(2-ethoxycarbonyl-cyclopropyliden)-acetic acid ethyl ester | 37608-34-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (2-ethoxycarbonyl-cyclopropyliden)-acetic acid ethyl ester
• 英文别名: (2-Aethoxycarbonyl-cyclopropyliden)-essigsaeure-aethylester；ethyl (2Z)-2-(2-ethoxy-2-oxoethylidene)cyclopropane-1-carboxylate
• CAS: 37608-34-7
• 化学式: C₁₀H₁₄O₄
• 分子量: 198.219
• InChiKey: CKXHJDRBYZNFQK-SREVYHEPSA-N

物化性质

• 沸点：
  261.4±23.0 °C(Predicted)
• 密度：
  1.230±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (2-ethoxycarbonyl-cyclopropyliden)-acetic acid ethyl ester 在 氢氧化钾 作用下， 生成 3-氧代己二酸
  参考文献：
  名称：

  380.谷氨酸和酯的结构。第七部分。3-甲基环丙烯-1：2-二羧酸的衍生物

  摘要：

  DOI：

  10.1039/jr9320002557
• 作为产物：
  描述：

  diethyl 3-methylenecyclopropane-trans-1,2-dicarboxylate 生成 (2-ethoxycarbonyl-cyclopropyliden)-acetic acid ethyl ester
  参考文献：
  名称：

  New Compounds. Some Aldehydic Hydrazones of Triaiminoguanidine

  摘要：

  DOI：

  10.1021/ja01142a603

文献信息

• Goss; Ingold; Thorpe, Journal of the Chemical Society, 1923, vol. 123, p. 360
  作者：Goss、Ingold、Thorpe

  DOI：——

  日期：——
• Nanometer structure and conductor mechanism of polymer modified by metal ion implantation
  作者：Yuguang Wu、Tonghe Zhang、Yanwen Zhang、Huixing Zhang、Xiaoji Zhang、Gu Zhou

  DOI：10.1007/bf02916735

  日期：2001.10

  Polyethylene terephthalate (PET) has been modified by Ag, Ti, Cu and Si ion implantation with a dose ranging from I X 10(16) to 2 x 10(17) ions/cm(2) using a metal vapor vacuum arc (MEVVA) source. The electrical properties of PET have been improved by metal ion implantation. The resistivity of implanted PET decreased obviously with an increase in ion dose. The results show that the conductive behavior of a metal ion implanted sample is different from Si-implantation samples. In order to understant the mechanism of electrical conduction, the structures of implanted layer were observed in detail by XRD and TEM. The nano carbon particles were dispersed in implanted PET. The nano metallic particles were built up in metallic ion implanted layers with dose range from 1 x 10(16) to 1 x 10(17) ions/cm(2). The nanometer metal net structure was formed in implanted layer when a dose of 2 x 10(17) ions/cm(2) is reached. Anomalous fractal growths were observed. These surface structure changes revealed conducting mechanism evolution. It is believed that the change would result in an improvement of the conductive properties. The conducting mechanism will be changed with increasing metal ion dose.