trichinolobenzene | 778541-87-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: trichinolobenzene
• 英文别名: 3,13,23-Triazaheptacyclo[20.8.0.02,11.04,9.012,21.014,19.024,29]triaconta-1,4,6,8,11,14,16,18,21,24,26,28-dodecaene-10,20,30-trione
• CAS: 778541-87-0；128807-20-5
• 化学式: C₂₇H₁₅N₃O₃
• 分子量: 429.434
• InChiKey: ZBLYWYCAUIBZHS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  33
• 可旋转键数：
  0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  87.3
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  [Pt2Cl2(μ-Cl)2(P(n-Bu)3)2] 、 trichinolobenzene 、 sodium hydride 以 四氢呋喃 为溶剂， 以60%的产率得到{(nBu3P)(Cl)Pt}3(trichinolobenzene-3H+)
  参考文献：
  名称：

  Lenz, Andreas; Polborn, Kurt; Beck, Wolfgang, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1994, vol. 49, # 7, p. 955 - 957

  摘要：

  DOI：
• 作为产物：
  描述：

  1,3,5-tris(2-carboxyanilino)benzene 以100%的产率得到
  参考文献：
  名称：

  CORDON, MICHAEL D.;JAFFE, EDWARD E.;FORIS, ANTHONY, DYES AND PIGM., 12,(1990) N, C. 301-305

  摘要：

  DOI：

文献信息

• ORGANIC ELECTROLUMINESCENCE ELEMENT
  申请人：Kyushu University, National University Corporation

  公开号：EP3843167A1

  公开（公告）日：2021-06-30

  An organic electroluminescent device having an anode, a cathode, and a light-emitting layer between the anode and the cathode, wherein the light-emitting layer contains at least a first organic compound, a second organic compound and a third organic compound satisfying the following formula (A), the second organic compound is a delayed fluorescent material, and the third organic compound is a light-emitting material, has a high light emission efficiency. Formula (A): ES1(A) > ES1(B) > ES1(C) wherein ES1(A), ES1(B) and ES1(C) each represent a lowest excited singlet energy level of the first organic compound, the second organic compound and the third organic compound, respectively.

  一种有机电致发光器件，具有阳极、阴极和位于阳极与阴极之间的发光层，其中发光层至少含有满足下式（A）的第一有机化合物、第二有机化合物和第三有机化合物，第二有机化合物是一种延迟荧光材料，第三有机化合物是一种发光材料，具有较高的发光效率。式（A）：ES1(A)>ES1(B)>ES1(C) 其中 ES1(A)、ES1(B) 和 ES1(C) 分别代表第一种有机化合物、第二种有机化合物和第三种有机化合物的最低激发单线能级。
• HOST MATERIAL, COMPOSITION, AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Kyulux, Inc.

  公开号：EP4102588A1

  公开（公告）日：2022-12-14

  To improve the emission efficiency, the driving voltage and the lifetime of an organic light-emitting device using a delayed fluorescent material. A host material for a delayed fluorescent material, containing a compound represented by the following general formula: R1 to R5 each are a substituent not containing a cyano group, n1 to n5 each are 0 to 4, Ar is a monocyclic arylene group or a monocyclic heteroarylene group.

  提高使用延迟荧光材料的有机发光器件的发射效率、驱动电压和寿命。一种延迟荧光材料的主材料，含有由以下通式表示的化合物：R1 至 R5 各为不含氰基的取代基，n1 至 n5 各为 0 至 4，Ar 为单环芳基或单环杂芳基。
• COMPOSITION, FILM, ORGANIC LIGHT EMITTING ELEMENT, METHOD FOR PROVIDING LIGHT EMITTING COMPOSITION, AND PROGRAM
  申请人：Kyulux, Inc.

  公开号：EP4102587A1

  公开（公告）日：2022-12-14

  An organic light emitting element produced by using a light emitting composition that contains both a first compound having a PBHT value more than 0.730 and a second compound having Esi lower than that of the first compound and ΔEST less than 0.20 eV is excellent in durability. Esi is the lowest excited singlet energy level, ΔEST is the difference between the lowest excited singlet energy level and the lowest excited triplet energy level.

  使用同时含有 PBHT 值大于 0.730 的第一种化合物和 Esi 低于第一种化合物且 ΔEST 小于 0.20 eV 的第二种化合物的发光组合物生产的有机发光元件具有优异的耐久性。Esi 是最低激发单电子能级，ΔEST 是最低激发单电子能级与最低激发三电子能级之差。
• Organic light-emitting element, and light-emitting material and fluorescent body used in same
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

  公开号：US11322693B2

  公开（公告）日：2022-05-03

  Disclosed is an organic light-emitting device using a compound capable of emitting delayed fluorescence and capable of undergoing intramolecular hydron transfer. The compound includes, for example, a compound represented by the general formula. X1 to X3 each represent O or S; R1 to R6 each represent nH or a substituent; n, n1 to n3 each represent an integer of 1 to 3.

  本发明公开了一种有机发光器件，该器件使用了一种能够发射延迟荧光并能进行分子内氢子转移的化合物。例如，该化合物包括由通式表示的化合物。X1至X3各自代表O或S；R1至R6各自代表nH或取代基；n、n1至n3各自代表1至3的整数。
• ORGANIC LIGHT-EMITTING ELEMENT, AND LIGHT-EMITTING MATERIAL AND FLUORESCENT BODY USED IN SAME
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

  公开号：US20190348617A1

  公开（公告）日：2019-11-14

  Disclosed is an organic light-emitting device using a compound capable of emitting delayed fluorescence and capable of undergoing intramolecular hydron transfer. The compound includes, for example, a compound represented by the general formula. X 1 to X 3 each represent O or S; R 1 to R 6 each represent n H or a substituent; n, n1 to n3 each represent an integer of 1 to 3.