3',3'-dimethylspiroheptane>

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 3',3'-dimethylspiroheptane>
• 英文别名: exo-3,3-dimethylspiro[bicyclo[2.2.1]heptane-2,2'-oxirane]；(1R,3R,4S)-2,2-dimethylspiro[bicyclo[2.2.1]heptane-3,2'-oxirane]
• 化学式: C₁₀H₁₆O
• 分子量: 152.236
• InChiKey: ISNKNHAUYOWDHN-KHQFGBGNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3',3'-dimethylspiroheptane> 、 alkaline earth salt of/the/ methylsulfuric acid 在 sodium ethanolate 作用下， 以 乙醇 为溶剂， 反应 5.0h， 以58%的产率得到2,2-dimethyl-3-<(methylthio)methyl>bicyclo<2.2.1>heptan-3-ol
  参考文献：
  名称：

  Lodochnikova; Nikitina; Plemenkov, Russian Journal of General Chemistry, 1998, vol. 68, # 11, p. 1744 - 1747

  摘要：

  DOI：
• 作为产物：
  描述：

  dl-camphene 在 sodium hypochlorite 、 Mn-TDClPP 、 甲基三辛基氯化铵 、 1-己基咪唑 作用下， 以 乙醇 、 水 为溶剂， 反应 0.03h， 以96%的产率得到3',3'-dimethylspiroheptane>
  参考文献：
  名称：

  Banfi, Stefano; Montanari, Fernando; Penso, Michele, Gazzetta Chimica Italiana, 1987, vol. 117, # 11, p. 689 - 694

  摘要：

  DOI：

文献信息

• Oxidation studies on some natural monoterpenes: Citral, pulegone, and camphene
  作者：E. M. Elgendy、S. A. Khayyat

  DOI：10.1134/s1070428008060067

  日期：2008.6

  Citral extracted from Cymbopogon citratus (Gramineae) was subjected to photochemical epoxidation with hydrogen peroxide to obtain a mixture of epoxy derivatives at the C-2=C-3 and C-6=C-7 double bonds. The thermal oxidation of citral with m-chloroperoxybenzoic acid at room temperature gave only the corresponding 6,7-epoxy derivative as a mixture of E and Z isomers with respect to the C-2=C-3 double bond. Photosensitized oxygenation of citral in the presence of tetraphenylporphyrin, Rose Bengal, or chlorophyll lead to a mixture of two isomeric hydroperoxides, (2E)-6-hydroperoxy-3,7-dimethylocta-2,7-dienal and (2E,5E)-7-hydroperoxy-3,7-dimethylocta-2,5-dienal. Epoxidation of pulegone isolated from Penny royal oil (Mentha pulegium, Lamiaceae) with hydrogen peroxide under irradiation with a sodium lamp lead to a mixture of cis- and trans-isomeric 2,2,6-trimethyl-1-oxaspiro[2.5]octan-4-ones, whereas under conditions of photosensitized oxygenation two hydroperoxide derivatives, 2-(1-hydroperoxy-1-methylethyl)-5-methylcyclohex-2-en-1-one and 2-hydroperoxy-5-methyl-2-(1-methylethenyl)cyclohexan-1-one, were also formed. Camphene reacted with hydrogen peroxide under irradiation to give a mixture of the corresponding endo- and exo-epoxy derivatives and camphor, while its thermal oxidation with m-chloroperoxybenzoic produced only the two former.
• Aerobic oxygenation/dehydrogenation of olefins and 14-dihydropyridines catalyzed by tris(tetrazolyl enolate)iron(III) complexes
  作者：Rolf W. Saalfrank、Stefan Reihs、Martin Hug

  DOI：10.1016/s0040-4039(00)61720-3

  日期：1993.9

  The catalytic epoxidation of olefins 4 - 7 catalyzed by synthetic metalloporphyrin analogues [FeL3] 3 associated with molecular oxygen in the presence of an electron source (isobutyraldehyde) is described. Furthermore, it is shown, that 4-substituted 1,4-dihydropyridines 12 can be dehydrogenated and dealkylated, respectively, by the same system. The analogy to cytochrome P-450 is obvious.
• Banfi, Stefano; Montanari, Fernando; Penso, Michele, Gazzetta Chimica Italiana, 1987, vol. 117, # 11, p. 689 - 694
  作者：Banfi, Stefano、Montanari, Fernando、Penso, Michele、Sosnovskikh, Viecheslav、Vigano, Patrizia

  DOI：——

  日期：——
• Lodochnikova; Nikitina; Plemenkov, Russian Journal of General Chemistry, <hi>1998</hi>, vol. 68, # 11, p. 1744 - 1747
  作者：Lodochnikova、Nikitina、Plemenkov、Litvinov、Kataeva

  DOI：——

  日期：——