1-methyl-3-methylene-2,4(1H,3H)-quinolinedione | 80504-82-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 1-methyl-3-methylene-2,4(1H,3H)-quinolinedione
• 英文别名: 1-Methyl-3-methylidenequinoline-2,4-dione
• CAS: 80504-82-1
• 化学式: C₁₁H₉NO₂
• 分子量: 187.198
• InChiKey: ORFBPRUDGSLORF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-methyl-3-methylene-2,4(1H,3H)-quinolinedione 以66%的产率得到1,6'-dimethyl-3',4'-dihydrospiroquinoline>-2,4,5'(1H,3H,6'H)-trione
  参考文献：
  名称：

  由邻羟基甲基衍生物生成杂环醌甲基化物及其环加成反应的研究

  摘要：

  由1,3-二甲基-4-羟基喹啉-2-酮和2,3-二氯-5,6-二氰基苯并醌（DDQ）制得的喹啉酮甲基（1a）产生二聚体（5）并与2发生原位反应，2-二甲基-2H -1-苯并吡喃，并与乙酸异丙烯酯，得到狄尔斯-阿尔德环加成产物；香豆素醌甲基化物与2,2-二甲基苯并吡喃的行为相似，但与乙酸异丙烯酯和2,3-苯并呋喃产生的加合物可能是[2 + 2]环加成反应产生的。

  DOI：

  10.1039/c39880000527
• 作为产物：
  描述：

  4-羟基-1,3-二甲基-1H-喹啉-2-酮 在 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 苯 为溶剂， 生成 1-methyl-3-methylene-2,4(1H,3H)-quinolinedione
  参考文献：
  名称：

  由邻羟基甲基衍生物生成杂环醌甲基化物及其环加成反应的研究

  摘要：

  由1,3-二甲基-4-羟基喹啉-2-酮和2,3-二氯-5,6-二氰基苯并醌（DDQ）制得的喹啉酮甲基（1a）产生二聚体（5）并与2发生原位反应，2-二甲基-2H -1-苯并吡喃，并与乙酸异丙烯酯，得到狄尔斯-阿尔德环加成产物；香豆素醌甲基化物与2,2-二甲基苯并吡喃的行为相似，但与乙酸异丙烯酯和2,3-苯并呋喃产生的加合物可能是[2 + 2]环加成反应产生的。

  DOI：

  10.1039/c39880000527

文献信息

• A diels-alder adduct of -methylflindersine and a quinolone quinone methide
  作者：Michael F. Grundon、V.N. Ramachandran、Barbara M. Sloan

  DOI：10.1016/s0040-4039(01)81839-6

  日期：1981.1
• CHAUNCEY, MAREK A.;GRUNDON, MICHAEL F.;RUTHERFORD, MARY J., J. CHEM. SOC. CHEM. COMMUN.,(1988) N 8, 527-529
  作者：CHAUNCEY, MAREK A.、GRUNDON, MICHAEL F.、RUTHERFORD, MARY J.

  DOI：——

  日期：——
• Optical Information Recording Medium and Optical Information Recording Method
  申请人：Watanabe Tetsuya

  公开号：US20070286059A1

  公开（公告）日：2007-12-13

  An optical information recording medium, comprising on a substrate a recording layer containing a dye compound having a specific structure. An optical information recording method, comprising recording information on the optical information recording medium by irradiation with laser light of a wavelength of 550 or shorter or 440 nm or shorter.
• Optical Information-Recording Medium and Information-Recording Method
  申请人：Takahashi Keita

  公开号：US20090130366A1

  公开（公告）日：2009-05-21

  There is provided an optical information-recording medium, comprising a recording layer capable of recording of information by irradiation of a laser beam having a wavelength of 440 nm or less on or above a substrate, the recording layer comprising a dye having two or more independent dye moieties in the molecule that are bound to each other in a manner other than by forming a conjugated bond to the dye moieties, and a method of recording information, comprising recording information by irradiating a laser beam having a wavelength of 440 nm or less on or above the optical information-recording medium according to the present invention described above.
• COMPOUND FOR PHOTORESIST, PHOTORESIST LIQUID, AND ETCHING METHOD USING THE SAME
  申请人：Watanabe Tetsuya

  公开号：US20100104985A1

  公开（公告）日：2010-04-29

  The present invention relates to a compound for photoresist, selected from the group consisting of a compound comprising an oxonol dye skeleton, a cyanine dye, a styryl dye, a compound comprising a merocyanine dye skeleton, a compound comprising a phthalocyanine dye skeleton, an azo compound, and a complex compound of an azo compound and a metal ion. The present invention further provides a photoresist liquid comprising at least one of the compound for photoresist and a method of etching a surface being processed using the photoresist liquid.