Undeca-4,6-diyne | 110999-07-0

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: Undeca-4,6-diyne
• 英文别名: 4,6-undecadiyne
• CAS: 110999-07-0
• 化学式: C₁₁H₁₆
• 分子量: 148.248
• InChiKey: WWHVOHSWJLQNFB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Undeca-4,6-diyne 在 N-lithiodiaminoethane 作用下， 以 正己烷 、 乙二胺 、 苯 为溶剂， 反应 0.17h， 以75.7%的产率得到1,3-undecadiyne
  参考文献：
  名称：

  Remizova, L. A.; Balova, I. A.; Favorskaya, I. A., Journal of Organic Chemistry USSR (English Translation), 1986, vol. 22, # 11, p. 2209 - 2210

  摘要：

  DOI：
• 作为产物：
  描述：

  2-heptynoic acid chloride 在 正丁基锂 作用下， 反应 3.5h， 生成 Undeca-4,6-diyne
  参考文献：
  名称：

  Flash vacuum pyrolysis of stabilised phosphorus ylides. Part 8. Preparation of symmetrical and unsymmetrical 1,3-diynes from alkynoyl ylides and oxalyl diylides

  摘要：

  Seven examples of the alkynoyl phosphorus ylides 5 have been prepared and are found, upon flash vacuum pyrolysis (FVP) at 750 degrees C, to undergo extrusion of Ph(3)PO to give the unsymmetrical 1,3-diynes 9 in moderate yield. Six examples of the oxalyl diylides 6 have been prepared and their fully assigned C-13 NMR spectra are presented. Upon FVP, those with R = aryl undergo two-fold extrusion of Ph(3)PO to give symmetrical 1,3-diynes 13 but this requires the unusually severe temperature of 900 degrees C. In contrast those with R = CO(2)Me, CO(2)Et or COPh undergo complete reaction at 500 degrees C but afford only Ph(3)PO and fragmentation products.

  DOI：

  10.1039/p19960000485

文献信息

• Balowa I. A., Remisowa L. A., Zh. organ. khimii, 30 (1994) N 2, S 207-209
  作者：Balowa I. A., Remisowa L. A.

  DOI：——

  日期：——
• REMIZOVA L. A.; BALOVA I. A.; FAVORSKAYA I. A., ZH. ORGAN. XIMII, 22,(1986) N 11, 2459-2460
  作者：REMIZOVA L. A.、 BALOVA I. A.、 FAVORSKAYA I. A.

  DOI：——

  日期：——
• Flash vacuum pyrolysis of stabilised phosphorus ylides. Part 8. Preparation of symmetrical and unsymmetrical 1,3-diynes from alkynoyl ylides and oxalyl diylides
  作者：R. Alan Aitken、Hugues Hérion、Caroline E. R. Horsburgh、Nazira Karodia、Shirley Seth

  DOI：10.1039/p19960000485

  日期：——

  Seven examples of the alkynoyl phosphorus ylides 5 have been prepared and are found, upon flash vacuum pyrolysis (FVP) at 750 degrees C, to undergo extrusion of Ph(3)PO to give the unsymmetrical 1,3-diynes 9 in moderate yield. Six examples of the oxalyl diylides 6 have been prepared and their fully assigned C-13 NMR spectra are presented. Upon FVP, those with R = aryl undergo two-fold extrusion of Ph(3)PO to give symmetrical 1,3-diynes 13 but this requires the unusually severe temperature of 900 degrees C. In contrast those with R = CO(2)Me, CO(2)Et or COPh undergo complete reaction at 500 degrees C but afford only Ph(3)PO and fragmentation products.
• Remizova, L. A.; Balova, I. A.; Favorskaya, I. A., Journal of Organic Chemistry USSR (English Translation), 1986, vol. 22, # 11, p. 2209 - 2210
  作者：Remizova, L. A.、Balova, I. A.、Favorskaya, I. A.

  DOI：——

  日期：——