2,2-dimethyl-3-methylene-norbornane-1-carboxylic acid | 10309-19-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2,2-dimethyl-3-methylene-norbornane-1-carboxylic acid
• 英文别名: Camphen-carbonsaeure-(4)；2,2-Dimethyl-3-methylen-norbornan-1-carbonsaeure；2.2-Dimethyl-3-methylen-bicyclo-[1.2.2]-heptan-carbonsaeure-(1)；2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane-1-carboxylic acid；2,2-dimethyl-3-methylidenebicyclo[2.2.1]heptane-1-carboxylic acid
• CAS: 10309-19-0
• 化学式: C₁₁H₁₆O₂
• mdl: MFCD03853285
• 分子量: 180.247
• InChiKey: ZZGALJOLYVMECF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.727
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,2-dimethyl-3-methylene-norbornane-1-carboxylic acid 在 五氯化磷 作用下， 生成 2-Chlorboran-4-carbonsaeureamid
  参考文献：
  名称：

  Houben; Pfankuch, Chemische Berichte, 1926, vol. 59, p. 2296

  摘要：

  DOI：
• 作为产物：
  描述：

  3,3-二甲基-2-亚甲基-双环[2.2.1]-庚烷-1-羧酸 在 硫酸 作用下， 生成 2,2-dimethyl-3-methylene-norbornane-1-carboxylic acid
  参考文献：
  名称：

  Houben; Pfankuch, Chemische Berichte, 1926, vol. 59, p. 2296

  摘要：

  DOI：

文献信息

• Catalytic process for the preparation of isolongifolene
  申请人：——

  公开号：US20040242936A1

  公开（公告）日：2004-12-02

  The present invention relates to a catalytic process for preparation of isolongifolene using nanocrystalline solid super acid. This process is an eco-friendly, single step, solvent free catalytic process for the preparation of a tricyclic sesqui-terpene hydrocarbon, isolongifolene. More particularly, the present invention provides a process for the catalytic isomerisation of longifolene to iso-longifolene using nano-crystalline sulfated zirconia as a solid super acid catalyst.

  本发明涉及使用纳米晶固体超强酸催化剂的催化过程，用于制备季萜烃类化合物孤立龙脑烯。该过程是一种环保、单步、无溶剂的催化过程，用于制备三环季萜烃类化合物孤立龙脑烯。更具体地说，本发明提供了一种使用纳米晶硫酸化锆作为固体超强酸催化剂，对长龙脑烯进行催化异构化制备异龙脑烯的过程。
• Perfume compositions containing
  申请人：Naarden International N.V.

  公开号：US04288349A1

  公开（公告）日：1981-09-08

  An acidic and somewhat resinous odor note tending to cistus and olibanium is imparted to a perfume composition or product containing the same by adding the 3,3-dimethylbicyclo-(2,2,1)-heptane-2-carboxylic acid compound thereto.

  向香水配方或含有该化合物的产品中添加3,3-二甲基双环[2,2,1]庚烷-2-羧酸化合物，会赋予一种酸性和略带松香的气味，趋向于岩蔷薇和乳香。
• OXIDATION CATALYST SYSTEM AND PROCESS FOR OXIDATION WITH THE SAME
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP0824962A1

  公开（公告）日：1998-02-25

  A substrate (e.g., a cycloalkane, a polycyclic hydrocarbon, an aromatic compound having a methyl group or methylene group adjacent to an aromatic ring) is oxidized with oxygen in the presence of an oxidation catalyst comprising an imide compound of the following formula (1) (e.g., N-hydroxyphthalimide), and a co-catalyst (except phosphovanadomolybdic acid) containing an element selected from the group consisting of Group 2A elements of the Periodic Table of Elements, transition metals (Group 3A to 7A elements, Group 8 elements, Group 1B elements and Group 2B elements of the Periodic Table of Elements) and Group 3B elements of the Periodic Table of Elements, for the formation of an oxide (e.g., a ketone, an alcohol, a carboxylic acid):    wherein R1 and R2 represent a substituent such as a hydrogen atom or a halogen atom, or R1 and R2 may together form a double bond or an aromatic or nonaromatic 5- to 12-membered ring, X is O or OH, and n is 1 to 3.

  底物（如环烷烃、多环烃、与芳香环相邻的具有甲基或亚甲基的芳香族化合物）在氧化催化剂存在下被氧气氧化，氧化催化剂包括下式(1)的亚胺化合物（如：N-羟基邻苯二甲酰亚胺）和助催化剂（磷酰二钼酸除外），助催化剂含有选自元素周期表 2A 族元素组成的组的元素、N-羟基邻苯二甲酰亚胺），以及含有选自元素周期表 2A 族元素、过渡金属（元素周期表 3A 族至 7A 族元素、8 族元素、1B 族元素和 2B 族元素）和 3B 族元素组成的组的元素的助催化剂（磷钒钼酸除外），以形成氧化物（如酮、醇、羧酸）： 其中 R1 和 R2 代表取代基，如氢原子或卤素原子，或 R1 和 R2 可共同形成双键或芳香族或非芳香族 5 至 12 元环，X 为 O 或 OH，n 为 1 至 3。
• Oxidation catalytic system and oxidation process
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP0858835A1

  公开（公告）日：1998-08-19

  A substrate (e.g., a cycloalkane, a polycyclic hydrocarbon, an aromatic compound having a methyl group) is oxidized with oxygen in the presence of an oxidation catalytic system comprising an imide compound of the following formula (1) (e.g. N-hydroxyphthalimide) and a co-catalyst containing a element selected from Group 3 to 12 elements (in particular, Group 4 to 11 elements) of the Periodic Table of Elements. The co-catalyst comprises a compound contains plural elements (except heteropolyacid and a combination of Group 7 and 8 elements of the Periodic Table of Elements), and is useful for the formation of an oxide (e.g., a ketone, an alcohol, a carboxylic acid):    wherein R1 and R2 represent a substituent such as a hydrogen atom or a halogen atom, or R1 and R2 may together form a double bond or an aromatic or nonaromatic 5- to 12-membered ring, X is O or OH, and n is 1 to 3.

  底物（如环烷烃、多环烃、具有甲基的芳香族化合物）在由下式(1)的酰亚胺化合物（如 N-羟基邻苯二甲酰亚胺）和含有选自元素周期表第 3 至 12 族元素（特别是第 4 至 11 族元素）的助催化剂组成的氧化催化系统存在的情况下与氧进行氧化。助催化剂由含有多种元素（杂多酸和元素周期表第 7 族和第 8 族元素的组合除外）的化合物组成，可用于形成氧化物（如酮、醇、羧酸）： 其中 R1 和 R2 代表取代基，如氢原子或卤素原子，或 R1 和 R2 可共同形成双键或芳香族或非芳香族 5 至 12 元环，X 为 O 或 OH，n 为 1 至 3。
• Oxidation catalytic system and oxidation process using same
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP1258292A1

  公开（公告）日：2002-11-20

  The present invention relates to an oxidation catalytic system which comprises an imide compound and a co-catalyst comprising a compound containing a Group 7A element of the Periodic Table of Elements, and a compound containing a Group 8 element of the Periodic Table of Elements. The present invention further relates to a process for oxidation which comprises the step of contacting a substrate with oxygen in the presence of said oxidation catalytic system.

  本发明涉及一种氧化催化体系，该体系包括一种亚胺化合物和一种助催化剂，助催化剂包括一种含有元素周期表第7A族元素的化合物和一种含有元素周期表第8族元素的化合物。本发明还涉及一种氧化工艺，该工艺包括在上述氧化催化体系存在下使底物与氧气接触的步骤。