A fast and selective decarboxylative difunctionalization and cyclization for easy access to gem-dihalo alcohol, ether, ester and bromo-1,4-dioxane
作者:Saikat Khamarui、Deblina Sarkar、Palash Pandit、Dilip K. Maiti
DOI:10.1039/c1cc16126a
日期:——
A general strategy for fast decarboxylative difunctionalization to gem-dihalohydrin, gem-dihaloether, gem-dibromoester and cyclized bromo-1,4-dioxane synthons with outstanding regio- and stereoselectivity is demonstrated.
展示了一种通用的策略,能够快速进行去羧基二功能化反应,生成高区域选择性和立体选择性的双卤醇、双卤醚、双溴酯和环化的溴代1,4-二氧六环前体。