3-(7-溴-9,9-二甲基-9H-芴-2-基)-9-苯基-9H-咔唑 | 1186644-43-8

• 物质功能分类: 化学试剂 - 有机试剂 - 多环化合物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 中文名称: 3-(7-溴-9,9-二甲基-9H-芴-2-基)-9-苯基-9H-咔唑
• 英文名称: 3-(7-bromo-9,9-dimethyl-9H-fluoren-2-yl)-9-phenyl-9H-carbazole
• 英文别名: 2-bromo-7-(9-phenylcarbazol-3-yl)-9,9-dimethylfluorene；3-(7-bromo-9,9-dimethylfluoren-2-yl)-9-phenylcarbazole
• CAS: 1186644-43-8
• 化学式: C₃₃H₂₄BrN
• 分子量: 514.464
• InChiKey: LYOIWHQTWCWWFK-UHFFFAOYSA-N

物化性质

• 沸点：
  678.2±55.0 °C(Predicted)
• 密度：
  1.31

计算性质

• 辛醇/水分配系数(LogP)：
  9.8
• 重原子数：
  35
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 危险性防范说明：
  P264,P280,P302+P352,P337+P313,P305+P351+P338,P362+P364,P332+P313
• 危险性描述：
  H315,H319

反应信息

• 作为反应物：
  描述：

  3-(7-溴-9,9-二甲基-9H-芴-2-基)-9-苯基-9H-咔唑 在 四(三苯基膦)钯 、 palladium bis[bis(diphenylphosphino)ferrocene] dichloride 、 potassium acetate 、 potassium carbonate 作用下， 以 四氢呋喃 、 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 16.0h， 生成
  参考文献：
  名称：

  화합물, 이를 포함하는 유기 광전자 소자 및 표시장치

  摘要：

  这段文字的中文翻译如下：这涉及到一种包含该化合物的有机发光器件以及包括该有机发光器件的显示装置，其中提供了如下以化学式I表示的化合物。在上述化学式I中，X至X，L至L，R至R，X，Ar，p和q的定义如规范中所定义。

  公开号：

  KR20150006758A
• 作为产物：
  描述：

  N-苯基-3-咔唑硼酸 、 2,7-二溴-9,9-二甲基芴 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 8.0h， 以70%的产率得到3-(7-溴-9,9-二甲基-9H-芴-2-基)-9-苯基-9H-咔唑
  参考文献：
  名称：

  화합물, 이를 포함하는 유기 광전자 소자 및 표시장치

  摘要：

  这段文字的中文翻译如下：这涉及到一种包含该化合物的有机发光器件以及包括该有机发光器件的显示装置，其中提供了如下以化学式I表示的化合物。在上述化学式I中，X至X，L至L，R至R，X，Ar，p和q的定义如规范中所定义。

  公开号：

  KR20150006758A

文献信息

• STYRYL-BASED COMPOUND, COMPOSITION CONTAINING STYRYL-BASED COMPOUND, AND ORGANIC LIGHT EMITTING DIODE INCLUDING STYRYL-BASED COMPOUND
  申请人：Han Sang-Hyun

  公开号：US20130119355A1

  公开（公告）日：2013-05-16

  A styryl-based compound represented by Formula 1, a composition containing the styryl-based compound, and an organic light-emitting diode (OLED) including the styryl-based compound: The styryl-based compound may exhibit high heat resistance and thus an OLED including the same may have low driving voltage, high brightness, high efficiency, and long lifetime.

  一种以化学式1表示的基于styryl的化合物，含有该基于styryl的化合物的组合物，以及包括该基于styryl的化合物的有机发光二极管（OLED）：基于styryl的化合物可能表现出高耐热性，因此包括该化合物的OLED可能具有低驱动电压、高亮度、高效率和长寿命。
• AROMATIC AMINE DERIVATIVE, AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Yabunouchi Nobuhiro

  公开号：US20110278551A1

  公开（公告）日：2011-11-17

  Provided are an organic electroluminescence device that not only provides high efficiency but also has a long lifetime, and an aromatic amine derivative that realizes the device. The organic electroluminescence device includes an aromatic amine derivative, including at least one substituent A having dibenzofuran and at least one substituent B selected from groups each having dibenzofuran or carbazole, in a molecule thereof, in which the substituent A and the substituent B include groups different from each other, and the substituent A and the substituent B are bonded to the same nitrogen atom, or different nitrogen atoms, in the molecule. The molecules of the aromatic amine derivative hardly crystallize, which improves a yield in the production of the organic electroluminescence device. In the organic electroluminescence device, including an organic thin film layer formed of one or more layers including at least a light emitting layer, the organic thin film layer being interposed between a cathode and an anode, the aromatic amine derivative is contained in at least one layer, particularly a hole transport layer, in the organic thin film layer.

  提供了一种既具有高效率又具有长寿命的有机电致发光器件，以及实现该器件的芳香胺衍生物。该有机电致发光器件包括一种芳香胺衍生物，其中该芳香胺衍生物的分子中包含至少一个具有二苯并呋喃的取代基A和至少一个从具有二苯并呋喃或咔唑的各个基团中选择的取代基B，其中取代基A和取代基B包含不同的基团，并且取代基A和取代基B连接到同一氮原子或不同的氮原子上。该芳香胺衍生物的分子几乎不结晶，从而提高了有机电致发光器件的产量。在包括至少一个发光层的一个或多个层的有机薄膜层中，该有机薄膜层被插入在阴极和阳极之间的有机电致发光器件中，该芳香胺衍生物包含在至少一层中，特别是在空穴传输层中。
• Amine-based compound, organic light emitting device comprising the amine-based compound, and flat panel display device including the organic light emitting device
  申请人：Samsung Mobile Display Co., Ltd.

  公开号：EP2149555B1

  公开（公告）日：2011-12-14
• AMINE-BASED COMPOUND, ORGANIC LIGHT EMITTING DEVICE COMPRISING THE AMINE-BASED COMPOUND, AND FLAT PANEL DISPLAY DEVICE INCLUDING THE ORGANIC LIGHT EMITTING DEVICE
  申请人：Hwang Seok-Hwan

  公开号：US20100025669A1

  公开（公告）日：2010-02-04

  The invention is directed to an amine-based compound represented by Formula 1, an organic light emitting device with an organic film including the same, and a flat panel display device including the organic light emitting device.
• NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME
  申请人：Rohm and Haas Electronic Materials Korea Ltd.

  公开号：US20150105563A1

  公开（公告）日：2015-04-16

  The present invention relates to novel organic electroluminescent compounds and an organic electroluminescent device containing the same. The organic electroluminescent compounds according to the present invention can be used as a phosphorescent host material, a hole transport material, or a mixed host material; have a good hole transport ability; prevent crystallization in the production of the device; are suitable for forming a layer; and improve the current density of the device thereby reducing the driving voltage of the device.