3a,4,7,7a-Tetrahydro-1H-4,7-methano-inden-8-ol | 6899-49-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3a,4,7,7a-Tetrahydro-1H-4,7-methano-inden-8-ol
• 英文别名: Tricyclo[5.2.1.02,6]deca-3,8-dien-10-ol
• CAS: 6899-49-6
• 化学式: C₁₀H₁₂O
• 分子量: 148.205
• InChiKey: ZMWMEVMAQGRUER-UHFFFAOYSA-N

物化性质

• 沸点：
  259.3±40.0 °C(Predicted)
• 密度：
  1.204±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3a,4,7,7a-Tetrahydro-1H-4,7-methano-inden-8-ol 以 丙酮 为溶剂， 反应 120.0h， 以35%的产率得到anti-Octahydro-1,2,4-metheno-1H-cyclobutapentalen-3-ol
  参考文献：
  名称：

  Carbonylation and valence isomerization of 1,3-dihomocubane derivatives by chlorodicarbonylrhodium dimer

  摘要：

  DOI：

  10.1021/jo00180a004

文献信息

• DIRECT PHOTOPATTERNING OF ROBUST AND DIVERSE MATERIALS
  申请人：CALIFORNIA INSTITUTE OF TECHNOLOGY

  公开号：US20150118188A1

  公开（公告）日：2015-04-30

  The present invention relates to methods of metathesizing olefins using catalysts previously considered to be practically inactive. The present invention further relates to novel photosensitive compositions, their use as photoresists, and methods related to patterning polymer layers on substrates. Further, modifications to the compositions and method provide for an unprecedented functionalization of the compositions, useful for example in the preparation of sensors, drug delivery systems, and tissue scaffolds. The novel compositions and associated methods also provide for the opportunity to prepare 3-dimensional objects which provide new access to critically dimensioned devices, including for example photonic devices.