Zn(methacrylamidobenzoate)2(1,10-phenanthroline) | 1446004-25-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: Zn(methacrylamidobenzoate)2(1,10-phenanthroline)
• 英文别名: Zn(methacrylamidobenzoate)₂(1,10-phenanthroline)；Zn(o-MAABA)₂(phen)
• CAS: 1446004-25-6
• 化学式: C₃₄H₂₈N₄O₆Zn
• 分子量: 654.01
• InChiKey: OYWZESXRBSQENN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  邻氨基苯甲酸 在 三乙胺 、 sodium hydroxide 作用下， 以 四氢呋喃 、 甲醇 、 水 为溶剂， 反应 8.5h， 生成 Zn(methacrylamidobenzoate)2(1,10-phenanthroline)
  参考文献：
  名称：

  Synthesis, structures of four coordination compounds constructed from o-methacrylamidobenzoic acid and their relationship between structure and solid state luminescence

  摘要：

  Four new coordination compounds, namely, Zn(o-MAABA)(2)(Phen) (1), [Cd(o-MAABA)(2)center dot 2H(2)O](2) (2), {[Pb2Cl2(o-MAABA)(2)(Phen)(4)]}center dot 2H(2)O (3 center dot 2H(2)O), [Pb(NO3)(o-MAABA)(Phen)](n) (4), where o-MAABA=o-methacrylamidobenzoic acid and phen=1, 10-phenanthroline, have been synthesized. All compounds were fully confirmed by FT-IR, elemental analysis and TGA analysis. Their structures were determined by single crystal X-ray diffraction, in which compound 1 shows a mononuclear structure, compounds 2 and 3 have binuclear structures and compound 4 shows an infinite chain. In 2 and 4, the adjacent chains are extended into a 3D supramolecular architecture via pi-pi interactions. Solid-state room temperature luminescence spectra revealed that emission bands of compound 1 were located at 524 nm (lambda(ex)=352 nm) and compound 4 at 479 and 584 nm (lambda(ex)=390 nm) assigned to the excimer formation. The emission at 454 nm (lambda(ex)=340 nm) of compound 2 was mainly ascribed to the Ligand-Metal Charge Transfer (LMCT). Crown Copyright (c) 2013 Published by Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2013.03.055