3-pentanone dibutyl ketal | 70672-83-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-pentanone dibutyl ketal
• 英文别名: 3,3-dibutoxy-pentane；pentan-3-one-dibutylacetal；Pentan-3-on-dibutylacetal；3,3-Dibutoxy-pentan；3,3-Dibutoxypentane
• CAS: 70672-83-2
• 化学式: C₁₃H₂₈O₂
• 分子量: 216.364
• InChiKey: ROHJSPLCOMNUPA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-溴-2-丁烯 、 3-pentanone dibutyl ketal 在 氢化铝 作用下， 生成 4-butoxy-4-ethyl-3-methyl-hex-1-ene
  参考文献：
  名称：

  Action d'organoaluminiques α-insatures sur les acetals et les cetals

  摘要：

  DOI：

  10.1016/s0022-328x(00)83185-x
• 作为产物：
  描述：

  3-戊酮 、 正丁醇 在 对甲苯磺酸 、 原甲酸三乙酯 作用下， 生成 3-pentanone dibutyl ketal
  参考文献：
  名称：

  MacKenzie; Stocker, Chem, 1955, vol. 20, p. 1695,1700

  摘要：

  DOI：

文献信息

• Rhenium complex-catalyzed allylation of acetals with allyltrimethylsilane
  作者：Yutaka Nishiyama、Keiko Shimoura、Noboru Sonoda

  DOI：10.1016/j.tetlet.2008.09.001

  日期：2008.11

  It was confirmed that the treatment of acetals with allyltrimethylsilane in the presence of a catalytic amount of the rhenium complex, ReBr(CO)(5), gave the corresponding homoallylic ethers in excellent to good yields. (C) 2008 Elsevier Ltd. All rights reserved.
• Erythromycin a derivatives and method for the preparation of the same
  申请人：TAISHO PHARMACEUTICAL CO. LTD

  公开号：EP0272110B1

  公开（公告）日：1993-04-07
• BARBOT F.; MINIAC P., J. ORGANOMETAL. CHEM., 1979, 170, NO 1, 1-8
  作者：BARBOT F.、 MINIAC P.

  DOI：——

  日期：——
• SOLID CATALYST FOR OLEFIN POLYMERIZATION AND PROCESS FOR PRODUCING OLEFIN POLYMER
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20130072648A1

  公开（公告）日：2013-03-21

  A solid catalyst for olefin polymerization and a process for producing an olefin polymer are provided. The polymer has a small content of a component which is dissolved out into a low temperature organic solvent, such as a low-molecular weight component and an amorphous component. The solid catalyst is obtained by bringing a solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom, a halogen atom, and an aliphatic carboxylate; an organoaluminum compound; and a compound represented by formula (I) into contact with each other: wherein R 1 is a hydrocarbyl group having 1 to 10 carbon atoms, R 2 is a hydrogen atom, a halogen atom or a hydrocarbyl group having 1 to 16 carbon atoms, and the R 1 the R 2 groups are independently the same or different, and the respective R 1 groups and R 2 groups may be joined with each other to form a ring.
• US4990602A
  申请人：——

  公开号：US4990602A

  公开（公告）日：1991-02-05