2-(((1R,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-3-ylselanyl)methyl)-2,3-dihydrobenzofuran | 1013022-41-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2-(((1R,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-3-ylselanyl)methyl)-2,3-dihydrobenzofuran
• CAS: 1013022-41-7
• 化学式: C₁₉H₂₆OSe
• 分子量: 349.375
• InChiKey: TXFHHTLIOVXSRB-JVFCCEQJSA-N

反应信息

• 作为产物：
  描述：

  、 2-烯丙基酚 在 甲醇 、 silver trifluoromethanesulfonate 作用下， 以 四氯化碳 、 二氯甲烷 为溶剂， 生成 2-(((1R,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-3-ylselanyl)methyl)-2,3-dihydrobenzofuran
  参考文献：
  名称：

  Asymmetric selenocyclization with the use of dialkyl monoterpene diselenides

  摘要：

  Selenocyclization with the use of the monoterpene diselenides from menthane, carane and pinane groups has been studied. The conditions for asymmetric selenocyclization have been optimized. It has been established that the best enantiomeric excesses were obtained in the case of selenocyclization for the unsubstituted alkyl diselenides with (+)-dineomenthyl diselenide. The results of the selenocyclization of the (+)-dineomenthyl diselenide with the unsaturated alcohols and acids are presented. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetasy.2007.11.032