A,2,2,3-四甲基环戊-3-烯-1-丁醛 | 65114-03-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 中文名称: A,2,2,3-四甲基环戊-3-烯-1-丁醛
• 英文名称: (-)-2-methyl-4-(2',2',3'-trimethyl-3'-cyclopenten-1'-yl)-butanal
• 英文别名: alpha,2,2,3-Tetramethylcyclopent-3-ene-1-butyraldehyde；2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)butanal
• CAS: 65114-03-6
• 化学式: C₁₃H₂₂O
• 分子量: 194.317
• InChiKey: QLWDKMHMOKIPHQ-UHFFFAOYSA-N

物化性质

• LogP：
  4.308 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  A,2,2,3-四甲基环戊-3-烯-1-丁醛 、 甲基锂 、 Sodium sulfate-III 、 水 在 乙醚 、 Brine 、 Sodium sulfate-III 作用下， 以 乙醚 为溶剂， 反应 4.0h， 以to yield 3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pentan-2-ol的产率得到檀香 210
  参考文献：
  名称：

  3-Methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pentan-2-ol compound and

  摘要：

  3-甲基-5-(2,2,3-三甲基环戊-3-烯-1-基)戊-2-醇具有强烈、珍贵的木质气味，让人联想到檀香油，尤其在香料组合中非常有价值。

  公开号：

  US04052341A1
• 作为产物：
  描述：

  2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-al 、 氢气 在 钯 作用下， 以 乙醇 为溶剂， 以to yield 2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)butanal的产率得到A,2,2,3-四甲基环戊-3-烯-1-丁醛
  参考文献：
  名称：

  3-Methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pentan-2-ol compound and

  摘要：

  3-甲基-5-(2,2,3-三甲基环戊-3-烯-1-基)戊-2-醇具有强烈、珍贵的木质气味，让人联想到檀香油，尤其在香料组合中非常有价值。

  公开号：

  US04052341A1

文献信息

• Dérivés hydroxylés de l'aldéhyde campholénique, leur utilisation à titre d'ingrédients parfumants et composition parfumante les contenant
  申请人：FIRMENICH SA

  公开号：EP0155591A2

  公开（公告）日：1985-09-25

  Les composés de formula dans laquelle: a. R1 = CH3; n=m=1; R2 = CH3; R3 = R4 = H, b. R1 = CH2; n=0; m=1; R2 = CH3; R3 = R4 = H, c. R1 = CH-CH3; n=0; m=1; R2 = CH3; R3 = R4 = H, d. R1 = H; n=m=0; R2 = R4 = CH3; R3 = C2H5, e. R1 = H; n=m=0; R2 = R3 = R4 = CH3, f. R1 = H; n=m=0; R2 = CH3; R3 = C2H5; R4 = H, g. R1 = H; n=m=0; R2 = R3 = CH3; R4 = H, h. R1 = H; n=m=1; R2 = CH3 R3 = C2H5; R4 = H i. R1 = H; n=m=1; R2 = R3 = CH3 ; R4 = H et dans laquelle l'une des lignes pointillées indique une liaison simple carbone-carbone et l'autre une liaison double, ou chacune des deux indique une liaison simple, possèdent des propriétés odorantes de type bois-santalé et, par conséquent, trouvent une utilisation pour la préparation des parfums et produits parfumés.

  式的化合物 其中 a.R1 = CH3; n=m=1; R2 = CH3; R3 = R4 = H、 b.R1 = CH2; n=0; m=1; R2 = CH3; R3 = R4 = H、 c.R1 = CH-CH3；n=0；m=1；R2 = CH3；R3 = R4 = H、 d.R1 = H; n=m=0; R2 = R4 = CH3; R3 = C2H5、 e.R1 = H; n=m=0; R2 = R3 = R4 = CH3、 f.R1 = H; n=m=0; R2 = CH3; R3 = C2H5; R4 = H、 g.R1 = H; n=m=0; R2 = R3 = CH3; R4 = H、 h.R1 = H; n=m=1; R2 = CH3 R3 = C2H5; R4 = H i.R1 = H; n=m=1; R2 = R3 = CH3; R4 = H 其中一条虚线表示碳-碳单键，另一条虚线表示碳-碳单键。 其中一条虚线表示碳-碳单键，另一条虚线表示双键，或者两条虚线都表示单键，具有檀香类型的芳香特性，因此可用于制备香水和香料产品。
• POLYALKOXY-POLYIMINE ADDUCTS FOR USE IN DELAYED RELEASE OF FRAGRANCE INGREDIENTS
  申请人：International Flavors & Fragrances Inc.

  公开号：EP3192566A1

  公开（公告）日：2017-07-19

  Disclosed is a fragrance adduct that is a reaction product between a polymeric amine and a reactive fragrance ingredient. The polymeric amine contains a backbone and at least one amino functional group, the reactive fragrance ingredient is an aldehyde, a ketone, an α,β-unsaturated electrophilic compound reactive towards the polymeric amine, or a combination thereof, and the reaction product is an imine compound or a Michael addition adduct. The fragrance adduct can be formulated into a fragrance composition, household product, personal care product, hair care product, or beauty care product. Also disclosed is a method for sequestering a fragrance using the fragrance adduct.

  本发明公开了一种香料加成物，它是聚合胺与活性香料成分的反应产物。聚合胺含有骨架和至少一个氨基官能团，反应性香料成分是醛、酮、对聚合胺有反应性的α,β-不饱和亲电化合物或它们的组合，反应产物是亚胺化合物或迈克尔加成加合物。该香料加合物可配制成香料组合物、家用产品、个人护理产品、护发产品或美容产品。此外，还公开了一种使用香料加合物封存香料的方法。
• Liquid laundry detergent compositions with silicone blends as fabric care agents
  申请人：Delplancke August Patrick Firmin

  公开号：US20050233938A1

  公开（公告）日：2005-10-20

  The invention is directed to aqueous liquid laundry detergent compositions for cleaning and imparting fabric care benefits to fabrics laundered therewith. Such compositions comprise (A) at least one detersive surfactant; (B) droplets of a silicone blend comprising a nitrogen-containing amino or ammonium functionalized polysiloxane and a nitrogen-free non-functionalized polysiloxane; and (C) at least one additional non-silicone laundry adjunct selected from detersive enzymes, dye transfer inhibiting agents, optical brighteners, suds suppressors and combinations thereof. The functionalized polysiloxane component of the silicone blend has a relatively low, i.e., less than 30 mol %, content of reactive/curable groups, a nitrogen content which ranges from 0.05% to 0.30% by weight and a viscosity which ranges from 0.00002 m 2 /s to 0.2 m 2 /s. The nitrogen-free non-functionalized polysiloxane material ranges in viscosity from 0.01 m 2 /sec to 2.0 m 2 /sec. The silicone blend is preferably used in a pre-formed emulsion which can be added to the balance of the detergent composition to form the droplets of the silicone blend which are dispersed in the detergent composition.

  本发明涉及水基液体洗衣粉组合物，用于清洁用其洗涤的织物并赋予织物护理功效。这种组合物包括：(A) 至少一种去污表面活性剂；(B) 由含氮氨基或铵官能化聚硅氧烷和不含氮的非官能化聚硅氧烷组成的有机硅混合物液滴；(C) 至少一种额外的非有机硅洗衣辅助剂，这些辅助剂选自去污酶、染料转移抑制剂、光学增白剂、泡沫抑制剂及其组合。有机硅混合物中的官能化聚硅氧烷组分具有相对较低的活性/固化基团含量，即小于 30 摩尔%，氮含量范围为 0.05% 至 0.30%（按重量计），粘度范围为 0.00002 m 2 /s 至 0.2 m 2 /s.无氮非官能化聚硅氧烷材料的粘度范围为 0.01 m 2 /秒至 2.0 米 2 /秒。硅氧烷混合物最好使用预制乳液，将其加入洗涤剂组合物的余量中，形成硅氧烷混合物液滴，分散在洗涤剂组合物中。
• PERFUMED LIQUID LAUNDRY DETERGENT COMPOSITIONS WITH FUNCTIONALIZED SILICONE FABRIC CARE AGENTS
  申请人：The Procter and Gamble Company

  公开号：EP1761620B1

  公开（公告）日：2009-07-29
• Perfumed liquid laundry detergent compositions with functionalized silicone fabric care agents
  申请人：Boutique Jean-Pol

  公开号：US20060003913A1

  公开（公告）日：2006-01-05

  The invention is directed to aqueous liquid laundry detergent compositions for cleaning and imparting fabric care benefits to fabrics laundered therewith and to methods for preparing such compositions. Such compositions comprise (A) at least one textile-cleaning surfactant; (B) droplets of miscible silicones comprising both a polarly-functionalized, preferably nitrogen-containing amino or ammonium functionalized, polysiloxane component and a nitrogen-free non-functionalized or non-polarly-functionalized polysiloxane component; and (C) a perfume component comprising fragrant aldehydes and/or ketones or a pro-perfume capable of providing such aldheyde and/or ketone perfume materials in situ. Incorporation of a polarly-functionalized polysiloxane fabric care agent into liquid laundry detergent compositions by miscibly combining it with a non-functionalized or non-polarly functionalized polysiloxane minimizes the undesirable interaction such polarly-functionalized silicone material might otherwise have with aldehyde and/or ketone perfume compounds.