2-碘-4-甲基喹啉 | 607-65-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 中文名称: 2-碘-4-甲基喹啉
• 英文名称: 2-iodo-4-methylquinoline
• 英文别名: 2-iodo-4-methyl-quinoline；2-Jod-4-methyl-chinolin
• CAS: 607-65-8
• 化学式: C₁₀H₈IN
• 分子量: 269.085
• InChiKey: ZXOBNGWBLZSZAE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-碘-4-甲基喹啉 在 正丁基锂 、 乙醚 作用下， 生成 4-甲基喹啉-2-羧酸
  参考文献：
  名称：

  Organometallic Derivatives of Carbazole and Quinoline. Amides of 3-Quinoline-carboxylic Acid

  摘要：

  DOI：

  10.1021/ja01851a018
• 作为产物：
  描述：

  4-甲基-2-氯-喹啉 在 氢碘酸 、 sodium iodide 作用下， 以 丁酮 为溶剂， 反应 24.0h， 以93%的产率得到2-碘-4-甲基喹啉
  参考文献：
  名称：

  Sakamoto, Takao; Arakida, Hiroko; Edo, Kiyoto, Chemical and pharmaceutical bulletin, 1982, vol. 30, # 10, p. 3647 - 3656

  摘要：

  DOI：

文献信息

• AMINE-BASED COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：SAMSUNG DISPLAY CO. LTD.

  公开号：US20190055187A1

  公开（公告）日：2019-02-21

  An amine-based compound represented by Formula 1, in which one of R 1 to R 10 is a group represented by Formula 2, and an organic light-emitting device including the same are provided: When the amine-based compound is included in an organic light-emitting device as a hole transport material, the device may exhibit excellent I-V-L characteristics, including a low driving voltage, improved efficiency, and improved lifespan.

  提供了由公式1表示的一种胺基化合物，其中R1至R10中的一个是由公式2表示的基团，并且包括该化合物的有机发光器件：当将该胺基化合物作为空穴传输材料包含在有机发光器件中时，该器件可能表现出优异的I-V-L特性，包括低驱动电压、提高效率和延长寿命。
• CONDENSED-CYCLIC COMPOUND AND ORGANIC LIGHT EMITTING DEVICE COMPRISING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20170062720A1

  公开（公告）日：2017-03-02

  The present disclosure provides a condensed-cyclic compound represented by Formula 1, in which one selected from R 1 to R 8 is a monoamine represented by Formula 2: The condensed-cyclic compound represented by Formula 1 may act as a hole transport material having a suitable energy level and band-gap. Further, the condensed-cyclic compound represented by Formula 1 has a fused core, and accordingly may have a high glass transition temperature (Tg), high melting point, and improved resistance to high temperatures. Therefore an organic light-emitting device including the condensed-cyclic compound represented by Formula 1 may retain high durability during storing and/or driving.

  本公开提供一种由化学式1表示的稠环化合物，其中R1至R8中选择一个为由化学式2表示的单胺：化学式1表示的稠环化合物可以作为具有适当能级和带隙的空穴传输材料。此外，化学式1表示的稠环化合物具有一个融合的核心，因此可能具有较高的玻璃转变温度（Tg）、高熔点和改善的耐高温性能。因此，包括化学式1表示的稠环化合物的有机发光器件在存储和/或驱动过程中可能保持高耐久性。
• CONDENSED CYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：Samsung Display Co., Ltd

  公开号：US20170256721A1

  公开（公告）日：2017-09-07

  A condensed cyclic compound and an organic light-emitting device including the same are provided. The compound may be represented by the following structure: wherein X 1 is N or C(R 1 ), X 2 is N or C(R 2 ), X 3 is N or C(R 3 ), X 4 is N or C(R 4 ), X 5 is N or C(R 5 ), and X 6 is N or C(R 6 ), and ring A 1 is a C 5 -C 60 carbocyclic group or a C 2 -C 60 heterocyclic group, provided that ring A 1 is not a benzene.

  提供了一种浓缩的环状化合物和包括该化合物的有机发光器件。该化合物可由以下结构表示：其中 X1为N或C（R1），X2为N或C（R2），X3为N或C（R3），X4为N或C（R4），X5为N或C（R5），X6为N或C（R6），环A1为C5-C60碳环或C2-C60杂环，前提是环A1不是苯环。
• CARBAZOLE-BASED COMPOUND AND ORGANIC LIGHT EMITTING DEVICE INCLUDING THE SAME
  申请人：Samsung Display Co., Ltd

  公开号：US20170213987A1

  公开（公告）日：2017-07-27

  Provided are a carbazole-based compound and an organic light-emitting device including the same. The carbazole-based compound may have the following general structure: wherein details and examples of L 1 through L 6 , R 1 through R 6 , a 1 through a 6 , and b 1 through b 6 are provided.

  提供了一种基于咔唑的化合物和包括该化合物的有机发光装置。该基于咔唑的化合物可能具有以下一般结构：其中提供了L1-L6、R1-R6、a1-a6和b1-b6的详细信息和示例。
• CARBAZOLE-BASED COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：Samsung Display Co., Ltd.

  公开号：US20170179400A1

  公开（公告）日：2017-06-22

  An organic light-emitting device including: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer, wherein the organic layer includes a carbazole-based compound represented by Formula 1A or 1B: When the carbazole-based compound represented by Formula 1A or 1B is included in the hole transport layer, an organic light-emitting device may have improved driving voltage, efficiency, luminance, and lifespan characteristics.

  一种有机发光器件，包括：第一电极；与第一电极相对的第二电极；以及位于第一电极和第二电极之间的有机层，该有机层包括一个发射层，其中该有机层包括由式1A或1B表示的咔唑基化合物： 当由式1A或1B表示的咔唑基化合物包含在空穴传输层中时，有机发光器件的驱动电压、效率、亮度和寿命特性可能得到改善。