(6-phenoxy-pyridin-2-yl)-methanol | 68523-19-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (6-phenoxy-pyridin-2-yl)-methanol
• 英文别名: 6-Phenoxy-2-pyridinemethanol；6-phenoxypyrid-2-ylmethanol；2-hydroxymethyl-6-phenoxypyridine；6-phenoxy-α-picolyl alcohol；(6-phenoxy-2-pyridyl) methanol；(6-phenoxypyridin-2-yl)methanol
• CAS: 68523-19-3
• 化学式: C₁₂H₁₁NO₂
• 分子量: 201.225
• InChiKey: LGNROYCDLXXDRN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  42.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (6-phenoxy-pyridin-2-yl)-methanol 生成 2-{[2-(4-Ethoxyphenyl)-2-methylpropoxy]methyl}-6-phenoxypyridine
  参考文献：
  名称：

  ODA, KEHNGO;NAKATANI, KIESI;NUMADA, MASARU;SIRAISI, SIRO;DZITAGAVA, TAKAT+

  摘要：

  DOI：
• 作为产物：
  描述：

  methyl 6-phenoxy-picolinate 生成 (6-phenoxy-pyridin-2-yl)-methanol
  参考文献：
  名称：

  VAN, HEERTUM, J. C.;MALHOTRA, S. K.

  摘要：

  DOI：

文献信息

• Pyridyl esters and thiolesters of .alpha.-substituted unsaturated acids
  申请人：Zoecon Corporation

  公开号：US04248875A1

  公开（公告）日：1981-02-03

  Pyridyl esters and thiolesters of .alpha.-substituted unsaturated acids, intermediates therefor, synthesis thereof and the use of said esters and thiolesters and compositions for the control of pests.

  吡啶酯和硫酯是α-取代不饱和酸的中间体，其合成方法以及所述酯和硫酯的用途及用于控制害虫的组合物。
• Combating pests with novel phenoxypyridylmethyl esters
  申请人：Bayer Aktiengesellschaft

  公开号：US04491585A1

  公开（公告）日：1985-01-01

  New phenoxypyridylmethyl esters of the general formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 have the meaning given in the description and R represents the radical ##STR2## wherein R.sup.4 and R.sup.5 have the meaning given in the description, and represents the radical ##STR3## wherein R.sup.6 and R.sup.7 have the meaning given in the description, are obtained by a process in which carboxylic acids of the general formula R--COOH (II) wherein R has the meaning given previously, or reactive derivatives of these acids, are reacted with phenoxypyridyl alcohols of the general formula ##STR4## wherein R.sup.1, R.sup.2 and R.sup.3 have the meaning given above, or with reactive derivatives of these alcohols, if appropriate in the presence of acid acceptors, if appropriate in the presence of catalysts and if appropriate in the presence of diluents. The new phenoxypyridylmethyl esters of the formula (I) are distinguished by a high pesticidal, particularly insecticidal and acardicidal activity.

  通式为##STR1##的新苯氧吡啶基甲酯，其中R.sup.1、R.sup.2和R.sup.3的含义如描述中所述，R代表基团##STR2##其中R.sup.4和R.sup.5的含义如描述中所述，并代表基团##STR3##其中R.sup.6和R.sup.7的含义如描述中所述，通过以下过程获得：将通式为R--COOH（II）的羧酸（其中R的含义如前述）或这些酸的反应衍生物与通式为##STR4##的苯氧吡啶醇（其中R.sup.1、R.sup.2和R.sup.3的含义如上所述）或这些醇的反应衍生物反应，如适当时在酸受体的存在下，如适当时在催化剂的存在下，如适当时在稀释剂的存在下。通式（I）的新苯氧吡啶基甲酯具有高杀虫活性，特别是对昆虫和蜱类有杀灭作用。
• Insecticidal alkenes
  申请人：Imperial Chemical Industries PLC

  公开号：US04812483A1

  公开（公告）日：1989-03-14

  A compound of formula: CXY.dbd.CH--CR.sup.1 R.sup.2 --CH.sub.2 OCH.sub.2 R wherein X and Y are each selected from hydrogen and halogen, R.sup.1 and R.sup.2 are each lower alkyl of up to four carbon atoms, or together with the adjacent carbon atom form a cycloalkyl group of up to six carbon atoms, and R represents a phenoxy- or benzyl-substituted phenyl group which may optionally be substituted with fluorine. The compounds are useful for combating insect pests.

  一种化合物的化学式为：CXY.dbd.CH--CR.sup.1 R.sup.2 --CH.sub.2 OCH.sub.2 R，其中X和Y分别选自氢和卤素，R.sup.1和R.sup.2分别是最多含有四个碳原子的低碳烷基，或者与相邻的碳原子一起形成最多含有六个碳原子的环烷基，R代表一个苯氧基或苄基取代的苯基，该苯基可选择性地取代氟。这些化合物可用于对抗昆虫害。
• Insecticidal ethers
  申请人：Imperial Chemical Industries PLC

  公开号：US04792563A1

  公开（公告）日：1988-12-20

  Insecticidally active compounds of the formula (I): ##STR1## wherein R.sup.4 represents a group selected from those groups represented by R.sup.5 in insecticidally active compounds of formula: ##STR2## R.sup.3 is selected from fluoromethyl and difluoromethyl, and either (a) R.sup.1 and R.sup.2 represent alkyl of one, two, three or four carbon atoms, or (b) R.sup.1 and R.sup.2 taken together with the adjacent carbon atom form a cycloalkyl ring of four, five or six carbon atoms.

  化学式(I)的杀虫活性化合物：其中R.sup.4代表从公式中由R.sup.5代表的那些基团中选择的一个基团。R.sup.3从氟甲基和二氟甲基中选择，且要么(a) R.sup.1和R.sup.2代表碳原子数为一、二、三或四的烷基，要么(b) R.sup.1和R.sup.2与相邻的碳原子一起形成四、五或六个碳原子的环烷基环。
• Cyclic dipeptide enantiomers
  申请人：ICI AUSTRALIA LIMITED

  公开号：EP0304954A2

  公开（公告）日：1989-03-01

  The invention provides novel cyclic dipeptide enantiomers comprising (R)-histidine or a derivative thereof as one of the amino acid residues. These compounds are useful a catalysts for production of (S) -α-­cyanomethyl alcohols from aldehydes.

  本发明提供了一种新颖的环二肽对映体，其中包括(R)-组氨酸或其衍生物作为其中一种氨基酸残基。这些化合物可用作催化剂，用于从醛类产生(S)-α-氰甲基醇。