5-(2¹-oxapent-4-enyl)-bicyclo<2.2.1>-2-heptene | 3188-73-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-(2¹-oxapent-4-enyl)-bicyclo<2.2.1>-2-heptene
• 英文别名: 5-allyloxymethylbicyclo[2.2.1]hept-2-ene；5-(Prop-2-enoxymethyl)bicyclo[2.2.1]hept-2-ene
• CAS: 3188-73-6
• 化学式: C₁₁H₁₆O
• 分子量: 164.247
• InChiKey: CNGRZRZYHPYQMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  5-(2¹-oxapent-4-enyl)-bicyclo<2.2.1>-2-heptene 在 硼烷四氢呋喃络合物 、 2-甲基-丁烯 、 sodium hydroxide 、 双氧水 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 4.0h， 以87%的产率得到3-(bicyclo[2.2.1]hept-5-en-2-ylmethoxy)propan-1-ol
  参考文献：
  名称：

  Oxidative Cyclorelease from Soluble Polymeric Supports

  摘要：

  Single electron oxidation is shown to be a viable method for effecting concomitant cyclization and cleavage (cyclorelease) of a series of polymer bound homobenzylic ethers. Soluble oligonorbornene polymers are stable toward redox chemistry and are isolable through precipitation with methanol, making them excellent supports for this process. These oxidative conditions are also shown to cleave secondary and tertiary alcohols and ethers in a new traceless approach to polymer-supported aldehyde and ketone synthesis.

  DOI：

  10.1021/jo0480951
• 作为产物：
  描述：

  3-溴丙烯 、 5-降冰片烯-2-甲醇 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以100%的产率得到5-(2¹-oxapent-4-enyl)-bicyclo<2.2.1>-2-heptene
  参考文献：
  名称：

  Oxidative Cyclorelease from Soluble Polymeric Supports

  摘要：

  Single electron oxidation is shown to be a viable method for effecting concomitant cyclization and cleavage (cyclorelease) of a series of polymer bound homobenzylic ethers. Soluble oligonorbornene polymers are stable toward redox chemistry and are isolable through precipitation with methanol, making them excellent supports for this process. These oxidative conditions are also shown to cleave secondary and tertiary alcohols and ethers in a new traceless approach to polymer-supported aldehyde and ketone synthesis.

  DOI：

  10.1021/jo0480951

文献信息

• POLYMERIZABLE COMPOSITIONS AND MOLDED ARTICLES PRODUCED BY USING THE SAME
  申请人：ZEON CORPORATION

  公开号：EP1655321A1

  公开（公告）日：2006-05-10

  The present invention provides a polymerizable composition and a resin formed object capable of providing a crosslinked cycloolefin resin formed object and a crosslinked cycloolefin resin composite excellent in heat resistance, more specifically, a polymerizable composition comprising a cycloolefin mixture containing 0.1 to 50% by mole of a cycloolefin having, as a substituent group, a monovalent group including an aliphatic carbon-carbon unsaturated bond, a metathesis polymerization catalyst, and a radical generating agent; and formed objects produced by using a polymerizable composition described above which preferably further comprises a chain transfer agent and making the cycloolefin mixture undergo at least ring-opening polymerization.

  本发明提供了一种可聚合组合物和一种树脂成型物，能够提供一种交联环烯烃树脂成型物和一种耐热性优异的交联环烯烃树脂复合材料，更具体地说，一种可聚合组合物包括一种环烯烃混合物，该环烯烃混合物含有0.1至50%（以摩尔计）的环烯烃混合物，其取代基为包括脂肪族碳-碳不饱和键的单价基团、偏聚合催化剂和自由基生成剂；以及通过使用上述可聚合组合物生产的成型物体，该组合物最好进一步包含链转移剂，并使环烯烃混合物至少进行开环聚合。
• Cp2ZrCl2-catalyzed hydroalumination of norbornene derivatives withi-Bu2AlCl
  作者：A. G. Ibragimov、D. L. Minsker、A. A. Berg、O. V. Shitikova、S. I. Lomakina、U. M. Dzhemilev

  DOI：10.1007/bf01150750

  日期：1992.12

  Cp2ZrCl2-catalyzed (Cp = eta5-C5H5) hydroalumination of substituted norbornenes with i-Bu2AlCl was conducted, yielding higher cycloalkylhaloalanes with high yields.
• LOPATIK D. V.; OSIPENKO I. F.; PROKOPOVICH I. P.; BULATSKAYA N. G., REDKOL. ZH. IZV. AN BSSR. CEP. XIM. N. MINSK, 1980, 9 S., BIBLIOGR. 7 NAZ+
  作者：LOPATIK D. V.、 OSIPENKO I. F.、 PROKOPOVICH I. P.、 BULATSKAYA N. G.

  DOI：——

  日期：——
• Polymerizable composition and molded articles produced by using the same
  申请人：Sugawara Tomoo

  公开号：US20060258828A1

  公开（公告）日：2006-11-16

  The present invention provides a polymerizable composition and a resin formed object capable of providing a crosslinked cycloolefin formed object and a crosslinked cycloolefin resin composite excellent in heat resistance, more specifically, a polymerizable composition comprising a cycloolefin mixture containing 0.1 to 50% by mole of a cycloolefin having, as a substituent group, a monovalent group including an aliphatic carbon-carbon unsaturated bond, a metathesis polymerization catalyst, and a radical generating agent; and formed objects produced by using a polymerizable composition described above which preferably further comprises a chain transfer agent and making the cycloolefin mixture undergo at least ring-opening polymerization.
• US7381782B2
  申请人：——

  公开号：US7381782B2

  公开（公告）日：2008-06-03