[Cu(5,6-dimethyl-1,10-phenanthroline)(salicylaldehydate)]NO3 | 229622-28-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [Cu(5,6-dimethyl-1,10-phenanthroline)(salicylaldehydate)]NO3
• 英文别名: (5,6-Dimethyl-1,10-phenanthroline-N,N')(nitrato-O)(salicylaldehydato-O,O) copper(II)；copper;5,6-dimethyl-1,10-phenanthroline;2-formylphenolate;nitrate
• CAS: 229622-28-0
• 化学式: C₇H₅O₂*C₁₄H₁₂N₂*Cu*NO₃
• 分子量: 454.929
• InChiKey: GZNZBUQVROQSDO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.73
• 重原子数：
  30
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  129
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  水杨醛 、 5,6-二甲基-1,10-菲咯啉 、 copper(II) nitrate trihydrate 在 氨 作用下， 以 乙醇 、 水 为溶剂， 生成 [Cu(5,6-dimethyl-1,10-phenanthroline)(salicylaldehydate)]NO3
  参考文献：
  名称：

  Cu–O stretching frequency correlation with phenanthroline pKa values in mixed copper complexes

  摘要：

  A study of Cu-O vibration frequencies in 32 isostructural mixed copper complexes containing eight differently substituted phenanthrolines and four different oxygen donor bidentate ligands, is presented. In all cases linear correlation was found between phenanthroline pK(a) values and the studied vibration frequencies, suggesting that an increase in phenanthroline basicity weakens Cu-O bonds in this type of compound. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00034-1

文献信息

• (5,6-Dimethyl-1,10-phenanthroline)(nitrato)(salicylaldehydato)copper(II)
  作者：L. Gasque、R. Moreno-Esparza、L. Ruiz-Ramírez、G. Medina-Dickinson

  DOI：10.1107/s0108270199001018

  日期：1999.7.15

  The Cu-II ion of the title complex, (5,6-dimethyl-1,10-phenanthroline-N, N')(2-formylphenolato-O,O')(nitrato-O)copper(II), [Cu(C7H5O2)(NO3)(C14H12N2)], displays a slightly distorted square-pyramidal coordination site, where one O atom from the nitrate ion is coordinated in the apical position [at 2.239 (2) Angstrom], and both O atoms from the salicylaldehydate [at 1.893 (2) and 1.963 (2) Angstrom] and both N atoms from the phenanthroline molecule [at 1.995 (2) and 2.005 (2) Angstrom] define its base. The five-membered chelate ring (CuC2N2) in the phenanthroline.