13-dodecyl-pentacosan-13-ol | 127727-85-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 13-dodecyl-pentacosan-13-ol
• 英文别名: 13-Dodecylpentacosan-13-ol
• CAS: 127727-85-9
• 化学式: C₃₇H₇₆O
• 分子量: 537.01
• InChiKey: ZKRJQBCHGCPMQJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.8
• 重原子数：
  38
• 可旋转键数：
  33
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  13-dodecyl-pentacosan-13-ol 在 碘 作用下， 生成 13-dodecyl-pentacos-12-ene
  参考文献：
  名称：

  Mineralogy of Tagish Lake: An ungrouped type 2 carbonaceous chondrite

  摘要：

  Abstract— In this paper we describe the recovery, handling and preliminary mineralogical investigation of the Tagish Lake meteorite. Tagish Lake is a type 2 carbonaceous chondrite which bears similarities to CI1 and CM chondrite groups, but is distinct from both. Abundant phyllosilicates as well as chondrules (however sparse) and common olivine grains in the matrix preclude any other classification. The bulk density of Tagish Lake (1.67 g/cc) is far lower than CI or CM chondrites (2.2‐2.3 and 2.6‐2.9 g/cc, respectively), or any other meteorite for that matter. We have identified two lithologies: a dominant carbonate‐poor lithology and a less‐abundant carbonate‐rich lithology. The meteorite is a breccia at all scales.We have noted similarities between Tagish Lake and some clasts within the enigmatic meteorite Kaidun; possibly there are genetic relationships here worth exploring. In the paper we describe a clast of CM1 material within Tagish Lake which is very similar to a major lithology in Kaidun.

  DOI：

  10.1111/j.1945-5100.2002.tb00852.x
• 作为产物：
  描述：

  magnesium,dodecane,bromide 、 碳酸二乙酯 在 二丁醚 作用下， 生成 13-dodecyl-pentacosan-13-ol
  参考文献：
  名称：

  Mineralogy of Tagish Lake: An ungrouped type 2 carbonaceous chondrite

  摘要：

  Abstract— In this paper we describe the recovery, handling and preliminary mineralogical investigation of the Tagish Lake meteorite. Tagish Lake is a type 2 carbonaceous chondrite which bears similarities to CI1 and CM chondrite groups, but is distinct from both. Abundant phyllosilicates as well as chondrules (however sparse) and common olivine grains in the matrix preclude any other classification. The bulk density of Tagish Lake (1.67 g/cc) is far lower than CI or CM chondrites (2.2‐2.3 and 2.6‐2.9 g/cc, respectively), or any other meteorite for that matter. We have identified two lithologies: a dominant carbonate‐poor lithology and a less‐abundant carbonate‐rich lithology. The meteorite is a breccia at all scales.We have noted similarities between Tagish Lake and some clasts within the enigmatic meteorite Kaidun; possibly there are genetic relationships here worth exploring. In the paper we describe a clast of CM1 material within Tagish Lake which is very similar to a major lithology in Kaidun.

  DOI：

  10.1111/j.1945-5100.2002.tb00852.x

文献信息

• METHODS FOR CONTROLLING SURFACE FUNCTIONALITY OF METAL OXIDE NANOPARTICLES, METAL OXIDE NANOPARTICLES HAVING CONTROLLED FUNCTIONALITY, AND USES THEREOF
  申请人：White Meghann A.

  公开号：US20080299046A1

  公开（公告）日：2008-12-04

  Methods for controlling surface functionality of metal oxide nanoparticles, nanoparticles having controlled surface functionality, and uses thereof are described herein. Methods for controlling the surface functionality of a metal oxide nanoparticle are can include attaching a ligand to a metal oxide nanoparticle, where the ligand can include a functional portion that is capable of forming an irreversible bond with an object at a site that is complementary to the functional portion without reacting with other reactive sites that may be present. Moreover, metal oxide nanoparticles having versatile ligands can include an anchoring portion that binds to the surface of the metal oxide nanoparticle and a functional portion that is capable of forming an irreversible bond with an object at a site that is complementary to the functional portion without reacting with other reactive sites that may be present. Uses thereof can include cancer detection, electronics, cosmetics, cellular delivery carriers, magnetic storage media, drug delivery carriers, nanocomposite formation for improved mechanical properties, and the like.

  金属氧化物纳米颗粒表面功能的控制方法，具有受控表面功能的纳米颗粒，以及它们的用途在此进行描述。控制金属氧化物纳米颗粒表面功能的方法可以包括将配体连接到金属氧化物纳米颗粒上，其中配体可以包括一个功能部分，该功能部分能够与物体上的一个与功能部分互补的位置形成不可逆结合，而不会与可能存在的其他反应位点发生反应。此外，具有多功能配体的金属氧化物纳米颗粒可以包括一个锚定部分，该部分与金属氧化物纳米颗粒的表面结合，以及一个功能部分，该功能部分能够与物体上的一个与功能部分互补的位置形成不可逆结合，而不会与可能存在的其他反应位点发生反应。其用途可以包括癌症检测、电子学、化妆品、细胞递送载体、磁存储介质、药物递送载体、用于改善机械性能的纳米复合材料形成等。
• Synthesis of Symmetrical Ketones from Grignard Reagents and 1,1′-Carbonyldiimidazole
  作者：Giuseppe Marchese、Daniela Bottalico、Vito Fiandanese、Angela Punzi

  DOI：10.1055/s-0029-1216815

  日期：2009.7

  Coupling reactions of 1,1′-carbonyldiimidazole with Grignard reagents provide a rapid and straightforward method for the synthesis of symmetrical ketones. Grignard reactions - coupling - acylations - 1,1′-carbonyldiimidazole - ketones

  1,1'-羰基二咪唑与格氏试剂的偶联反应为合成对称酮提供了一种快速而直接的方法。 格氏反应-偶联-酰化-1,1'-羰基二咪唑-酮
• The first phase-transfer catalysed reactions of trialkylboranes. A highly facile synthesis of trialkylmethanols from alkenes
  作者：Bai Junchai、Ding Hongxun

  DOI：10.1039/c39900000323

  日期：——

  The phase-transfer catalysed reactions of trialkylboranes, generated in situ via hydroboration of alkenes, with chloroform and aqueous sodium hydroxide, followed by treatment with hydrogen peroxide, provide an economic and convenient method for the synthesis of trialkylmethanols.

  三烷基硼烷的相转移催化反应是通过烯烃的硼氢化反应与氯仿和氢氧化钠水溶液原位生成的，然后用过氧化氢处理，为合成三烷基甲醇提供了一种经济而便捷的方法。
• Breusch; Baykut, Chemische Berichte, 1955, vol. 88, p. 913,915, 916
  作者：Breusch、Baykut

  DOI：——

  日期：——
• JUNCHAI, BAI;HONGXUN, DING, J. CHEM. SOC. CHEM. COMMUN.,(1990) N, C. 323
  作者：JUNCHAI, BAI、HONGXUN, DING

  DOI：——

  日期：——