p-hydroxy isobutyl cinnamate | 1357473-49-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• 英文名称: p-hydroxy isobutyl cinnamate
• CAS: 1357473-49-4
• 化学式: C₁₃H₁₆O₃
• 分子量: 220.268
• InChiKey: UFKQSSIRCSDZPI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  16.0
• 可旋转键数：
  4.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  46.53
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  p-hydroxy isobutyl cinnamate 、 p-methoxycinnamoyl chloride 在 吡啶 作用下， 生成 4-(3-isobutoxy-3-oxoprop-1-en-1-yl)phenyl 3-(4-methoxyphenyl)acrylate
  参考文献：
  名称：

  Synthesis and Mesomorphism of Novel Liquid-Crystalline Isobutyl-p-(p′-n-Alkoxy Cinnamoyloxy) Cinnamates

  摘要：

  A new homologous series viz. Isobutyl-p-(p'-n-alkoxy cinnamoyloxy) cinnamates consisting of 11 homologs has been synthesized with an isobutyl cinnamate end group and a further cinnamate moiety as a linking group. The methyl to butyl homologs are nonmesomorphic, and the pentyl to hexadecyl derivatives are enantiotropic nematogens without exhibition of any smectic phases. The average thermal stability for the nematic phase is 138.1 degrees C with a middle ordered melting point. The structures of the novel materials were confirmed by spectroscopic techniques. The liquid crystal phase type was determined by optical polarizing microscopy and all textures are of the threaded type. The mesomorphic behavior of the series is compared with a structurally similar homologous series.

  DOI：

  10.1080/15421406.2011.591659
• 作为产物：
  描述：

  对羟基苯甲醛 在 哌啶 、 吡啶 、 硫酸 作用下， 生成 p-hydroxy isobutyl cinnamate
  参考文献：
  名称：

  Synthesis and Mesomorphism of Novel Liquid-Crystalline Isobutyl-p-(p′-n-Alkoxy Cinnamoyloxy) Cinnamates

  摘要：

  A new homologous series viz. Isobutyl-p-(p'-n-alkoxy cinnamoyloxy) cinnamates consisting of 11 homologs has been synthesized with an isobutyl cinnamate end group and a further cinnamate moiety as a linking group. The methyl to butyl homologs are nonmesomorphic, and the pentyl to hexadecyl derivatives are enantiotropic nematogens without exhibition of any smectic phases. The average thermal stability for the nematic phase is 138.1 degrees C with a middle ordered melting point. The structures of the novel materials were confirmed by spectroscopic techniques. The liquid crystal phase type was determined by optical polarizing microscopy and all textures are of the threaded type. The mesomorphic behavior of the series is compared with a structurally similar homologous series.

  DOI：

  10.1080/15421406.2011.591659

文献信息

• Synthesis and Mesomorphism of Novel Liquid-Crystalline Isobutyl-p-(p′-n-Alkoxy Cinnamoyloxy) Cinnamates
  作者：R. B. Patel、V. R. Patel、A. V. Doshi

  DOI：10.1080/15421406.2011.591659

  日期：2012.1.1

  A new homologous series viz. Isobutyl-p-(p'-n-alkoxy cinnamoyloxy) cinnamates consisting of 11 homologs has been synthesized with an isobutyl cinnamate end group and a further cinnamate moiety as a linking group. The methyl to butyl homologs are nonmesomorphic, and the pentyl to hexadecyl derivatives are enantiotropic nematogens without exhibition of any smectic phases. The average thermal stability for the nematic phase is 138.1 degrees C with a middle ordered melting point. The structures of the novel materials were confirmed by spectroscopic techniques. The liquid crystal phase type was determined by optical polarizing microscopy and all textures are of the threaded type. The mesomorphic behavior of the series is compared with a structurally similar homologous series.