N'-dehydroabietoyl-salicylhydrazide | 1309654-88-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: N'-dehydroabietoyl-salicylhydrazide
• 英文别名: N-dehydroabietoylsalicylhydrazide
• CAS: 1309654-88-3
• 化学式: C₂₇H₃₄N₂O₃
• 分子量: 434.579
• InChiKey: QZCNXVBXRMNWSQ-XSBVVTFOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.99
• 重原子数：
  32.0
• 可旋转键数：
  3.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  78.43
• 氢给体数：
  3.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  甲醇 、 iron(III) chloride hexahydrate 、 N'-dehydroabietoyl-salicylhydrazide 以 甲醇 为溶剂， 以55%的产率得到poly[chloro(N-dehydroabietoylsalicylhydrazide(2-))(methanol)iron(III)] methanol solvate
  参考文献：
  名称：

  Synthesis, crystal structure and magnetic property of an iron(III) coordination polymer with N-acyl-salicylhydrazide ligand

  摘要：

  A one-dimensional coordination polymer of iron(III) with N-dehydroabietoyl-salicylhydrazide (H3L) ligand, [Fe (HL)Cl(CH3OH)](n)center dot nCH(3)OH (1), was synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, and infrared spectra analysis. The N-dehydroabietoyl-salicylhydrazide ligand in the compound is doubly deprotonated and acts as a tetradentate ligand to Fe(III) ions in tridentate-monodentate/back-to-back fashion, giving rise to a linear chain structure. The 1D chain is further extended to 2D supramolecular network by intermolecular hydrogen bonds. The magnetic study of the compound indicates an antiferromagnetic coupling interaction between Fe(III) ions. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.03.066
• 作为产物：
  描述：

  dehydroabietic acid chloride 、 水杨酰肼 在 三乙胺 作用下， 以 氯仿 为溶剂， 反应 24.5h， 以71%的产率得到N'-dehydroabietoyl-salicylhydrazide
  参考文献：
  名称：

  Synthesis, crystal structure and magnetic property of an iron(III) coordination polymer with N-acyl-salicylhydrazide ligand

  摘要：

  A one-dimensional coordination polymer of iron(III) with N-dehydroabietoyl-salicylhydrazide (H3L) ligand, [Fe (HL)Cl(CH3OH)](n)center dot nCH(3)OH (1), was synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, and infrared spectra analysis. The N-dehydroabietoyl-salicylhydrazide ligand in the compound is doubly deprotonated and acts as a tetradentate ligand to Fe(III) ions in tridentate-monodentate/back-to-back fashion, giving rise to a linear chain structure. The 1D chain is further extended to 2D supramolecular network by intermolecular hydrogen bonds. The magnetic study of the compound indicates an antiferromagnetic coupling interaction between Fe(III) ions. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.03.066