(4Z)-2-tert-butyl-4-[(2E)-2-(3-tert-butyl-5-methyl-4-oxocyclohexa-2,5-dien-1-ylidene)ethylidene]-6-methylcyclohexa-2,5-dien-1-one | 147120-00-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (4Z)-2-tert-butyl-4-[(2E)-2-(3-tert-butyl-5-methyl-4-oxocyclohexa-2,5-dien-1-ylidene)ethylidene]-6-methylcyclohexa-2,5-dien-1-one
• CAS: 147120-00-1
• 化学式: C₂₄H₃₀O₂
• 分子量: 350.501
• InChiKey: KYCGFNICJBBFGI-BUOZRGFLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  26
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (4Z)-2-tert-butyl-4-[(2E)-2-(3-tert-butyl-5-methyl-4-oxocyclohexa-2,5-dien-1-ylidene)ethylidene]-6-methylcyclohexa-2,5-dien-1-one 在 溶剂黄146 、 锌 作用下， 生成 2-Tert-butyl-4-[2-(3-tert-butyl-4-hydroxy-5-methylphenyl)ethenyl]-6-methylphenol
  参考文献：
  名称：

  Oxidations with silver carbonate/celite. V. Oxidations of phenols and related compounds

  摘要：

  DOI：

  10.1021/jo00809a004
• 作为产物：
  描述：

  2,4-二甲基-6-叔丁基苯酚 在 silica gel 、 silver carbonate 作用下， 以 苯 为溶剂， 生成 (4Z)-2-tert-butyl-4-[(2E)-2-(3-tert-butyl-5-methyl-4-oxocyclohexa-2,5-dien-1-ylidene)ethylidene]-6-methylcyclohexa-2,5-dien-1-one
  参考文献：
  名称：

  Oxidations with silver carbonate/celite. V. Oxidations of phenols and related compounds

  摘要：

  DOI：

  10.1021/jo00809a004

文献信息

• Polycarbonate copolymer, coating solution, electrophotographic photoreceptor, and electric device
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10241427B2

  公开（公告）日：2019-03-26

  A polycarbonate copolymer includes a repeating unit A represented by a formula (1) below, chain ends of the PC copolymer being terminated by a monovalent aromatic group or a monovalent fluorine-containing aliphatic group. In the above formula (1), R1 is a hydrogen atom or an alkyl group having 1 to 2 carbon atoms; an average repeating number n is in a range from 6 to 40 and L is an integer of 1 to 4; and when an aromatic ring is substituted by two or more of R1 (L≥2), the two or more of R1 are the same or different from each other.

  聚碳酸酯共聚物包括由下式（1）表示的重复单元 A，PC 共聚物的链端由一价芳香族基团或一价含氟脂肪族基团终止。 在上式（1）中，R1 是氢原子或具有 1 至 2 个碳原子的烷基；平均重复数 n 在 6 至 40 的范围内，L 是 1 至 4 的整数；当芳香环被两个或两个以上的 R1（L≥2）取代时，两个或两个以上的 R1 彼此相同或不同。
• POLYCARBONATE COPOLYMER, COATING SOLUTION, ELECTROPHOTOGRAPHIC PHOTORECEPTOR, AND ELECTRIC DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20170075237A1

  公开（公告）日：2017-03-16

  A polycarbonate copolymer includes a repeating unit A represented by a formula (1) below, chain ends of the PC copolymer being terminated by a monovalent aromatic group or a monovalent fluorine-containing aliphatic group. In the above formula (1), R 1 is a hydrogen atom or an alkyl group having 1 to 2 carbon atoms; an average repeating number n is in a range from 6 to 40 and L is an integer of 1 to 4; and when an aromatic ring is substituted by two or more of R 1 (L≧2), the two or more of R 1 are the same or different from each other.
• US9551946B2
  申请人：——

  公开号：US9551946B2

  公开（公告）日：2017-01-24
• Oxidations with silver carbonate/celite. V. Oxidations of phenols and related compounds
  作者：Marcel Fetizon、Valeria Balogh、Michel Golfier

  DOI：10.1021/jo00809a004

  日期：1971.5