(1S,2S,3R,4S,5S,6R)-4-[(2S,3R,4S,5S,6R)-4,5-Dimethoxy-6-methoxymethyl-3-((2S,3R,4R,5S,6S)-3,4,5-trimethoxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-5,6-dimethoxy-2-nitro-cyclohexane-1,3-diol | 95519-79-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (1S,2S,3R,4S,5S,6R)-4-[(2S,3R,4S,5S,6R)-4,5-Dimethoxy-6-methoxymethyl-3-((2S,3R,4R,5S,6S)-3,4,5-trimethoxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-5,6-dimethoxy-2-nitro-cyclohexane-1,3-diol
• CAS: 95519-79-2
• 化学式: C₂₆H₄₇NO₁₆
• 分子量: 629.656
• InChiKey: XSZLMSZVUVXSAD-CBNPYGKJSA-N

反应信息

• 作为反应物：
  描述：

  乙酸酐 、 (1S,2S,3R,4S,5S,6R)-4-[(2S,3R,4S,5S,6R)-4,5-Dimethoxy-6-methoxymethyl-3-((2S,3R,4R,5S,6S)-3,4,5-trimethoxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-5,6-dimethoxy-2-nitro-cyclohexane-1,3-diol 在 Raney Ni (T-4) 、 氢气 作用下， 生成 Acetic acid (1R,2S,3S,4R,5S,6S)-3-acetoxy-2-acetylamino-6-[(2S,3R,4S,5S,6R)-4,5-dimethoxy-6-methoxymethyl-3-((2S,3R,4R,5S,6S)-3,4,5-trimethoxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-4,5-dimethoxy-cyclohexyl ester
  参考文献：
  名称：

  Kitagawa, Isao; Kamigauchi, Toshiyuki; Ikeda, Yoshiharu, Chemical and pharmaceutical bulletin, 1984, vol. 32, # 12, p. 4858 - 4865

  摘要：

  DOI：
• 作为产物：
  描述：

  在 lead(IV) acetate 、 硝基甲烷 、 sodium methylate 作用下， 生成 (1S,2S,3R,4S,5S,6R)-4-[(2S,3R,4S,5S,6R)-4,5-Dimethoxy-6-methoxymethyl-3-((2S,3R,4R,5S,6S)-3,4,5-trimethoxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-5,6-dimethoxy-2-nitro-cyclohexane-1,3-diol 、 (3S,4S,6aR,6bS,8aR,9R,12aS,14bR)-9-Methoxy-4-methoxymethyl-4,6a,6b,8a,11,11,14b-heptamethyl-1,2,3,4,4a,5,6,6a,6b,7,8,8a,9,10,11,12,12a,14,14a,14b-icosahydro-picen-3-ol
  参考文献：
  名称：

  Kitagawa, Isao; Kamigauchi, Toshiyuki; Ikeda, Yoshiharu, Chemical and pharmaceutical bulletin, 1984, vol. 32, # 12, p. 4858 - 4865

  摘要：

  DOI：