| 1400906-89-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1400906-89-9
• 化学式: C₃₄H₃₃ClO₅S
• 分子量: 589.152
• InChiKey: IQPAQIHMDIKXKP-LYKQQZMYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.33
• 重原子数：
  41.0
• 可旋转键数：
  12.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  53.99
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  在 copper acetylacetonate 作用下， 以 甲醇 、 乙醚 、 甲苯 为溶剂， 反应 1.08h， 生成 1-p-tolyl-2,3,4-tri-O-benzyl-7-methyl-1-thio-β-D-glucoheptopyrano-6-ulose
  参考文献：
  名称：

  Study on Metal-Induced Reactions of α-Diazocarbonyl Glucosides

  摘要：

  Conversions of diazocarbonyl carbohydrate compounds catalyzed by a series of rhodium and copper catalysts in conventional heating or microwave conditions were investigated. C-H insertion product was obtained in the presence of Rh-2(OAc)(4). Intermolecular reactions rather than intramolecular reactions occurred in the presence of copper catalysts.

  DOI：

  10.1021/jo300986c
• 作为产物：
  描述：

  1-p-tolyl-2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranuronic acid 在 2,6-二甲基吡啶 、 草酰氯 作用下， 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Study on Metal-Induced Reactions of α-Diazocarbonyl Glucosides

  摘要：

  Conversions of diazocarbonyl carbohydrate compounds catalyzed by a series of rhodium and copper catalysts in conventional heating or microwave conditions were investigated. C-H insertion product was obtained in the presence of Rh-2(OAc)(4). Intermolecular reactions rather than intramolecular reactions occurred in the presence of copper catalysts.

  DOI：

  10.1021/jo300986c