1-O,6-O-Diacetylloganol | 39947-80-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 1-O,6-O-Diacetylloganol
• 英文别名: methyl (1S,4aS,6S,7R,7aS)-1,6-diacetyloxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-4-carboxylate
• CAS: 39947-80-3；66213-19-2；71462-04-9；87554-85-6；91739-09-2
• 化学式: C₁₅H₂₀O₇
• 分子量: 312.32
• InChiKey: UJVSCOPJNGPMCR-GFFXGSQUSA-N

物化性质

• 沸点：
  386.9±42.0 °C(Predicted)
• 密度：
  1.24±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  88.1
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  1-O,6-O-Diacetylloganol 、 trimethylsilyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside 、 三氟甲磺酸三甲基硅酯 以84%的产率得到
  参考文献：
  名称：

  TIETZE, LUTZ F.;FISCHER, ROLAND;REMBERG, GERD, LIEBIGS ANN. CHEM.,(1987) N 11, 971-975

  摘要：

  DOI：
• 作为产物：
  描述：

  乙酸酐 、 Loganetin/1-Epiloganetin 在 吡啶 作用下， 生成 1-O,6-O-Diacetylloganol
  参考文献：
  名称：

  Fungitoxic non-glycosidic iridoids from Alibertia macrophylla

  摘要：

  The aqueous alcohol extract of the leaves of Alibertia macrophylla afforded two epimeric pairs of iridoid aglycones and one of them showed high inhibitory activity against Aspergillus niger, Cladosporium sphaerospermum, C. cladosporioides and Colletotrichum gloesporioides. Three of the compounds are reported for the first time from natural sources. Their structures were established on the basis of spectroscopic studies, mainly through C-13 NMR analysis.

  DOI：

  10.1016/0031-9422(92)83701-y

文献信息

• TIETZE, LUTZ F.;FISCHER, ROLAND;REMBERG, GERD, LIEBIGS ANN. CHEM.,(1987) N 11, 971-975
  作者：TIETZE, LUTZ F.、FISCHER, ROLAND、REMBERG, GERD

  DOI：——

  日期：——
• Fungitoxic non-glycosidic iridoids from Alibertia macrophylla
  作者：M.Claudia M. Young、Marcia R. Braga、Sonia M.C. Dietrich、Hugo E. Gottlieb、Ligia M.V. Trevisan、Vanderlan Da S. Bolzani

  DOI：10.1016/0031-9422(92)83701-y

  日期：1992.10

  The aqueous alcohol extract of the leaves of Alibertia macrophylla afforded two epimeric pairs of iridoid aglycones and one of them showed high inhibitory activity against Aspergillus niger, Cladosporium sphaerospermum, C. cladosporioides and Colletotrichum gloesporioides. Three of the compounds are reported for the first time from natural sources. Their structures were established on the basis of spectroscopic studies, mainly through C-13 NMR analysis.