向下）以保持呼吸道畅通，防止吸入。保持患者安静，维持正常体温。寻求医疗帮助。 /芳香烃及其相关化合物/

/SRP:/ Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Aromatic hydrocarbons and related compounds/

来源:Hazardous Substances Data Bank (HSDB)

毒理性

• 解毒与急救

/SRP:/ 基本治疗：建立专利气道（如有需要，使用口咽或鼻咽气道）。如有必要，进行吸痰。密切观察呼吸不足的迹象，如有必要，进行辅助通气。通过非重复呼吸面罩以10至15升/分钟的速度给予氧气。监测肺水肿，并在必要时进行治疗……。监测休克，并在必要时进行治疗……。预防癫痫发作，并在必要时进行治疗……。对于眼睛污染，立即用水冲洗眼睛。在转运过程中，用0.9%的生理盐水（NS）持续冲洗每只眼睛……。不要使用催吐剂。对于摄入，如果患者能够吞咽、有强烈的干呕反射且不流口水，则用水冲洗口腔，并给予5毫升/千克，最多200毫升的水进行稀释。给予活性炭……。/芳香烃及其相关化合物/

/SRP:/ Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 mL/kg up to 200 mL of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal ... . /Aromatic hydrocarbons and related compounds/

来源:Hazardous Substances Data Bank (HSDB)

毒理性

• 解毒与急救

/SRP:/ 高级治疗：对于无意识、严重肺水肿或严重呼吸困难的病人，考虑进行口咽或鼻咽气管插管以控制气道。考虑使用药物治疗肺水肿……正压通气技术，使用气囊面罩装置可能有益。考虑使用药物治疗肺水肿……考虑给予β激动剂，如沙丁胺醇，用于严重支气管痉挛……监测心率和必要时治疗心律失常……开始静脉输注5%葡萄糖（D5W）/SRP: "保持开放"，最低流量/。如果出现低血容量迹象，使用0.9%生理盐水（NS）或乳酸钠林格液（LR）。对于伴有低血容量迹象的低血压，谨慎给予液体。注意液体过载的迹象……用地西泮或劳拉西泮治疗癫痫……使用丙美卡因氢氯化物协助眼部冲洗……/芳香烃及其相关化合物/

/SRP:/ Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in severe respiratory distress. Consider drug therapy for pulmonary edema ... . Positive-pressure ventilation techniques with a bag valve mask device may be beneficial. Consider drug therapy for pulmonary edema ... . Consider administering a beta agonist such as albuterol for severe bronchospasm ... . Monitor cardiac rhythm and treat arrhythmias if necessary ... Start IV administration of D5W /SRP: "To keep open", minimal flow rate/. Use 0.9% saline (NS) or lactated Ringer's (LR) if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluid cautiously. Watch for signs of fluid overload ... .Treat seizures with diazepam or lorazepam ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Aromatic hydrocarbons and related compounds/

来源:Hazardous Substances Data Bank (HSDB)

安全信息

• 危险品标志：
  Xn
• 安全说明：
  S26,S36
• 危险类别码：
  R36/37/38,R20/21/22
• WGK Germany：
  3

制备方法与用途

聚（丙烯腈－丁二烯－苯乙烯）共聚物（ABS）是一种典型的两相结构的三组分热塑性树脂，由聚（苯乙烯－丙烯腈）共聚物即SAN连续相和分散的聚丁二烯橡胶相组成。

化学性质 无色单斜晶系结晶或白色粉末，可溶于冷水，其水溶液呈酸性。

用途 ABS广泛应用于汽车、电子、电器、机械、纺织、铁路等行业。具体用途包括制备各种零件如仪表、电气和电器的组件，用于12英寸黑白电视机、彩电机箱。此外，还用作汽车工业材料、建筑材料、木材代用品，并用于制造安全帽、旅行箱、用具壳体及泡沫塑料等。

类别 有毒物品

可燃性危险特性 可燃；加热分解会释放有毒氮氧化物烟雾。

储运特性 库房应通风并保持低温干燥环境。

灭火剂 推荐使用干粉、泡沫、砂土、二氧化碳或雾状水进行灭火。

反应信息

• 作为反应物：
  描述：

  、 聚(丙烯腈-丁二烯-苯乙烯) 、 、 、 乙二胺四乙酸 、 sodium dodecyl benzene sulfonate 、 、 丙烯酸乙酯 、 甲基丙烯酸 以 乙酸乙酯 、 溶剂黄146 、 水 为溶剂， 反应 5.0h， 生成 2-甲基-2-丙烯酸与2-丙烯酸乙酯的聚合物丙烯酸酯的共聚物
  参考文献：
  名称：

  Particle agglomeration in rubber latices

  摘要：

  弹性乳胶制备中的粒径分布可以通过将制备好的乳胶与聚集剂（AgAg）共聚物处理来有效控制和改善。聚集剂共聚物具有弹性“核心”和接枝在其上的“壳层”，壳层由聚合酸和酯共聚物组成。接枝的共聚物可以有益地是乙基丙烯酸乙酯和甲基丙烯酸的聚合混合物。聚集的乳胶产品可以用于直接利用其粒径分布有利的弹性组分或用于其他目的，如接枝聚合物混合物、ABS和类似产品。

  公开号：

  US04419496A1
• 作为产物：
  描述：

  丙烯腈 、 、 苯乙烯 生成 聚(丙烯腈-丁二烯-苯乙烯)
  参考文献：
  名称：

  Polymers derived from a conjugated diolefin, a vinyl-substituted

  摘要：

  本发明涉及由至少三种单体共聚而成的聚合物。该聚合物的重量百分比约为40至84％来自共轭二烯，约为15至50％来自含有乙烯基的芳香化合物，约为1至8％来自烯烃不饱和腈。这些聚合物可添加到胎面胶料中，以提高湿地牵引力和耐磨性。

  公开号：

  US05310815A1

文献信息

• [EN] NITRILE COMPOUND AND ITS USE IN PEST CONTROL<br/>[FR] COMPOSE NITRILE ET SON UTILISATION POUR LE CONTROLE DES INSECTES ET ANIMAUX NUISIBLES
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2005063694A1

  公开（公告）日：2005-07-14

  The present invention provides a nitrile compound represented by the formula (I): wherein R represents C1-C4 fluoroalkyl, Q represents halogen, C1-C11 alkyl optionally substituted with halogen, C2-C6 alkenyl group optionally substituted with halogen, C2-C6 alkynyl optionally substituted with halogen, C3-C7 cycloalkyl optionally substituted with halogen or (C3-C7 cycloalkyl optionally substituted with halogen)C1-C4 alkyl, which has excellent control effect against pests.

  本发明提供了一种由式(I)表示的腈化合物：其中R代表C1-C4氟烷基，Q代表卤素，C1-C11烷基可选择地取代卤素，C2-C6烯基基团可选择地取代卤素，C2-C6炔基可选择地取代卤素，C3-C7环烷基可选择地取代卤素或(C3-C7环烷基可选择地取代卤素)C1-C4烷基，对害虫具有出色的控制效果。
• NOVEL METHINE DYES
  申请人：LANXESS Deutschland Gmbh

  公开号：US20190112486A1

  公开（公告）日：2019-04-18

  The present invention relates to novel methine dyes, methods for the preparation thereof and use thereof for dyeing plastics, especially polyamides, so as to obtain yellow to orange colourings with improved light fastness and improved thermal stability.

  本发明涉及新型甲纶染料，其制备方法和用于染色塑料，特别是聚酰胺，以获得改善光牢度和热稳定性的黄色至橙色着色。
• [EN] POLYMERS<br/>[FR] POLYMÈRES
  申请人：CHROMATWIST LTD

  公开号：WO2021058970A1

  公开（公告）日：2021-04-01

  A method of identifying a first object, the method comprises: providing a first object comprising a material, the material comprising a polymer and a luminescent compound; and detecting an absorption and/or excitation and/or emission spectrum from the luminescent compound of the first object which is indicative of the identity of the object; wherein the luminescent compound is represented by the following general formula (A): wherein X represents one of a nitrogen atom, an oxygen atom, a sulphur atom, a phosphorus atom, or a selenium atom; R represents an aromatic group and/or an aliphatic group; p is an integer of 1 to 2; q and s are independently integers of 1, 2, 3, or 4; Y1, Y2, and Y3 independently represent a hydrogen atom, a deuterium atom, a fluorine atom, a chlorine atom, a bromine atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a polyglycol group (e.g. a group comprising a polyethylene glycol moiety), an oxygen atom (e.g. a hydroxyl group or an alkylated oxygen atom forming an alkoxy group), a nitrogen atom (e.g. a primary, secondary, or tertiary amine group), a cyano group, a nitro group; and/or wherein Y1, Y2, and/or Y3 may combine together to form a condensed ring (e.g. a condensed aromatic ring).

  一种识别第一对象的方法，该方法包括：提供一种第一对象，该对象包含一种材料，该材料包含聚合物和发光化合物；以及检测来自第一对象发光化合物的吸收和/或激发和/或发射光谱，该光谱表明对象的身份；其中发光化合物由以下通式（A）表示：其中X代表氮原子、氧原子、硫原子、磷原子或硒原子中的一个；R代表芳香族和/或脂肪族基团；p是1到2的整数；q和s是独立的1、2、3或4的整数；Y1、Y2和Y3独立代表氢原子、氘原子、氟原子、氯原子、溴原子、取代或未取代的烷基团、取代或未取代的芳基团、聚乙二醇团（例如，包含聚乙二醇部分的团）、氧原子（例如，羟基或形成醇氧基的烷基化氧原子）、氮原子（例如，伯胺、仲胺或叔胺基团）、腈基、硝基；和/或其中Y1、Y2和/或Y3可以相互结合形成一个稠环（例如，稠合的芳香环）。
• Heterocyclic Compound
  申请人：Amasaki Ichiro

  公开号：US20100004439A1

  公开（公告）日：2010-01-07

  A compound represented by the following Formula (1): wherein, Het 1 represents a bivalent five- or six-membered aromatic heterocyclic residue and may further be substituted; X a to X d each independently represent a heteroatom and may further be substituted; Y a to Y f each independently represent a heteroatom or a carbon atom and may further be substituted; the ring bound to Het 1 may have a double bond at any position

  以下是您提供的化学公式(1)的中文翻译： 其中，Het1代表一个二价的五元或六元芳香杂环基团，且可以进一步被取代；Xa至Xd每个独立地代表一个杂原子，且可以进一步被取代；Ya至Yf每个独立地代表一个杂原子或一个碳原子，且可以进一步被取代；与Het1相连的环可以在任何位置有一个双键。
• Method for the preparation of aromatic chloroformates
  申请人：Davis Charles Gary

  公开号：US20060293535A1

  公开（公告）日：2006-12-28

  A method for preparing an aromatic chloroformate comprising, introducing a mixture of at least one aromatic hydroxyl compound, phosgene, at least one solvent, and at least one organic base into a flow reactor to obtain a unidirectionally flowing reaction mixture. The unidirectionally flowing reaction mixture is maintained at a temperature between about 0° C. and about 60° C. to produce a single product stream comprising an aromatic chloroformate.

  一种制备芳香氯甲酸酯的方法包括，将至少一种芳香羟基化合物、光气、至少一种溶剂和至少一种有机碱的混合物引入流动反应器中，以获得单向流动的反应混合物。将单向流动的反应混合物保持在约0°C至约60°C的温度下，以产生包含芳香氯甲酸酯的单一产物流。