Diethyl 2-[[3-[tert-butyl(dimethyl)silyl]oxy-4-[2-[tert-butyl(dimethyl)silyl]oxynaphthalen-1-yl]naphthalen-2-yl]methylidene]propanedioate | 1352391-08-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• 英文名称: Diethyl 2-[[3-[tert-butyl(dimethyl)silyl]oxy-4-[2-[tert-butyl(dimethyl)silyl]oxynaphthalen-1-yl]naphthalen-2-yl]methylidene]propanedioate
• 英文别名: diethyl 2-[[3-[tert-butyl(dimethyl)silyl]oxy-4-[2-[tert-butyl(dimethyl)silyl]oxynaphthalen-1-yl]naphthalen-2-yl]methylidene]propanedioate
• CAS: 1352391-08-2
• 化学式: C₄₀H₅₂O₆Si₂
• 分子量: 685.02
• InChiKey: HUNLHCFNFYQIIJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.94
• 重原子数：
  48
• 可旋转键数：
  14
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  Diethyl 2-[[3-[tert-butyl(dimethyl)silyl]oxy-4-[2-[tert-butyl(dimethyl)silyl]oxynaphthalen-1-yl]naphthalen-2-yl]methylidene]propanedioate 在 四丁基氟化铵 作用下， 以 四氢呋喃 为溶剂， 反应 5.0h， 以95%的产率得到
  参考文献：
  名称：

  A Selective, Colorimetric, and Fluorescent Chemodosimeter for Relay Recognition of Fluoride and Cyanide Anions Based on 1,1′-Binaphthyl Scaffold

  摘要：

  The reaction-based relay recognition of fluoride and cyanide anions was demonstrated for the first time, with rapid response and unique triple (fluorescence color, intensity and absorption band) output modes In either of two sequential sensing events. Ratiometric determination of these two anions by fluorescence and/or absorbance spectra is also achieved.

  DOI：

  10.1021/ol202926e
• 作为产物：
  描述：

  叔丁基二甲基氯硅烷 在 吡啶 、 咪唑 、 4-二甲氨基吡啶 、 四氯化钛 作用下， 以 四氢呋喃 、 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 25.0h， 生成 Diethyl 2-[[3-[tert-butyl(dimethyl)silyl]oxy-4-[2-[tert-butyl(dimethyl)silyl]oxynaphthalen-1-yl]naphthalen-2-yl]methylidene]propanedioate
  参考文献：
  名称：

  A Selective, Colorimetric, and Fluorescent Chemodosimeter for Relay Recognition of Fluoride and Cyanide Anions Based on 1,1′-Binaphthyl Scaffold

  摘要：

  The reaction-based relay recognition of fluoride and cyanide anions was demonstrated for the first time, with rapid response and unique triple (fluorescence color, intensity and absorption band) output modes In either of two sequential sensing events. Ratiometric determination of these two anions by fluorescence and/or absorbance spectra is also achieved.

  DOI：

  10.1021/ol202926e

文献信息

• A Selective, Colorimetric, and Fluorescent Chemodosimeter for Relay Recognition of Fluoride and Cyanide Anions Based on 1,1′-Binaphthyl Scaffold
  作者：Ming Dong、Yu Peng、Yu-Man Dong、Ning Tang、Ya-Wen Wang

  DOI：10.1021/ol202926e

  日期：2012.1.6

  The reaction-based relay recognition of fluoride and cyanide anions was demonstrated for the first time, with rapid response and unique triple (fluorescence color, intensity and absorption band) output modes In either of two sequential sensing events. Ratiometric determination of these two anions by fluorescence and/or absorbance spectra is also achieved.