1-(trans-4-Pentylcyclohexyl)-4-ethoxybenzene | 84540-32-9

• 物质功能分类: 有机原料 - 烃类化合物及其衍生物 - 芳香烃
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-(trans-4-Pentylcyclohexyl)-4-ethoxybenzene
• 英文别名: 1-ethoxy-4-(4-pentylcyclohexyl)benzene
• CAS: 84540-32-9
• 化学式: C₁₉H₃₀O
• 分子量: 274.4
• InChiKey: GJHKWLSRHNWTAN-UHFFFAOYSA-N

物化性质

• 熔点：
  53 °C
• 沸点：
  375.7±21.0 °C(Predicted)
• 密度：
  0.920±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  20
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 危险品运输编号：
  UN 2811
• 危险性防范说明：
  P280,P305+P351+P338
• 危险性描述：
  H302

制备方法与用途

用途：液晶单体

反应信息

• 作为产物：
  描述：

  5-(4-ethoxyphenyl)-2-pentylcyclohexan-1-one 生成 1-(trans-4-Pentylcyclohexyl)-4-ethoxybenzene
  参考文献：
  名称：

  JOSIMOTO, XATAOSAKI

  摘要：

  DOI：

文献信息

• LIQUID CRYSTAL COMPOUNDS OF BUTYLENES
  申请人：Hu Baohua

  公开号：US20110260106A1

  公开（公告）日：2011-10-27

  A nematic phase liquid crystal compound with negative dielectric constant has a structure represented by wherein R1 represents a hydrogen atom or linear alkyl having 1 to 8 carbon atoms or linear alkenyl having 1-8 carbon atoms, or an alkoxy or alykenoxy formed by substituting one or nonadjacent two CH1 in the linear alkyl or alkenyl with oxygen atom, wherein 0 to 4 hydrogen atoms of R1 group can be substituted with fluorine; R2 represents a hydrogen atom or linear alkyl having 1 to 8 carbon atoms, or R2 represents a linear fluoroalkyl having 1 to 8 carbon atoms, in which group 0 to 4 hydrogens can be substituted with fluorine atoms; A represents a benzene ring or 1,4-cyclohexane ring, if A is a benzene ring 0 to 4 hydrogen atoms on the benzene ring may be substituted with fluorine; n=1 to 2, and m=0 to 2.

  一种具有负介电常数的向列相液晶化合物，其结构表示为其中，R1代表氢原子或具有1至8个碳原子的线性烷基或具有1至8个碳原子的线性烯基，或通过将线性烷基或烯基中的一个或非相邻的两个CH1取代为氧原子而形成的烷氧基或烯氧基，其中R1基团的0至4个氢原子可以被氟取代；R2代表氢原子或具有1至8个碳原子的线性烷基，或R2代表具有1至8个碳原子的线性氟代烷基，其中该基团的0至4个氢原子可以被氟原子取代；A代表苯环或1,4-环己烷环，如果A是苯环，则苯环上的0至4个氢原子可以被氟取代；n=1至2，m=0至2。
• CYCLOHEPTANE DERIVATIVE AND PREPARATION METHOD AND USE THEREOF
  申请人：SHI JIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIALS CO., LTD.

  公开号：US20150252261A1

  公开（公告）日：2015-09-10

  A cycloheptane derivative as represented by formula (I), and preparation method and use thereof; the compound has photostability and thermostability, wide nematic phase and liquid crystalline state temperature range, and good low-temperature intersolubility, and particularly has low rotary viscosity γ 1 and good dielectric anisotropy (Δ∈>0).

  一种由式（I）表示的环庚烷衍生物，其制备方法和用途；该化合物具有光稳定性和热稳定性，宽的向列相和液晶状态温度范围，良好的低温相容性，特别是具有低旋转粘度γ1和良好的介电各向异性（Δ∈>0）。
• POLYMERIZABLE COMPOUND AND LIQUID CRYSTAL COMPOSITION INCLUDING IT
  申请人：Ito Maiko

  公开号：US20120092608A1

  公开（公告）日：2012-04-19

  Provided is a polymerizable compound with large solubility in a liquid crystal composition and high reactivity irradiated by ultraviolet in the longer wavelength range. Provided is a liquid crystal composition that satisfies at least one of characteristics such as high maximum temperature of a nematic phase, low minimum temperature of a nematic phase, small viscosity, suitable optical anisotropy, large negative dielectric anisotropy, large specific resistance, high stability to ultraviolet light and high stability to heat, or that is suitably balanced between at least two of the characteristics. Provided is the polymerizable compound wherein at least one of a 1,3-phenylene structure and a 2,7-fluorenediyl structure is introduced to the polymerizable compound to give stable displays by forming a polymer with a high degree of polymerization in a PSA device production process using longer wavelengths, the liquid crystal composition includes the compound, and the liquid crystal display device contains the composition.

  提供了一种具有较大溶解度和高反应性的聚合物化合物，该化合物可在较长波长范围内受紫外线照射。提供了一种液晶组合物，该组合物具有以下特征之一：高向列相最高温度、低向列相最低温度、小粘度、适当的光学各向异性、大负介电各向异性、大特定电阻、对紫外线和热稳定性高，或在至少两个特征之间适当平衡。提供了一种聚合物化合物，其中至少引入了1,3-苯基结构和2,7-芴基二基结构，以在使用较长波长的PSA设备生产过程中形成高聚物，从而提供稳定的显示，该液晶组合物包括该化合物，且液晶显示装置包含该组合物。
• Liquid crystal composition and liquid crystal display element comprising the same
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：EP0768361A1

  公开（公告）日：1997-04-16

  The invention presents an excellent liquid crystal display composition possessing a negative dielectric anisotropy, comprising one or more compounds selected from the group consisting of formulas I, II, III, IV and V, where R1 is alkyl, alkoxyalkyl, mono- or difluoroalkyl, or alkenyl, with each group having 2 to 7 carbon atoms; h, i, j, and k denote 0 or 1 with proviso that i+j=1; m is 0, 1 or 2; a six-membered ring expressed by A, B, or C respectively represents any one of trans-1-sila-1,4-cyclohexylene, trans-4-sila-1,4-cyclohexylene, or trans-1,4-cyclohexylene group; L represents F; and L1 and L2 represent H or F; n is 0, 1 or 2; and R2 is H, R1 or OR1, in which at least one compound thereof contains trans-1-sila-1,4-cyclohexylene group or trans-4-sila-1,4-cyclohexylene group.

  本发明提出了一种具有负电介电各向异性的优异液晶显示器组合物，该组合物由一种或多种选自式 I、II、III、IV 和 V 组的化合物组成、 其中，R1 是烷基、烷氧基烷基、单或二氟烷基或烯基，每个基团具有 2 至 7 个碳原子；h、i、j 和 k 表示 0 或 1，但 i+j=1 ；m 是 0、1 或 2；分别由 A、B 或 C 表示的六元环代表反式-1-硅杂-1,4-环己烯、反式-4-硅杂-1,4-环己烯或反式-1,4-环己烯基团中的任一个；L代表F；L1和L2代表H或F；n为0、1或2；R2为H、R1或OR1，其中至少一种化合物含有反式-1-西拉-1,4-环己烯基团或反式-4-西拉-1,4-环己烯基团。
• LIQUID CRYSTAL COMPOSITION AND LIQUID CRYSTAL DISPLAY ELEMENT INCORPORATING SAME
  申请人：DIC Corporation

  公开号：EP2806009A1

  公开（公告）日：2014-11-26

  It is an object of the present invention to provide a liquid crystal composition which is suitably used in a liquid crystal display device without impairment of properties inherent in liquid crystal display devices, such as dielectric anisotropy, viscosity, upper limit of temperature of a nematic phase, stability of a nematic phase at low temperature, and γ1, and generation of screen burn-in in the display device, the liquid crystal composition being less likely to cause droplet stains in manufacturing of the liquid crystal display device and enabling ejection of a liquid crystal material in a stable amount in an ODF process; it is another object of the present invention to provide a liquid crystal display device in which such a liquid crystal composition is used. There is provided a liquid crystal composition having a negative dielectric anisotropy and containing at least one compound represented by General Formula (I) and at least one compound represented by General Formula (II). There is also provided a liquid crystal display device involving use of such a liquid crystal composition having a negative dielectric anisotropy and containing at least one compound represented by General Formula (I) and at least one compound represented by General Formula (II).

  本发明的一个目的是提供一种液晶组合物，该液晶组合物可适当地用于液晶显示装置中，而不会损害液晶显示装置的固有特性，如介电体各向异性、粘度、向列相的温度上限、向列相在低温下的稳定性和γ1，也不会在显示装置中产生烧屏现象，该液晶组合物在制造液晶显示装置时不易造成液滴污点，并能在 ODF 工艺中以稳定的量喷射液晶材料；本发明的另一个目的是提供一种使用这种液晶组合物的液晶显示装置。 本发明提供了一种具有负介电各向异性的液晶组合物，它含有至少一种由通式（I）表示的化合物和至少一种由通式（II）表示的化合物。本发明还提供了一种液晶显示装置，其中使用了这种具有负介电各向异性的液晶组合物，并含有至少一种由通式（I）代表的化合物和至少一种由通式（II）代表的化合物。