{meso-tetrakis[4-(4-ethoxy-4-oxobutoxy)phenyl]porphyrinato}platinum | 1430405-71-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• 英文名称: {meso-tetrakis[4-(4-ethoxy-4-oxobutoxy)phenyl]porphyrinato}platinum
• CAS: 1430405-71-2
• 化学式: C₆₈H₆₈N₄O₁₂Pt
• 分子量: 1328.39
• InChiKey: URGYLIFHZCSQAN-HPOWWELSSA-N

反应信息

• 作为反应物：
  描述：

  {meso-tetrakis[4-(4-ethoxy-4-oxobutoxy)phenyl]porphyrinato}platinum 在 水 、 potassium hydroxide 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 24.0h， 生成
  参考文献：
  名称：

  Noble metal porphyrin derivatives bearing carboxylic groups: Synthesis, characterization and photophysical study

  摘要：

  The synthesis and characterization of meso-carboxyphenylporphyrins metallated with transition metals Pt, Pd, Rh, and Ru are described. The photophysical properties of the dyes were investigated by UV-Vis absorption, emission spectroscopy and cyclic voltammetry. Structures of platinum and palladium derivatives were elucidated by X-ray. The activity of the formed complexes as dyes for DSSCs was studied, however the performance is rather low compared to the reference dye N719. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.06.080
• 作为产物：
  描述：

  5,10,15,20-tetra-[4-(4-ethoxy-4-oxobutoxy)phenyl]-porphyrin 在 platinum(II) chloride 作用下， 以 苯甲腈 为溶剂， 反应 1.0h， 以96%的产率得到{meso-tetrakis[4-(4-ethoxy-4-oxobutoxy)phenyl]porphyrinato}platinum
  参考文献：
  名称：

  Noble metal porphyrin derivatives bearing carboxylic groups: Synthesis, characterization and photophysical study

  摘要：

  The synthesis and characterization of meso-carboxyphenylporphyrins metallated with transition metals Pt, Pd, Rh, and Ru are described. The photophysical properties of the dyes were investigated by UV-Vis absorption, emission spectroscopy and cyclic voltammetry. Structures of platinum and palladium derivatives were elucidated by X-ray. The activity of the formed complexes as dyes for DSSCs was studied, however the performance is rather low compared to the reference dye N719. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.06.080