DPSA 4-(2,2-二苯基乙烯基)-N,N-二苯基苯胺 | 89114-90-9

• 物质功能分类: 有机原料 - 氨基化合物 - 环烷胺、芳香单胺、芳香多胺及其衍生物和盐
• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: DPSA 4-(2,2-二苯基乙烯基)-N,N-二苯基苯胺
• 中文别名: DPSA4-(2,2-二苯基乙烯基)-N,N-二苯基苯胺；4-N,N-二甲氨基-B-苯基对称二苯代乙烯
• 英文名称: 4-(2,2-diphenylvinyl)-N,N-diphenylaniline
• 英文别名: α-phenyl-4'-N,N-diphenylaminostilbene；4'-diphenylamino-α-phenylstilbene；4-(2,2-diphenylethenyl)-N,N-diphenylaniline
• CAS: 89114-90-9
• 化学式: C₃₂H₂₅N
• 分子量: 423.557
• InChiKey: NIZIGUQDQIALBQ-UHFFFAOYSA-N

物化性质

• 熔点：
  100-101°C
• 沸点：
  558.8±29.0 °C(Predicted)
• 密度：
  1.143±0.06 g/cm3(Predicted)
• 溶解度：
  可溶于氯仿（轻微）、己烷（轻微、加热）

计算性质

• 辛醇/水分配系数(LogP)：
  9.3
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 安全说明：
  S61
• 危险类别码：
  R53

反应信息

• 作为产物：
  描述：

  二苯甲酮 、 P-[[4-(二苯基氨基)苯基]甲基]磷酸二乙酯 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 以60%的产率得到DPSA 4-(2,2-二苯基乙烯基)-N,N-二苯基苯胺
  参考文献：
  名称：

  基于二苯基乙烯基封端的苯乙烯胺衍生物的高效蓝光二极管

  摘要：

  在本文中，我们报道了用二苯基乙烯基封端的蓝色荧光苯乙烯胺衍生物的合成和电致发光性质。通过 HornerWadsworth-Emmons 反应合成了一系列新的苯乙烯胺衍生物。为了探索这些分子的电致发光特性，制造了具有ITO / NPB / 1-5掺杂在MADN / Bphen / Liq / Al中的多层有机发光器件。所有器件都表现出具有良好 EL 性能的蓝色发射。在本文报道的那些中，使用掺杂剂 5 的器件在 11.0 V 时表现出 24,000 cd/m 2 的最大亮度，在 20 mA/cm 2 时的发光效率为 12.5 cd/A，在 20 mA 时的功率效率为 6.50 lm/W /cm 2 和CIEx,y坐标（x = 0.173, y = 0.306）在8.0 V时，所有这些都证明了这些材料在蓝色OLED中的优越性。

  DOI：

  10.5012/bkcs.2010.31.02.389

文献信息

• Electrophotographic photoconductor, process for forming an image, image forming apparatus and a process cartridge for the same
  申请人：——

  公开号：US20030190540A1

  公开（公告）日：2003-10-09

  Providing an electrophotographic photoconductor comprising a conductive support and a photoconductive layer disposed on the photoconductive support; wherein the photoconductive layer contains an azo compound expressed by a general formula <<1>>. Ar &Parenopenst;N═N—Cp) n general formula <<1>> (in the general formula <<1>>, Ar expresses one of a substituted or non-substituted aromatic carbon hydride group and heterocyclic ring aromatic series group which can be combined by way of a bond group; Cp expresses a coupler residual group; n expresses an integer of one of 1, 2, 3, and 4; at least one of the Cp is a coupler residual group selected from one of the following general formulae <<2>>, <<3>>, and <<4>>.) 1

  提供一种电照相光导体，包括导电支持和设置在光导支承上的光导层；其中，所述光导层含有一种由下式表示的偶氮化合物。
• Aromatic Amine Compound, and Light-Emitting Element, Light-Emitting Device, and Electronic Device Using the Aromatic Amine Compound
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20130076237A1

  公开（公告）日：2013-03-28

  Novel aromatic amine compounds are provided. Light-emitting elements having high emission efficiency and high reliability are provided. Further, light-emitting devices and electronic devices using the light-emitting devices are provided. Specifically, an aromatic amine compound represented by the general formula (1), and light-emitting elements, light-emitting devices and electronic devices that are formed using the aromatic amine compound represented by the general formula (1) are provided. By using the aromatic amine compound represented by the general formula (1) for light-emitting elements, light-emitting devices and electronic devices, the light-emitting elements, light-emitting devices and electronic devices can have high emission efficiency.

  提供了新型芳香胺化合物。提供了具有高发射效率和高可靠性的发光元件。此外，提供了使用这些发光元件的发光器件和电子器件。具体来说，提供了一种由通用式（1）表示的芳香胺化合物，以及使用由通用式（1）表示的芳馥胺化合物形成的发光元件、发光器件和电子器件。通过在发光元件、发光器件和电子器件中使用由通用式（1）表示的芳馥胺化合物，可以实现这些发光元件、发光器件和电子器件具有高发射效率。
• Aromatic amine compound, and light emitting element, light emitting device, and electronic device using aromatic amine compound
  申请人：Nakashima Harue

  公开号：US20070096639A1

  公开（公告）日：2007-05-03

  An object is to provide an aromatic amine compound with excellent heat resistance. Another object is to provide a light emitting element, a light emitting device, and an electronic device with excellent heat resistance. An aromatic amine compound represented by General Formula (1) is provided. The aromatic amine compound represented by General Formula (1) has a high glass transition point and excellent heat resistance. By using the aromatic amine compound represented by General Formula (1) for a light emitting element, a light emitting device, and an electronic device, a light emitting element, a light emitting device, and an electronic device with excellent heat resistance can be obtained.

  提供一种具有优异耐热性的芳香胺化合物是一个目标。另一个目标是提供一个具有优异耐热性的发光元件、发光装置和电子设备。提供了由通用式（1）表示的芳香胺化合物。由通用式（1）表示的芳香胺化合物具有较高的玻璃转变温度和优异的耐热性。通过将由通用式（1）表示的芳香胺化合物用于发光元件、发光装置和电子设备，可以获得具有优异耐热性的发光元件、发光装置和电子设备。
• Phenanthroline derivative compound
  申请人：Nomura Ryoji

  公开号：US20070037983A1

  公开（公告）日：2007-02-15

  The present invention provides a novel phenanthroline derivative compound, and a manufacturing method thereof, and an electron transporting material, a light emitting element, a light emitting device, and an electronic device using the phenanthroline derivative compound. The phenanthroline derivative compound is characterized by being represented by General Formula 1. Note in General Formula 1 that Ar 1 represents an aryl group, and preferably a substituted or unsubstituted phenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted anthryl group, or a substituted or unsubstituted phenanthryl group. As an example of a preferable compound, there is TMPBP, NaBP, PBP, or the like. A light emitting element, a light emitting device, and an electronic device preferably contain the compound in a light emitting layer, and in that case, the compound is preferably utilized as a host.

  本发明提供了一种新颖的菲啰啉衍生物化合物及其制造方法，以及一种电子传输材料、发光元件、发光装置和使用该菲啰啉衍生物化合物的电子设备。该菲啰啉衍生物化合物的特征在于其由通用式1表示。请注意，在通用式1中，Ar1代表芳基，最好是取代或未取代的苯基、取代或未取代的萘基、取代或未取代的蒽基或取代或未取代的菲啰基。作为一种理想的化合物示例，有TMPBP、NaBP、PBP等。发光元件、发光装置和电子设备最好在发光层中含有该化合物，在这种情况下，该化合物最好用作宿主。
• Heterocyclic Compound, and Light-Emitting Element, Light-Emitting Device, Lighting Device, and Electronic Appliance Using Heterocyclic Compound
  申请人：NOMURA Hiroko

  公开号：US20100244672A1

  公开（公告）日：2010-09-30

  An object is to provide a novel heterocyclic compound having a bipolar property. Another object is to provide a light-emitting element, a light-emitting device, and an electronic appliance each having high emission efficiency. A heterocyclic compound represented by a general formula (G1), a light-emitting element, a light-emitting device, and an electronic appliance each formed using the heterocyclic compound represented by the general formula (G1) are provided. By use of the heterocyclic compound represented by the general formula (G1) to a light-emitting element, a light-emitting device, and an electronic appliance, the light-emitting element, the light-emitting device, and the electronic appliance can each have high emission efficiency.

  提供一种具有双极性质的新型杂环化合物是一个目标。另一个目标是提供具有高发射效率的发光元件、发光装置和电子器件。提供了由通式（G1）表示的杂环化合物、使用由通式（G1）表示的杂环化合物形成的发光元件、发光装置和电子器件。通过使用由通式（G1）表示的杂环化合物到发光元件、发光装置和电子器件中，可以使发光元件、发光装置和电子器件具有高发射效率。