tetra-O-acetylmucic dialdehyde | 98221-46-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: tetra-O-acetylmucic dialdehyde
• 英文别名: Tetra-O-acetyl-dialdehydo-galacto-hexodialdose；Tetra-O-acetyl-galaktodiose；[(2R,3S,4R,5S)-3,4,5-triacetyloxy-1,6-dioxohexan-2-yl] acetate
• CAS: 98221-46-6；901791-12-6
• 化学式: C₁₄H₁₈O₁₀
• 分子量: 346.291
• InChiKey: NEYQPQQSWQAISW-LVEBTZEWSA-N

物化性质

• 沸点：
  461.6±45.0 °C(Predicted)
• 密度：
  1.283±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -1
• 重原子数：
  24
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  139
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  tetra-O-acetylmucic dialdehyde 在 镍 吡啶 、 氢气 作用下， 以 乙醇 为溶剂， 生成 2,3,4,5-Tetra-O-acetyl-1,6-di-O-methansulfonylgalactit
  参考文献：
  名称：

  710的制备阿尔法。 .omega.二ö一些糖醇的衍生物-methanesulphonyl

  摘要：

  DOI：

  10.1039/jr9610003656
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 potassium permanganate 作用下， 生成 tetra-O-acetylmucic dialdehyde
  参考文献：
  名称：

  �ber die Konstitution des Condurits und �ber einige Cyclohexantetrole

  摘要：

  DOI：

  10.1007/bf01488962

文献信息

• DISPERSION AND PROCESS FOR PRODUCTION OF MOLDINGS BY USING THE SAME
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1512725A1

  公开（公告）日：2005-03-09

  A shaped article (e.g., a porous material, and a spherical particle) comprising (A) a resin component is produced by kneading the resin component (A) (e.g., a thermoplastic resin) and a water-soluble auxiliary component (B) to prepare a dispersed composition, and eluting the auxiliary component (B) from the dispersed composition. The auxiliary component (B) may comprise 100 parts by weight of an oligosaccharide (B1) and 0.5 to 100 parts by weight of a water-soluble plasticizing component (B2) for plasticizing the oligosaccharide. The oligosaccharide (B1) may comprise a tetrasaccharide. The plasticizing component (B2) may comprise a saccharide or a sugar alcohol. Use of the dispersed composition ensures to form a shaped article having a given shape industrially with advantage even in the case of using a wide variety of resin components.

  通过捏合树脂组分（A）（例如热塑性树脂）和水溶性辅助组分（B）以制备分散组合物，并从分散组合物中洗脱辅助组分（B），制备出一种由树脂组分（A）组成的成型品（例如多孔材料和球形颗粒）。辅助组分（B）可包括按重量计 100 份的低聚木糖（B1）和按重量计 0.5 至 100 份的水溶性增塑组分（B2），用于对低聚木糖进行增塑。寡糖（B1）可包括四糖。塑化成分（B2）可以是糖或糖醇。即使在使用多种树脂成分的情况下，使用分散组合物也能确保在工业上形成具有特定形状的成型品。
• COMPOSITE PARTICLE AND DISPERSION
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP1693401A1

  公开（公告）日：2006-08-23

  A multiple particle (e.g., a spherical particle) comprising an organic solid component (A) containing a plurality of organic solid materials (e.g., polymers) is produced by eluting a water-soluble auxiliary component (B) containing at least an oligosaccharide (B1) from a composition having a disperse system, in which a particulate dispersed phase comprising the organic solid component (A) is dispersed in a matrix comprising the auxiliary component (B). The organic solid materials may be different in affinity relative to the auxiliary component (B) from each other. The particle may have a core-shell structure which comprises a core containing a first organic solid material (e.g., a hydrophobic polymer) and a shell containing a second organic solid material (e.g., a hydrophilic polymer) immiscible with the first organic solid material. The weight ratio of the organic solid component (A) relative to the auxiliary component (B) may be about 55/45 to 1/99. The multiple particle corresponding to the dispersed phase (e.g., a core-shell particle) can be produced by a convenient process independently of affinity between the dispersed phase and the matrix and polymerization manner of the polymer.

  通过从具有分散系统的组合物中洗脱含有至少一种寡糖（B1）的水溶性辅助组分（B），制得一种由含有多种有机固体材料（如聚合物）的有机固体组分（A）组成的多颗粒（如球形颗粒），在该组合物中，由有机固体组分（A）组成的颗粒分散相被分散在由辅助组分（B）组成的基质中。有机固体材料相对于辅助成分（B）的亲和力可能互不相同。颗粒可具有核壳结构，包括含有第一种有机固体材料（如疏水性聚合物）的核和含有与第一种有机固体材料不相溶的第二种有机固体材料（如亲水性聚合物）的壳。有机固体成分（A）相对于辅助成分（B）的重量比可以约为 55/45 至 1/99。与分散相相对应的多粒子（例如核壳粒子）可以通过方便的工艺生产，与分散相和基质之间的亲和性以及聚合物的聚合方式无关。
• Dispersion and process for producing colored organic solid particle
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP2447327A1

  公开（公告）日：2012-05-02

  A colored particle (e.g., a spherical particle) comprising an organic solid component (e.g., a polymer component) and a coloring agent (e.g., an oil-soluble dye, and an organic or inorganic pigment) is produced by eluting a water-soluble auxiliary component comprising at least an oligosaccharide from a composition having a disperse system, in which a particulate dispersed phase comprising the organic solid component and the coloring agent is dispersed in a matrix comprising the auxiliary component. The weight ratio of the polymer component relative to the auxiliary component may be about 55/45 to 1/99. The proportion of the coloring agent may be about 0.001 to 100 parts by weight relative to 100 parts by weight of the organic solid component. Such a process ensures conveniently and industrially advantageous production of a colored particle (e.g., a colored polymer particle) corresponding to the dispersed phase independently of affinity between the dispersed phase and the matrix.

  通过从具有分散系统的组合物中洗脱包含至少一种寡糖的水溶性辅助组分，制得包含有机固体组分（如聚合物组分）和着色剂（如油溶性染料和有机或无机颜料）的有色颗粒（如球形颗粒），其中包含有机固体组分和着色剂的颗粒分散相分散在包含辅助组分的基质中。聚合物组分与辅助组分的重量比可以是 55/45 至 1/99。相对于 100 重量份的有机固体成分，着色剂的比例可以是约 0.001 至 100 重量份。这样的工艺可确保方便地生产出与分散相相对应的有色颗粒（如有色聚合物颗粒），且不受分散相与基质之间亲和力的影响，具有工业优势。
• Dispersion and process for production of Moldings by Using the same
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP2431411A1

  公开（公告）日：2012-03-21

  A shaped article (e.g., a porous material, and a spherical particle) comprising (A) a resin component is produced by kneading the resin component (A) (e.g., a thermoplastic resin) and a water-soluble auxiliary component (B) to prepare a dispersed composition, and eluting the auxiliary component (B) from the dispersed composition. The auxiliary component (B) may comprise 100 parts by weight of an oligosaccharide (B1) and 0.5 to 100 parts by weight of a water-soluble plasticizing component (B2) for plasticizing the oligosaccharide. The oligosaccharide (B1) may comprise a tetrasaccharide. The plasticizing component (B2) may comprise a saccharide or a sugar alcohol. Use of the dispersed composition ensures to form a shaped article having a given shape industrially with advantage even in the case of using a wide variety of resin components.

  通过捏合树脂组分（A）（例如热塑性树脂）和水溶性辅助组分（B）以制备分散组合物，并从分散组合物中洗脱辅助组分（B），制备出一种由树脂组分（A）组成的成型品（例如多孔材料和球形颗粒）。辅助组分（B）可包括按重量计 100 份的低聚木糖（B1）和按重量计 0.5 至 100 份的水溶性增塑组分（B2），用于对低聚木糖进行增塑。寡糖（B1）可包括四糖。塑化成分（B2）可以是糖或糖醇。即使在使用多种树脂成分的情况下，使用分散组合物也能确保在工业上形成具有特定形状的成型品。
• Dispersion and process for production of moldings by using the same
  申请人：Ito Hisayoshi

  公开号：US20050239925A1

  公开（公告）日：2005-10-27

  A shaped article (e.g., a porous material, and a spherical particle) comprising (A) a resin component is produced by kneading the resin component (A) (e.g., a thermoplastic resin) and a water-soluble auxiliary component (B) to prepare a dispersed composition, and eluting the auxiliary component (B) from the dispersed composition. The auxiliary component (B) may comprise 100 parts by weight of an oligosaccharide (B 1 ) and 0.5 to 100 parts by weight of a water-soluble plasticizing component (B 2 ) for plasticizing the oligosaccharide. The oligosaccharide (B 1 ) may comprise a tetrasaccharide. The plasticizing component (B 2 ) may comprise a saccharide or a sugar alcohol. Use of the dispersed composition ensures to form a shaped article having a given shape industrially with advantage even in the case of using a wide variety of resin components.

  通过捏合树脂组分（A）（如热塑性树脂）和水溶性辅助组分（B）以制备分散组合物，并从分散组合物中洗脱辅助组分（B），制备出由（A）树脂组分组成的成型品（如多孔材料和球形颗粒）。辅助组分（B）可包括 100 重量份的寡糖（B 1 ）和 0.5 至 100 重量份的水溶性增塑组分（B 2 ），用于对寡糖进行塑化。寡糖（B 1 可包括四糖。塑化成分（B 2 可包括糖或糖醇。即使在使用多种树脂成分的情况下，使用分散组合物也能确保在工业上形成具有特定形状的成型品。