N,N'-双-(4-吡啶基)苯四甲酰亚胺 | 34072-51-0

• 物质功能分类: 医药中间体 - 杂环化合物 - 吡啶类化合物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 中文名称: N,N'-双-(4-吡啶基)苯四甲酰亚胺
• 英文名称: N,N'-di-(4-pyridyl)-1,2,4,5-benzenetetracarboxydiimide
• 英文别名: N′-bis(4-aminopyridine)phenylenediimide；N,N'-bis-(4-pyridyl)pyromellitic diimide；diPyBi；Pyrrolo[3,4-f]isoindole-1,3,5,7-tetraone, 2,6-di(pyridin-4-yl)-；2,6-dipyridin-4-ylpyrrolo[3,4-f]isoindole-1,3,5,7-tetrone
• CAS: 34072-51-0
• 化学式: C₂₀H₁₀N₄O₄
• 分子量: 370.324
• InChiKey: MGZBZNMCVZTMAP-UHFFFAOYSA-N

物化性质

• 沸点：
  679.9±65.0 °C(Predicted)
• 密度：
  1.606±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  28
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  101
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  [((CO)4Re)2(bibenzimidazolate)] 、 N,N'-双-(4-吡啶基)苯四甲酰亚胺 以 四氢呋喃 为溶剂， 以85%的产率得到((Re(CO)3)2-(BiBzIm)2-μ,μ'-(diPyBi)2*H2O
  参考文献：
  名称：

  Rhenium-Based Molecular Rectangles as Frameworks for Ligand-Centered Mixed Valency and Optical Electron Transfer

  摘要：

  A series of six neutral, tetrametallic, molecular rectangles has been synthesized that have the form ([Re(CO)(3)](2)BiBzlm)2-mu,mu'-(LL)(2), where BiBzlm is 2,2'-bisbenzimidazolate and LL is a reducible, dipyridyl or diazine ligand. X-ray crystallographic studies of the six show that the rectangle frameworks, as defined by the metal atoms, range in size from 5.7 Angstrom x 7.2 Angstrom to 5.7 Angstrom x 19.8 Angstrom. The singly reduced rectangles are members of an unusual category of mixed-valence compounds in which the ligands themselves are the redox centers and interligand electronic communication is controlled by direct ligand orbital overlap rather than by superexchange through the metal ions. Despite nominally identical coordination-defined ligand positioning, the spectrally determined electronic strengths, H-ab(2), vary by roughly 100-fold. As shown by X-ray crystallography and computational modeling, the observed differences largely reflect detailed geometric configurational differences that can either facilitate or frustrate productive direct orbital overlap.

  DOI：

  10.1021/ja0473182
• 作为产物：
  描述：

  4-氨基吡啶 、 均苯四甲酸二酐 以 N,N-二甲基甲酰胺 为溶剂， 生成 N,N'-双-(4-吡啶基)苯四甲酰亚胺
  参考文献：
  名称：

  晶体工程设计比色指示剂阵列以区分芳香族有机分子的位置异构体的方法

  摘要：

  判别由颜色：一个2D比色指示剂阵列已被设计由晶体工程方法（N⋅⋅⋅H 涉及固态共研磨为二羟基萘的位置异构体的视觉辨别O氢键键合和电荷转移络合）。通过单晶X射线分析确定控制π平面紧密堆积并因此决定复合物颜色的因素，从而可以通过晶体工程进行微调。

  DOI：

  10.1002/asia.200800341

文献信息

• ORGANIC PHOTOELECTRIC DEVICE AND IMAGE SENSOR
  申请人：Samsung Electronics Co., Ltd.

  公开号：US20170069690A1

  公开（公告）日：2017-03-09

  An organic photoelectric device includes a first electrode and a second electrode facing each other, and an active layer between the first electrode and the second electrode, wherein the active layer includes an n-type semiconductor compound that is transparent in a visible ray region and represented by Chemical Formula 1, and a p-type semiconductor compound having a maximum absorption wavelength in a wavelength region of about 500 nm to about 600 nm of a visible ray region.

  一种有机光电器件包括彼此对向的第一电极和第二电极，以及位于第一电极和第二电极之间的活性层，其中活性层包括透明于可见光区域的n型半导体化合物，其化学式为1，并且包括在可见光区域约500纳米至约600纳米波长范围内具有最大吸收波长的p型半导体化合物。
• Crystal Engineering Approach To Design Colorimetric Indicator Array To Discriminate Positional Isomers of Aromatic Organic Molecules
  作者：Darshak R. Trivedi、Yuzo Fujiki、Norifumi Fujita、Seiji Shinkai、Kazuki Sada

  DOI：10.1002/asia.200800341

  日期：2009.2.2

  Discriminating by color: A 2D colorimetric indicator array has been designed by a crystal engineering approach (N⋅⋅⋅HO hydrogen bonding and charge‐transfer complexation) involving solid‐state co‐grinding for the visual discrimination of positional isomers of dihydroxynaphthalene. Factors governing the close packing of π planes, and hence color of the complex, were determined by single‐crystal X‐ray analysis, allowing

  判别由颜色：一个2D比色指示剂阵列已被设计由晶体工程方法（N⋅⋅⋅H 涉及固态共研磨为二羟基萘的位置异构体的视觉辨别O氢键键合和电荷转移络合）。通过单晶X射线分析确定控制π平面紧密堆积并因此决定复合物颜色的因素，从而可以通过晶体工程进行微调。
• [EN] METAL-ORGANIC MATERIALS (MOMS) FOR ADSORPTION OF POLARIZABLE GASES AND METHODS OF USING MOMS<br/>[FR] MATÉRIAUX ORGANOMÉTALLIQUES (MOM) POUR L'ADSORPTION DE GAZ POLARISABLES ET LEURS PROCÉDÉS D'UTILISATION
  申请人：UNIV SOUTH FLORIDA

  公开号：WO2014074378A1

  公开（公告）日：2014-05-15

  Embodiments of the present disclosure provide for multi-component metal- organic materials (MOMs), systems including the MOM, systems for separating components in a gas, methods of separating polarizable gases from a gas mixture, and the like.

  本公开的实施例提供了多组分金属有机材料（MOMs），包括MOM的系统，用于分离气体中组分的系统，从气体混合物中分离极化气体的方法等。
• METAL COMPLEX AND ADSORBENT MATERIAL, STORAGE MATERIAL, AND SEPARATING MATERIAL COMPRISING SAME
  申请人：Kuraray Co., Ltd.

  公开号：EP2746248A1

  公开（公告）日：2014-06-25

  The problem of providing a metal complex having excellent gas adsorption performance, gas storage performance, and gas separation performance is solved by a metal complex comprising a dicarboxylic acid compound (I) including 20 to 99 mole % of a dicarboxylic acid compound (I-1) selected from terephthalic acid derivatives having an electron-donating group in the 2nd position such as 2-methoxyterephthalic acid, 2-methylterephthalic acid, and terephthalic acid, and 80 to 1 mole % of a dicarboxylic acid compound (I-2) selected from terephthalic acid derivatives having an electron-withdrawing group in the 2nd position such as 2-nitroterephthalic acid, 2-fluoroterephthalic acid, 2-chloroterephthalic acid, 2-bromoterephthalic acid, and 2-iodoterephthalic acid; at least one kind of metal ion selected from metal ions belonging to Group 2 and Groups 7 to 12 of the periodic table; and an organic ligand capable of bidentate binding to the metal ion.

  提供一种具有优异气体吸附性能、气体储存性能和气体分离性能的金属络合物的问题是通过一种金属络合物来解决的，该金属络合物包括二羧酸化合物（I），其中包括 20 至 99 摩尔％的二羧酸化合物（I-1），该二羧酸化合物选自在第 2 位具有电子供基的对苯二甲酸衍生物，如 2-甲氧基对苯二甲酸、80-1摩尔％的二羧酸化合物（I-2），该化合物选自在第 2 位上具有取电子基团的对苯二甲酸衍生物，如 2-硝基对苯二甲酸、2-氟对苯二甲酸、2-氯对苯二甲酸、2-溴对苯二甲酸和 2-碘对苯二甲酸；至少一种金属离子，选自元素周期表中第 2 族和第 7 至 12 族的金属离子；以及一种有机配体，能与金属离子双齿结合。
• METAL COMPLEX, AND ABSORBENT, OCCLUSION MATERIAL AND SEPARATION MATERIAL PRODUCED THEREFROM
  申请人：Kuraray Co., Ltd.

  公开号：EP2868649A1

  公开（公告）日：2015-05-06

  The metal complex comprises a multivalent carboxylic acid compound, at least one metal ion selected from ions of metals belonging to Groups 2 to 13 of the periodic table, an organic ligand capable of multidentate binding to the metal ion, and a C1 or C2 monocarboxylic acid compound. The metal complex has excellent gas adsorption, storage, and separation performance as well as excellent durability. The metal complex is stably present under high temperature and high humidity, and can maintain high adsorption performance.

  金属络合物由多价羧酸化合物、至少一种选自元素周期表第 2 至 13 族金属离子的金属离子、一种能与金属离子多价结合的有机配体以及一种 C1 或 C2 单羧酸化合物组成。金属络合物具有优异的气体吸附、储存和分离性能，以及出色的耐久性。金属络合物在高温高湿条件下也能稳定存在，并保持较高的吸附性能。