6-(2-羟基苯基)菲啶 | 34411-94-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 中文名称: 6-(2-羟基苯基)菲啶
• 英文名称: 6-(2-hydroxyphenyl)phenanthridine
• 英文别名: 2-phenanthridin-6-yl-phenol；2-Phenanthridin-6-ylphenol；2-phenanthridin-6-ylphenol
• CAS: 34411-94-4
• 化学式: C₁₉H₁₃NO
• 分子量: 271.318
• InChiKey: SYRDZOSDJITKRL-UHFFFAOYSA-N

物化性质

• 沸点：
  458.8±30.0 °C(Predicted)
• 密度：
  1.264±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  21
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  33.1
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2'-allyloxybenzophenone 在 对甲苯磺酸 作用下， 以 甲苯 为溶剂， 650.0 ℃ 、1.33 Pa 条件下， 反应 21.0h， 生成 6-(2-羟基苯基)菲啶
  参考文献：
  名称：

  1-（2-芳氧基苯基）烷氨基和2-（芳基甲基）苯氧基自由基的气相转化研究

  摘要：

  在650°C（5×10 –2 –5×10 –3 Torr）下对丙烯醚9-11和肟醚15-17进行快速真空热解会生成2-（芳基甲基）苯氧基4和1-（2 -分别可以经由螺二烯基互变的-芳氧基苯基）链氨基胺基5导致通常以低到中等产率分离的普通产物。亚氨基5通常在环化后经历β-切割，从而产生腈（例如21）和/或苯并呋喃（例如22）。苯氧基4表现出更复杂的行为，主要受制于氢提取过程的影响，最终导致生成产物，例如酚（例如32），吲哚27或菲啶34和35。

  DOI：

  10.1039/a800884a

文献信息

• Gas-phase generation and cyclisation reactions of imidoyl radicals
  作者：Rino Leardini、Hamish McNab、Daniele Nanni、Anton G. Tenan、Andrew Thomson

  DOI：10.1039/c1ob06228j

  日期：——

  Some 1,2-diarylimidoyl radicals were generated in the gas-phase by intramolecular radical translocation from ortho-imino-aryloxyl radicals, in turn generated under flash vacuum pyrolysis (FVP) conditions. The imidoyls reacted with XRortho′-substituents in the N-aryl group to give (in most cases) modest yields of cyclisation products. Depending on the nature of the bridging atom (X), the formation of

  在气相中，通过邻亚氨基亚氨基芳基氧基的分子内基团易位而在气相中产生了一些1，2-二芳基酰亚胺基，然后在快速真空热解（FVP）条件下产生了该基团。亚胺基与N-芳基中的XR邻位取代基反应（在大多数情况下）产生适量的环化产物。取决于桥接原子（X）的性质，这些产物的形成是通过进一步的氢原子易位（X = CH 2）或通过ipso引发的-攻击芳基（R = Ph），或通过直接取代杂原子（X = S）。XR = N（Me）Ph时，主要反应产物可能是不涉及相应亚氨酰基的竞争途径的结果。
• ORGANIC ELECTROLUMINESCENT DEVICE HAVING AN AZATRIPHENYLENE DERIVATIVE
  申请人：Zheng Shiying

  公开号：US20090115316A1

  公开（公告）日：2009-05-07

  Azatriphenylene derivatives and their use in the electron-transporting layer of an electroluminescent device that comprises an anode, a spaced-apart cathode, and at least one electron-transporting layer disposed between the spaced-apart anode and cathode. Such EL devices provide lower drive voltage, improved power efficiency, and longer operational lifetime.

  Azatriphenylene衍生物及其在电致发光装置中的使用，该装置包括阳极，间隔的阴极，以及至少一个位于间隔的阳极和阴极之间的电子传输层。这样的EL设备提供更低的驱动电压、改善的功率效率和更长的操作寿命。
• Heterocyclic compound and organic light-emitting element using same
  申请人：LG CHEM, LTD.

  公开号：US10032997B2

  公开（公告）日：2018-07-24

  The present specification provides a heterocyclic compound and an organic light emitting device using the same.

  本说明书提供了一种杂环化合物和使用该杂环化合物的有机发光器件。
• Organic element for low voltage electroluminescent devices
  申请人：Begley J. William

  公开号：US20070092755A1

  公开（公告）日：2007-04-26

  An OLED device comprises a cathode, a light emitting layer and an anode, in that order, and comprises; (i) a further layer located between the cathode and the light emitting layer, containing (a) 10 vol % or more of a carbocyclic fused ring aromatic compound, and (b) at least one salt or complex of a Group IA, IIA, IIIA and IIB element of the Periodic Table, and (ii) an additional layer, located between the anode and the light emitting layer, containing a compound of Formula (8) wherein: each R independently represents hydrogen or an independently selected substituent, at least one R representing an electron-withdrawing substituent having a Hammett's sigma para value of at least 0.3. Such devices exhibit reduce drive voltage while maintaining good luminance.
• PHOSPHORESCENT OLED HAVING DOUBLE EXCITON-BLOCKING LAYERS
  申请人：Liao Liang-Sheng

  公开号：US20080315753A1

  公开（公告）日：2008-12-25

  An organic light-emitting device comprising an anode; a cathode; a hole-transporting layer disposed between the anode and the cathode; a phosphorescent light-emitting layer disposed between the hole-transporting layer and the cathode, wherein the phosphorescent light-emitting layer includes at least one host and at least one phosphorescent dopant; a first exciton-blocking layer disposed between the hole-transporting layer and the phosphorescent light-emitting layer; wherein the first exciton-blocking layer has a triplet energy greater than the triplet energy of the host in the phosphorescent light-emitting layer; and a second exciton-blocking layer disposed between the first exciton-blocking layer and the phosphorescent light-emitting layer, wherein the second exciton-blocking layer is in contact with the phosphorescent light-emitting layer, and wherein the second exciton-blocking layer has a triplet energy less than the triplet energy of the first exciton-blocking layer.