(1S*,3R*,4S*,6R*,7R*,8R*,11Z)-6-benzyloxy-4,8-dihydroxy-11-capnosene-2,10-dione | 142750-42-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (1S*,3R*,4S*,6R*,7R*,8R*,11Z)-6-benzyloxy-4,8-dihydroxy-11-capnosene-2,10-dione
• CAS: 142750-42-3
• 化学式: C₂₇H₃₆O₆
• 分子量: 456.579
• InChiKey: CYOFYGQWRBZVNG-OYKKBPGRSA-N

反应信息

• 作为产物：
  描述：

  苯甲酰氯 、 1,2,4-甲桥戊搭烯-5-甲醛,八氢-,(1alpha,2alpha,3abeta,4alpha,5alpha,6aalpha,7R*)-(9CI) 在 吡啶 作用下， 反应 3.0h， 生成 (1S*,3R*,4S*,6R*,7R*,8R*,11Z)-6-benzyloxy-4,8-dihydroxy-11-capnosene-2,10-dione
  参考文献：
  名称：

  Tobacco Chemistry. 73. 4,6,8-Trihydroxy-11-Capnosene-2,10-dione, a Cembrane-Derived Bicyclic Diterpenoid from Tobacco.

  摘要：

  A new diterpenoid containing a rare carbobicyclic cembrane-derived skeleton, the capnosane skeleton, has been isolated from flowers of Greek tobacco. It has been identified as (1S*,3R*,4S*,6R*,7R*,8R*,11Z)-4,6,8-trihydroxy-11-capnosene-2,10-dione (1) by spectral methods and X-ray analysis of the corresponding benzoate (3). A full account of the X-ray work is given.

  DOI：

  10.3891/acta.chem.scand.46-0367