dithiocarbonic acid S-methyl ester-O-thujan-3-yl ester | 54825-97-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: dithiocarbonic acid S-methyl ester-O-thujan-3-yl ester
• 英文别名: Dithiokohlensaeure-S-methylester-O-thujan-3-ylester；O-(4-methyl-1-propan-2-yl-3-bicyclo[3.1.0]hexanyl) methylsulfanylmethanethioate
• CAS: 54825-97-7
• 化学式: C₁₂H₂₀OS₂
• 分子量: 244.422
• InChiKey: OYDNKPDBNXJYJJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  66.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  dithiocarbonic acid S-methyl ester-O-thujan-3-yl ester 生成 (-)-alpha-侧柏烯
  参考文献：
  名称：

  Tschugajew; Fomin, Chemische Berichte, 1912, vol. 45, p. 1295

  摘要：

  DOI：
• 作为产物：
  描述：

  蒽紫红素 生成 dithiocarbonic acid S-methyl ester-O-thujan-3-yl ester
  参考文献：
  名称：

  Tschugajew; Fomin, Chemische Berichte, 1912, vol. 45, p. 1295

  摘要：

  DOI：

文献信息

• Tschugajew, Chemische Berichte, 1904, vol. 37, p. 1480
  作者：Tschugajew

  DOI：——

  日期：——
• Methylmercury and total mercury in estuarine organisms from Rio de Janeiro, Brazil
  作者：Helena do A. Kehrig、Monica Costa、Isabel Moreira、Olaf Malm

  DOI：10.1007/bf02987407

  日期：2001.7

  Guanabara Bay (GB), located in the Rio de Janeiro State, is still a productive estuary on the south-eastern Brazilian coast. It is an ecosystem heavily impacted by organic matter, oil and a number of other toxic compounds, including Hg. The present study aimed to comparatively evaluate the aquatic total mercury (THg) and MeHg contamination, and the ratios of MeHg to THg (% MeHg), in 3 species of marine organisms, Micropogonias furnieri-carnivorous fish (N=81), Mugil spp. - detritivorous fish (N=20) and Perna perna- filter-feeding bivalves (N=190), which are widely consumed by the population. A total of 291 specimens were collected at the bay in different periods between 1988 and 1998. THg concentrations were determined by cold vapour AAS with stannous chloride as a reducing agent. MeHg was extracted by dithizone-benzene and measured by GC-ECD. Analytical quality was checked through certified standards. All organisms presented both low THg and MeHg concentrations and they were below the maximum limit of 1,000 mug Hg(.)kg(-1) wet wt. as established for human intake of predatory fish by the new Brazilian legislation. Carnivorous fish showed higher THg and MeHg concentrations, and also % MeHg in muscle tissues, than organisms with other feeding habits and lower trophic levels. The average of THg concentrations in carnivorous fish was 108.9 +/- 58.6 mug(.)kg(-1) wet wt. (N=61) in 1990 and 199.5 +/- 116.2 mug(.)kg(-1) wet wt. (N=20) in 1998, but they presented different total length and body weights. The average THg content in detritivorous fish was 15.4 +/-5.8 mug(.)kg(-1) wet wt., whereas THg concentrations ranged from 4.1 to 53.5 mug(.)kg(-1) wet wt. for the molluscs. The THg and MeHg contents of mussel varied according to the sampling point and water quality. MeHg concentration in detritivorous fish was similar to MeHg concentration in molluscs, but there was a significant difference in the MeHg/THg ratio: the carnivorous fish presented higher MeHg percentages (98 %) than the detritivorous fish (54%) and the molluscs (33%). Weight-normalised average concentration of THg in carnivorous fish collected in 1990 (0.18 0.08 mug(.)g(-1)/0.7 kg wet wt.) and in 1998 (0.16 +/-0.09 mug(.)g(-1)/0.7 kg wet wt.) presented no significant difference (t=1.34; P <0.5). In conclusion, the low THg and MeHg concentrations in the organisms from the GB ecosystem, are related to its eutrophic conditions and elevated amounts of suspended matter. In this situation, Hg could be strongly complexed or adsorbed by the particulate, which would dilute the Hg inputs and reduce its residence time in the water column, with a consequent decrease in its availability to organisms.
• Kondakow; Skworzow, Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1910, vol. 42, p. 504
  作者：Kondakow、Skworzow

  DOI：——

  日期：——
• Tschugajew, Untersuchungen auf dem Gebiet der Terpene und Campher <Moskau 1903>, S. 146
  作者：Tschugajew

  DOI：——

  日期：——
• Tschugajew, Chemische Berichte, 1900, vol. 33, p. 3120
  作者：Tschugajew

  DOI：——

  日期：——