2,6-di-tert-butyl-4-methoxy-4-(4-methoxyphenyl)-2,5-cyclohexadien-1-imine | 134006-27-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2,6-di-tert-butyl-4-methoxy-4-(4-methoxyphenyl)-2,5-cyclohexadien-1-imine
• 英文别名: 2,6-Ditert-butyl-4-methoxy-4-(4-methoxyphenyl)cyclohexa-2,5-dien-1-imine
• CAS: 134006-27-2
• 化学式: C₂₂H₃₁NO₂
• 分子量: 341.494
• InChiKey: ZFKPBBQRRZKWEO-UHFFFAOYSA-N

物化性质

• 沸点：
  456.7±45.0 °C(Predicted)
• 密度：
  0.97±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  25
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  42.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  甲醇 、 2,6-Ditert-butyl-4-(4-methoxyphenyl)aniline 在 2,6-二甲基吡啶 作用下， 以 乙腈 为溶剂， 以73%的产率得到2,6-di-tert-butyl-4-methoxy-4-(4-methoxyphenyl)-2,5-cyclohexadien-1-imine
  参考文献：
  名称：

  Electrochemistry of anilines. 6. Reactions of electrogenerated biphenylylnitrenium ions

  摘要：

  3,5-Di-tert-butyl-substituted biphenyl-4-ylnitrenium ions are generated by anodic oxidation of the corresponding biphenylylamines in acetonitrile in the presence of a base. The reactions of these species with several nucleophiles are studied. The principal reaction sites are identified as the positions ortho and para to the = NH moiety. No reactions at the iminium nitrogen and in the second ring of the biphenyl system are observed. Products are characterized by spectroscopic techniques. Some common spectroscopic features of the iminoquinolide reaction products are discussed.

  DOI：

  10.1021/jo00015a019

文献信息

• Electrochemistry of anilines. 6. Reactions of electrogenerated biphenylylnitrenium ions
  作者：Anton Rieker、Bernd Speiser

  DOI：10.1021/jo00015a019

  日期：1991.7

  3,5-Di-tert-butyl-substituted biphenyl-4-ylnitrenium ions are generated by anodic oxidation of the corresponding biphenylylamines in acetonitrile in the presence of a base. The reactions of these species with several nucleophiles are studied. The principal reaction sites are identified as the positions ortho and para to the = NH moiety. No reactions at the iminium nitrogen and in the second ring of the biphenyl system are observed. Products are characterized by spectroscopic techniques. Some common spectroscopic features of the iminoquinolide reaction products are discussed.