2,10-dimethylindeca-1,5E,9-triene | 152063-09-7

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 2,10-dimethylindeca-1,5E,9-triene
• 英文别名: (5E)-2,10-dimethylundeca-1,5,9-triene
• CAS: 152063-09-7
• 化学式: C₁₃H₂₂
• 分子量: 178.318
• InChiKey: KBCAPPRNOPECQT-AATRIKPKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2,10-dimethylindeca-1,5E,9-triene 在 aluminum isopropoxide 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 反应 4.0h， 生成 2,10-dimethylundeca-1,6E,10-trien-3-ol
  参考文献：
  名称：

  Synthesis and an attempt at electrophilic cyclization of some derivatives of 2,10-dimethylundeca-1,5,9-triene

  摘要：

  Terminally functionized terpenoids of the bis-norfarnesane series, stereoisomeric with respect to the centra double bond, were synthesized on the basis of 1,4-butynediol. Their electrophilic cyclization under the action of the complex Hg(OSO2CF3)2 . PhNMe2 led to a moderate yield of a mixture of monocyclic olefins.

  DOI：

  10.1007/bf01150742
• 作为产物：
  描述：

  (E)-6-Methyl-2,6-heptadien-1-ol 在 正丁基锂 、 氨 、 lithium 、 对甲苯磺酰氯 、 lithium chloride 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 反应 2.83h， 生成 2,10-dimethylindeca-1,5E,9-triene
  参考文献：
  名称：

  Synthesis and an attempt at electrophilic cyclization of some derivatives of 2,10-dimethylundeca-1,5,9-triene

  摘要：

  Terminally functionized terpenoids of the bis-norfarnesane series, stereoisomeric with respect to the centra double bond, were synthesized on the basis of 1,4-butynediol. Their electrophilic cyclization under the action of the complex Hg(OSO2CF3)2 . PhNMe2 led to a moderate yield of a mixture of monocyclic olefins.

  DOI：

  10.1007/bf01150742

文献信息

• Synthesis and an attempt at electrophilic cyclization of some derivatives of 2,10-dimethylundeca-1,5,9-triene
  作者：A. V. Lozanova、A. A. Surkova、A. M. Moiseenkov

  DOI：10.1007/bf01150742

  日期：1992.12

  Terminally functionized terpenoids of the bis-norfarnesane series, stereoisomeric with respect to the centra double bond, were synthesized on the basis of 1,4-butynediol. Their electrophilic cyclization under the action of the complex Hg(OSO2CF3)2 . PhNMe2 led to a moderate yield of a mixture of monocyclic olefins.