(-)-α-fenchyl acetate | 69651-95-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (-)-α-fenchyl acetate
• 英文别名: exo-Fenchyl acetate；[(2R)-1,3,3-trimethyl-2-bicyclo[2.2.1]heptanyl] acetate
• CAS: 69651-95-2
• 化学式: C₁₂H₂₀O₂
• 分子量: 196.29
• InChiKey: JUWUWIGZUVEFQB-YZRBJQDESA-N

物化性质

• 保留指数：
  1214

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (-)-α-fenchyl acetate 在 chromium(VI) oxide 、 sodium tetrahydroborate 、 乙酸酐 、 溶剂黄146 作用下， 以 乙醇 为溶剂， 生成 endo-5-hydroxy-(-)-α-fenchyl acetate
  参考文献：
  名称：

  High potency dipeptide sweeteners. 1. L-Aspartyl-D-phenylglycine esters

  摘要：

  Twenty esters of L-aspartyl-D-phenylglycine, as well as two substituted analogues, an o-fluoro and a p-hydroxy-phenylglycine ester, were prepared. The L-aspartyl-D-phenylglycine (-)-alpha- and (+)-beta-fenchyl esters had the highest sweetness potency at 1200 and 3700 times that of sucrose, respectively. The high potency of these sweeteners is surprising as the phenyl group occupies a position previously believed to accommodate only much smaller groups.

  DOI：

  10.1021/jm00165a027

文献信息

• Compounds, Compositions, And Methods For Reducing Or Eliminating Bitter Taste
  申请人：Hayashi David

  公开号：US20130096209A1

  公开（公告）日：2013-04-18

  The present invention provides edible compositions comprising a compound of the present invention, food products comprising such edible compositions and methods of preparing such food products. The present invention also provides methods of reducing the amount of NaCl in a food product, methods of reducing the sodium intake in a diet, and methods of reducing bitter taste in a food product.
• COMPOUNDS, COMPOSITIONS, AND METHODS FOR REDUCING OR ELIMINATING BITTER TASTE
  申请人：CHROMOCELL CORPORATION

  公开号：US20150237900A1

  公开（公告）日：2015-08-27

  The present invention provides edible compositions comprising a compound of the present invention, food products comprising such edible compositions and methods of preparing such food products. The present invention also provides methods of reducing the amount of NaCl in a food product, methods of reducing the sodium intake in a diet, and methods of reducing bitter taste in a food product.
• US8865779B2
  申请人：——

  公开号：US8865779B2

  公开（公告）日：2014-10-21
• US9408407B2
  申请人：——

  公开号：US9408407B2

  公开（公告）日：2016-08-09
• US9872514B2
  申请人：——

  公开号：US9872514B2

  公开（公告）日：2018-01-23