cyclonona-1,5-diyne | 118620-69-2

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: cyclonona-1,5-diyne
• CAS: 118620-69-2
• 化学式: C₉H₁₀
• 分子量: 118.178
• InChiKey: IOBMXAHSUDFCIA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  bis(η2-ethylene)(η5-pentamethylcyclopentadienyl)cobalt(I) 、 cyclonona-1,5-diyne 以 not given 为溶剂， 以3%的产率得到
  参考文献：
  名称：

  环状二炔的三倍和四倍[2 + 2]环加成反应作为立体效应的结果：在通往聚合物的过程中。

  摘要：

  CpCo介导的环状二炔的[2 + 2]环加成的微调具有三键（C 2 H 4，Si 2 Me 4）之间的小桥，产生纳米带状环芳基1和2。2 ; R = H（1），CO 2 Me（1、2）。

  DOI：

  10.1002/(sici)1521-3773(19981231)37:24<3376::aid-anie3376>3.0.co;2-x
• 作为产物：
  描述：

  nona-2,7-diyne-1,9-diol 在 联苯 、 三溴化磷 、 lithium 作用下， 以 四氢呋喃 为溶剂， 生成 cyclonona-1,5-diyne
  参考文献：
  名称：

  A convenient synthesis of ethano-bridged cyclic diynes — Preparation of 1,1,2,2-tetramethyl-1,2-disilacycloocta-3,7-diyne

  摘要：

  Cyclic diynes bridged by an ethano moiety on one side are formed in the reaction of alpha,omega-dihalogen precursors with lithium in presence of biphenyl. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)10329-x

文献信息

• Syntheses and properties of medium sized carbocyclic diacetylenes
  作者：Rolf Gleiter、Detlef Kratz、Volker Schehlmann

  DOI：10.1016/0040-4039(88)85217-1

  日期：1988.1

  The syntheses and properties of cyclonona-1,5-diyne (1), cyclodeca-1,5-diyne (3), cycloundeca-1,5-diyne (4) and cycloundeca-1,6-diyne(5) are reported.

  报道了Cyclonona-1,5-diyne（1），cyclodeca-1,5-diyne（3），cycloundeca-1,5-diyne（4）和cycloundeca-1,6-diyne（5）的合成和性质。
• Synthesis and properties of medium-sized (C9-C12) carbocyclic diacetylenes
  作者：R. Gleiter、D. Kratz、W. Schaefer、V. Schehlmann

  DOI：10.1021/ja00024a035

  日期：1991.11

  The syntheses of 1,5-cyclononadiyne (3), 1,5-cyclodecadiyne (4), 1,5-cycloundecadiyne (5), 1,6-cycloundecadiyne (6), 1,6-cyclododecadiyne (7), and 1,7-cyclododecadiyne (8) have been carried out. Diacetylenes 3 and 4 are prepared from 5-cyclononynone and 5-cyclodecynone, respectively. Compounds 5-8 are synthesized from cyclic diones by thermolysis of the corresponding bisselenadiazoles. The obtained cyclic diacetylenes are further characterized by their bis(hexacarbonyldicobalt) complexes. The geometrical parameters of 3-8 were calculated with force field and semiempirical methods. From the structural data, a correlation between the C-13 resonance of the sp-hybridized carbon atoms adjacent to the ethano bridge in 3-5 and the corresponding resonance of the symmetric dialkynes 1,5-cyclooctadiyne (1), 1,6-cyclodecadiyne (2), and 1,7-cyclododecadiyne (8) with the bending angle at this center can be verified. The PE spectra of 3-8 have been recorded, and an interpretation of the bands in the low-energy region is presented. It is found that the splitting of the PE bands that are assigned to the in-plane pi-MO's (pi-i) strongly depends on the size of the methylene bridge. In the case of a propano bridge (e.g., in 3, 6, and 7), the splitting between pi-i- and pi=i+ is relatively large. The splitting of the bands that are assigned to the out-of-plane pi-MO's (pi-o) decreases with increasing transannular distance.
• GLEITER, ROLF;KRATZ, DETLEF;SCHEHLMANN, VOLKER, TETRAHEDRON LETT., 29,(1988) N 23, C. 2813-2816
  作者：GLEITER, ROLF、KRATZ, DETLEF、SCHEHLMANN, VOLKER

  DOI：——

  日期：——
• A convenient synthesis of ethano-bridged cyclic diynes — Preparation of 1,1,2,2-tetramethyl-1,2-disilacycloocta-3,7-diyne
  作者：Gebhard Haberhauer、Rolf Roers、Rolf Gleiter

  DOI：10.1016/s0040-4039(97)10329-x

  日期：1997.12

  Cyclic diynes bridged by an ethano moiety on one side are formed in the reaction of alpha,omega-dihalogen precursors with lithium in presence of biphenyl. (C) 1997 Elsevier Science Ltd.
• Threefold and Fourfold [2+2] Cycloadditions of Cyclic Diynes as a Consequence of Steric Effects: En Route to Polymers
  作者：Gebhard Haberhauer、Frank Rominger、Rolf Gleiter

  DOI：10.1002/(sici)1521-3773(19981231)37:24<3376::aid-anie3376>3.0.co;2-x

  日期：1998.12.31

  The fine-tuning of the CpCo-mediated [2+2] cycloaddition of cyclic diynes with small bridges between the triple bonds (C2 H4 , Si2 Me4 ) yields nanosized beltlike cyclophanes 1 and 2. =SiMe2 ; R = H (1), CO2 Me (1, 2).

  CpCo介导的环状二炔的[2 + 2]环加成的微调具有三键（C 2 H 4，Si 2 Me 4）之间的小桥，产生纳米带状环芳基1和2。2 ; R = H（1），CO 2 Me（1、2）。