Saussureal | 141365-00-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Saussureal
• CAS: 141365-00-6
• 化学式: C₁₅H₂₀O₃
• 分子量: 248.322
• InChiKey: OOHSZMHOXQXINH-FBEMMQQVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  18.0
• 可旋转键数：
  1.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  43.37
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  Saussureal 在 palladium on activated charcoal 氢气 、 对甲苯磺酸 作用下， 以 乙醇 、 苯 为溶剂， 24.0 ℃ 、95.06 kPa 条件下， 反应 10.5h， 生成 (3S,3aS,5aR,9aR,9bS)-3,5a,9-Trimethyl-3a,4,5,5a,6,7,9a,9b-octahydro-3H-naphtho[1,2-b]furan-2-one
  参考文献：
  名称：

  A sesquiterpenoid with plant growth regulatory activity fromSaussurea lappa

  摘要：

  Saussureal, a sesquiterpenoid with a new type of modified eudesmane skeleton has been isolated from roots of Saussurea lappa. In saussureal, ring A is five-membered and displays significant biological activity as a plant growth regulator. Its structure has been elucidated on the basis of spectral data and chemical correlation with alpha-santenolide.

  DOI：

  10.1016/0031-9422(91)83069-w

文献信息

• A sesquiterpenoid with plant growth regulatory activity fromSaussurea lappa
  作者：K.K. Talwar、I.P. Singh、P.S. Kalsi

  DOI：10.1016/0031-9422(91)83069-w

  日期：1992.1

  Saussureal, a sesquiterpenoid with a new type of modified eudesmane skeleton has been isolated from roots of Saussurea lappa. In saussureal, ring A is five-membered and displays significant biological activity as a plant growth regulator. Its structure has been elucidated on the basis of spectral data and chemical correlation with alpha-santenolide.