1,7-Bis(prop-2-enyl)pentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione | 905458-74-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 1,7-Bis(prop-2-enyl)pentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione
• 英文别名: 1,7-bis(prop-2-enyl)pentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione
• CAS: 905458-74-4
• 化学式: C₁₇H₁₈O₂
• 分子量: 254.329
• InChiKey: QHQMYNSUYODECT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,7-Bis(prop-2-enyl)pentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione 以 二苯醚 为溶剂， 以43%的产率得到
  参考文献：
  名称：

  Strategic utilization of catalytic metathesis and photo-thermal metathesis in caged polycyclic frames

  摘要：

  Highly functionalized cage compounds have been prepared via cross-metathesis (CM) using Grubbs modified N-tolyol catalyst 7. A strategic utilization of photo-thermal metathesis and catalytic metathesis sequence for the synthesis of functionalized caged molecules has been demonstrated. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.02.131

文献信息

• Strategic utilization of catalytic metathesis and photo-thermal metathesis in caged polycyclic frames
  作者：Sambasivarao Kotha、Vittal Seema、Kuldeep Singh、Kodand Dinkar Deodhar

  DOI：10.1016/j.tetlet.2010.02.131

  日期：2010.4

  Highly functionalized cage compounds have been prepared via cross-metathesis (CM) using Grubbs modified N-tolyol catalyst 7. A strategic utilization of photo-thermal metathesis and catalytic metathesis sequence for the synthesis of functionalized caged molecules has been demonstrated. (C) 2010 Elsevier Ltd. All rights reserved.