9,9,10,10-tetrachloro-9,10-dihydro-9,10-distannaanthracene | 710353-81-4

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 9,9,10,10-tetrachloro-9,10-dihydro-9,10-distannaanthracene
• CAS: 710353-81-4
• 化学式: C₁₂H₈Cl₄Sn₂
• 分子量: 531.428
• InChiKey: NZNPNWJGQFUPOC-UHFFFAOYSA-J

物化性质

• 熔点：
  285-288 °C (decomp)(Solvent: Chloroform ; Dichloromethane)

计算性质

• 辛醇/水分配系数(LogP)：
  -9.9
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  bis(o-bromophenyl)bis(p-methoxyphenyl)stannane 在 三氯化铝 t-BuLi 作用下， 以 四氢呋喃 、 甲苯 、 正戊烷 为溶剂， 生成 9,9,10,10-tetrachloro-9,10-dihydro-9,10-distannaanthracene
  参考文献：
  名称：

  Synthesis, Structures and Reactions of Novel 9,10‐Dihydro‐9,10‐distannaanthracenes

  摘要：

  AbstractA method for the synthesis of 9,10‐dihydro‐9,10‐distannaanthracenes has been improved and applied to the synthesis of novel unsymmetrical 9,10‐dihydro‐9,10‐distannaanthracenes. The first 9,9,10,10‐tetrahalo‐9,10‐dihydro‐9,10‐distannaanthracenes were successfully synthesized by halogenation of 9,9,10,10‐tetrakis(p‐methoxyphenyl)‐9,10‐dihydro‐9,10‐distannaanthracene. The structures of the newly obtained 9,10‐dihydro‐9,10‐distannaanthracenes were determined by X‐ray analysis. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

  DOI：

  10.1002/ejic.200300382

文献信息

• Synthesis, Structures and Reactions of Novel 9,10‐Dihydro‐9,10‐distannaanthracenes
  作者：Masaichi Saito、Natsumi Henzan、Minehiko Nitta、Michikazu Yoshioka

  DOI：10.1002/ejic.200300382

  日期：2004.2

  AbstractA method for the synthesis of 9,10‐dihydro‐9,10‐distannaanthracenes has been improved and applied to the synthesis of novel unsymmetrical 9,10‐dihydro‐9,10‐distannaanthracenes. The first 9,9,10,10‐tetrahalo‐9,10‐dihydro‐9,10‐distannaanthracenes were successfully synthesized by halogenation of 9,9,10,10‐tetrakis(p‐methoxyphenyl)‐9,10‐dihydro‐9,10‐distannaanthracene. The structures of the newly obtained 9,10‐dihydro‐9,10‐distannaanthracenes were determined by X‐ray analysis. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)