((allyloxy)methyl)cyclohexane | 20396-09-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: ((allyloxy)methyl)cyclohexane
• 英文别名: Prop-2-enoxymethylcyclohexane
• CAS: 20396-09-2
• 化学式: C₁₀H₁₈O
• 分子量: 154.252
• InChiKey: YINUPFYEJNMWPS-UHFFFAOYSA-N

物化性质

• 沸点：
  201.2±9.0 °C(Predicted)
• 密度：
  0.864±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  ((allyloxy)methyl)cyclohexane 在 Fe⁰(bpyr) 对甲苯磺酸 作用下， 以 四氢呋喃 、 苯 为溶剂， 生成
  参考文献：
  名称：

  Takacs, James M.; Anderson, Lawrence G.; Madhavan, G. V. Bindu, Angewandte Chemie, 1987, vol. 99, # 10, p. 1073 - 1075

  摘要：

  DOI：
• 作为产物：
  描述：

  3-溴丙烯 、 环己甲醇 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 0.5h， 以58%的产率得到((allyloxy)methyl)cyclohexane
  参考文献：
  名称：

  可靠的区域选择性二烷基醚裂解与混合三卤化硼

  摘要：

  描述了用于不对称烷基醚的区域选择性裂解以产生烷基醇和烷基溴化物产物的方案。与单独的BBr 3相比，三卤呋喃酮的混合物触发了这种转化并显示出改善的反应性分布（区域选择性和产率）。此外，该程序可以有效合成（B–Cl）硼酸二烷基酯。产生无环二烷氧基硼酰氯的方法是有限的，这些中间体在主族化学中构成重要的合成子。

  DOI：

  10.1021/acs.orglett.8b02356

文献信息

• PROCESS FOR PRODUCING EPOXY COMPOUND
  申请人：Nagato Nobuyuki

  公开号：US20120029217A1

  公开（公告）日：2012-02-02

  According to the present, invention, a process for producing an epoxy compound, where an epoxy compound can be selectively produced from olefins with good yield at low cost in a safe manner by a simple operation under mild conditions without using a quaternary ammonium salt or a metal compound, is provided. The present invention relates to a process for producing an epoxy compound, comprising epoxidizing a carbon-carbon double bond of an organic compound having a carbon-carbon double bond by using hydrogen peroxide as an oxidant, wherein the epoxidation is carried by out using an organic nitrile compound and an organic amine compound.

  根据本发明，提供了一种生产环氧化合物的方法，其中可以通过简单操作在温和条件下以低成本安全地从烯烃中选择性地生产环氧化合物，而无需使用季铵盐或金属化合物。本发明涉及一种生产环氧化合物的方法，包括使用过氧化氢作为氧化剂，通过使用有机腈化合物和有机胺化合物对含有碳碳双键的有机化合物的碳碳双键进行环氧化。
• Process for the preparation of vinyl ether compounds
  申请人：Iwahama Takahiro

  公开号：US20070149828A1

  公开（公告）日：2007-06-28

  A vinyl ether compound represented by following Formula (2): wherein R represents an organic group; and R 1 , R 2 , R 3 and R 4 are the same as or different from one another and each represent a hydrogen atom or an organic group, is produced by isomerizing an allyl ether compound in the presence of a base and a compound of a Group VIII element of the Periodic Table of Elements, which allyl ether compound is represented by following Formula (1): wherein R, R 1 , R 2 , R 3 and R 4 are as defined above.

  以下是化学式（2）表示的乙烯醚化合物： 其中R代表有机基团；R1，R2，R3和R4相同或不同，每个代表氢原子或有机基团。该乙烯醚化合物是通过在碱和元素周期表第VIII族元素的化合物存在下异构化烯丙醚化合物而制得的，该烯丙醚化合物由以下化学式（1）表示： 其中R，R1，R2，R3和R4如上定义。
• METHOD FOR PRODUCING EPOXY COMPOUND
  申请人：Showa Denko K.K.

  公开号：EP2412712A1

  公开（公告）日：2012-02-01

  According to the present invention, a process for producing an epoxy compound, where an epoxy compound can be selectively produced from olefins with good yield at low cost in a safe manner by a simple operation under mild conditions without using a quaternary ammonium salt or a metal compound, is provided. The present invention relates to a process for producing an epoxy compound, comprising epoxidizing a carbon-carbon double bond of an organic compound having a carbon-carbon double bond by using hydrogen peroxide as an oxidant, wherein the epoxidation is carried by out using an organic nitrile compound and an organic amine compound.

  根据本发明，提供了一种生产环氧化合物的工艺，在该工艺中，不使用季铵盐或金属化合物，在温和的条件下，通过简单的操作，可以安全地以低成本从烯烃中选择性地生产出产率高的环氧化合物。本发明涉及一种生产环氧化合物的工艺，包括用过氧化氢作为氧化剂使具有碳碳双键的有机化合物的碳碳双键环氧化，其中环氧化是用有机腈化合物和有机胺化合物进行的。
• PHOTOCURABLE SUPPORT MATERIAL COMPOSITION FOR INKJET 3D PRINTERS, INK FOR INKJET 3D PRINTERS, CARTRIDGE FOR INKJET 3D PRINTERS, METHOD FOR PRODUCING SUPPORT MATERIAL AND METHOD FOR PRODUCING OPTICALLY SHAPED ARTICLE
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP3508335A1

  公开（公告）日：2019-07-10

  In the present invention, a photocurable support material composition for an inkjet 3D printer comprises a water-soluble ethylenically unsaturated monomer containing an ionic group and a counter ion, and comprises a photopolymerization initiator. The ionic group is preferably at least one selected from a group consisting of carboxylic acid group, phosphoric acid group, and sulfonic acid group. The counter ion is preferably at least one selected from a group consisting of sodium ion, potassium ion, and ammonium ion.

  在本发明中，一种用于喷墨式 3D 打印机的光固化支撑材料组合物包含一种含有离子基团和反离子的水溶性乙烯基不饱和单体，并包含一种光聚合引发剂。离子基团最好至少选自羧酸基团、磷酸基团和磺酸基团。反离子最好是选自钠离子、钾离子和铵离子组成的组中的至少一种。
• RESIN COMPOSITION, METHOD FOR MANUFACTURING THREE-DIMENSIONAL OBJECT USING RESIN COMPOSITION, THREE-DIMENSIONAL OBJECT, AND OBJECT-GRIPPING ATTACHMENT, AND INDUSTRIAL ROBOT USING OBJECT-GRIPPING ATTACHMENT
  申请人：Konica Minolta, Inc.

  公开号：EP3685989A1

  公开（公告）日：2020-07-29

  The purpose of the present invention is to provide a resin composition which is capable of producing a three-dimensional object having high tensile strength and dimensional accuracy and is easily detectable by a metal detector. The resin composition is used in a method in which a liquid-liquid type resin composition is selectively irradiated with an active energy ray to produce a three-dimensional object composed of a cured product of the resin composition. The resin composition contains a photopolymerizable compound and a metal-containing particle, which can be detected by a metal detector and has been surface-treated with a surfactant, the content of the metal-containing particle being 10-55 mass% with respect to the solid content of a resin.

  本发明的目的是提供一种树脂组合物，它能够生产出具有高抗拉强度和尺寸精度的三维物体，并且易于被金属探测器探测到。该树脂组合物的使用方法是，用活性能量射线选择性地照射液-液型树脂组合物，以产生由该树脂组合物的固化产物构成的三维物体。该树脂组合物含有一种可光聚合的化合物和一种含金属的微粒，该微粒可被金属检测器检测到，并经过表面活性剂的表面处理，含金属微粒的含量为树脂固体含量的 10-55 质量％。