二环[2.2.2]辛烷-1,2-二醇 | 110977-46-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 二环[2.2.2]辛烷-1,2-二醇
• 英文名称: bicyclo<2.2.2>octane-1,2-diol
• 英文别名: Bicyclo[2.2.2]octane-1,2-diol
• CAS: 110977-46-3
• 化学式: C₈H₁₄O₂
• 分子量: 142.198
• InChiKey: NTKHGLJHACZPLM-UHFFFAOYSA-N

物化性质

• 沸点：
  274.1±8.0 °C(Predicted)
• 密度：
  1.273±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  二环[2.2.2]辛烷-1,2-二醇 在 2,6-二甲基吡啶 作用下， 生成 1-Ethoxy-(E)-2-ethylidenebicyclo<2.2.2>octane
  参考文献：
  名称：

  Takeuchi, K.; Ohga, Y.; Kitagawa, T., Journal de Chimie Physique et de Physico-Chimie Biologique, 1992, vol. 89, # 7, p. 1631 - 1638

  摘要：

  DOI：
• 作为产物：
  描述：

  三氟甲磺酸苄酯 在 氢氧化钾 作用下， 以 甲醇 、 四氯化碳 为溶剂， 反应 2.0h， 生成 二环[2.2.2]辛烷-1,2-二醇
  参考文献：
  名称：

  Ring-Expansion of Bridgehead Aldehydes with 1-Adamantanecarbonyl Cation or Benzoyl Trifluoromethanesulfonate: A New Route to Bicyclic and Tricyclic 1,2-Diols

  摘要：

  在三氟甲磺酸存在下，桥头醛与由 1-金刚烷阳离子和一氧化碳生成的 1-金刚烷羰基阳离子或与三氟甲磺酸苯甲酰酯发生酰化反应，会使醛环扩张一个碳原子。将反应混合物加水处理后，可得到在邻接碳上含有酰氧基的桥头醇，皂化后可得到邻接二醇，总产率很高。例如，双环[2.2.1]庚烷-1-甲醛可生成双环[2.2.2]辛烷-1,2-二醇，而其他方法很难获得这种物质。

  DOI：

  10.1055/s-1987-28022

文献信息

• PROCESS FOR PREPARING EPISULFIDE COMPOUNDS
  申请人：Asahi Kasei Chemicals Corporation

  公开号：EP2700636A1

  公开（公告）日：2014-02-26

  Provided is a method for producing an episulfide compound, the method including a step of thiating epoxy groups of (B) an epoxy compound by a reaction with (C) a thiating agent in the presence of (A) a polyhydric hydroxyl compound having two or more hydroxyl groups.

  本发明提供了一种生产环硫化化合物的方法，该方法包括以下步骤：在(A)具有两个或两个以上羟基的多羟基化合物存在下，通过与(C)硫化剂反应，硫化(B)环氧化合物的环氧基团。
• Selective oxidation of tertiary-secondary vic-diols to α-hydroxy ketones by dioxiranes
  作者：Ruggero Curci、Lucia D'Accolti、Antonia Detomaso、Caterina Fusco、Ken'ichi Takeuchi、Yasushi Ohga、Philip E. Eaton、Yu Chi Yip

  DOI：10.1016/0040-4039(93)88085-w

  日期：1993.7

  Isolated dimethyldioxirane (1a) and methyl(trifluoromethyl)dioxirane (1b) efficiently afford the conversion of bicyclic diols bicyclo(2.2.2]octane-1,2-diol (2) and (+)-pinane-2,3-diol (6), of tricyclic diols adamantane-1,2-diol (3), homoadamantane-3,4-diol (4), and of homopentaprismane-3,4-diol (5) into the corresponding alpha-hydroxy ketones in high yields and under mild conditions. In the oxidation of (+)-pinane-2,3-diol (6), (-)-2-hydroxy-3-pinanone (11) is obtained in optical yield >97% with retention of configuration.
• TAKEUCHI, KENICHI;AKIYAMA, FUMIO;IKAI, KEIZO;SHIBATA, TADASHI;KATO, MIDOR+, TETRAHEDRON LETT., 29,(1988) N 8, 873-876
  作者：TAKEUCHI, KENICHI、AKIYAMA, FUMIO、IKAI, KEIZO、SHIBATA, TADASHI、KATO, MIDOR+

  DOI：——

  日期：——
• Magnetic recording medium
  申请人：Murayama Yuichiro

  公开号：US20050112409A1

  公开（公告）日：2005-05-26

  A magnetic recording medium is provided that includes a non-magnetic support and at least one magnetic layer provided on or above the non-magnetic support, the magnetic layer containing a ferromagnetic powder dispersed in a binder, the binder containing a polyurethane resin having a bridged hydrocarbon structure or a spiro structure, and the ferromagnetic powder containing an acicular ferromagnetic substance having a major axis length of 20 to 50 nm or a tabular ferromagnetic substance having a plate size of 10 to 50 nm. There is also provided the magnetic recording medium wherein it further includes a non-magnetic layer provided between the non-magnetic support and the magnetic layer, the non-magnetic layer containing a non-magnetic powder dispersed in a binder, and the binder of the non-magnetic layer containing a polyurethane resin having a bridged hydrocarbon structure or a spiro structure.
• SULFONIC ACID POLYOL COMPOUND, POLYURETHANE RESIN, POLYURETHANE RESIN FOR MAGNETIC RECORDING MEDIUM, AND MAGNETIC RECORDING MEDIUM
  申请人：OMURA Kazufumi

  公开号：US20090087687A1

  公开（公告）日：2009-04-02

  A compound represented by the Formula below is provided. (in Formula (1), X denotes a divalent linking group, R 1 and R 2 independently denote an alkyl group having 3 or more carbons and having at least one hydroxy group or an aralkyl group having 8 or more carbons and having at least one hydroxy group, the alkyl group and aralkyl group may have a substituent, and M denotes a hydrogen atom or a cation). There is also provided a polyurethane resin obtained by polymerization of a polyisocyanate and a polyol that includes the compound. There is also provided a magnetic recording medium that includes a non-magnetic support and, above the support, at least one magnetic layer including a ferromagnetic powder dispersed in a binder that includes the polyurethane resin. There is also provided a magnetic recording medium that includes a non-magnetic support, above the support at least one non-magnetic layer including a non-magnetic powder dispersed in a binder ( 1 ), and, above the non-magnetic layer, at least one magnetic layer having a ferromagnetic powder dispersed in a binder ( 2 ), in which binder ( 1 ) and/or binder ( 2 ) is the polyurethane resin.