咪唑离子 | 17009-90-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 中文名称: 咪唑离子
• 英文名称: imidazolium ion
• 英文别名: 1H-imidazol-3-ium；Imidazoliumkation；imidazolium；imidazole cation；hydron;1H-imidazole
• CAS: 17009-90-4
• 化学式: C₃H₅N₂
• 分子量: 69.0861
• InChiKey: RAXXELZNTBOGNW-UHFFFAOYSA-O

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  29.9
• 氢给体数：
  2
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  咪唑离子 在 苯并咪唑 作用下， 生成 咪唑
  参考文献：
  名称：

  Catalan, Javier; Elguero, Jose; Flammang, Robert, Angewandte Chemie, 1983, vol. 95, # 4, p. 323 - 324

  摘要：

  DOI：
• 作为产物：
  描述：

  、 以 高氯酸 为溶剂， 生成 hexaquochromium(II) 、 咪唑离子
  参考文献：
  名称：

  Preparation of a series of (imidazole)pentaaquachromium(III) complexes and kinetics of their reduction by 1-hydroxy-1-methylethyl radicals

  摘要：

  A series of (imidazole) pentaaquachromium(III) complexes, (H2O)5Cr(Im-X,Y)3+ were prepared and characterized in acidic aqueous solution. These complexes are reduced by .C(CH3)2OH radicals with rate constants that vary with substituents on the imidazole ring. At 25-degrees-C the values of the rate constants, k/10(5) L mol-1 s-1 (X, Y), are 1.1 (1-CH3, H), 2.1 (2-CH3, H), 3.8 (4-CH3, H), 6.6 (H, H), 7.2 (4-CH3, 5-CONH2), and 16 (4-Cl, 5-Cl). A mechanism is proposed whereby the initial electron transfer takes place at coordinated imidazole, followed by a rapid intramolecular electron transfer to yield Cr(H2O)6(2+) and X,Y-ImH+.

  DOI：

  10.1021/ic00003a024
• 作为试剂：
  描述：

  苯佐卡因 、 1-chloro-2-oct-1-ynyl-5-trifluoromethylbenzene 在 palladium diacetate potassium phosphate 、 copper(l) iodide 、 咪唑离子 作用下， 以 甲苯 为溶剂， 以67%的产率得到1-(p-ethoxycarbonylphenyl)-2-n-hexyl-5-trifluoromethyl-1H-indole
  参考文献：
  名称：

  General and Efficient Indole Syntheses Based on Catalytic Amination Reactions

  摘要：

  Highly flexible and efficient syntheses of the indole backbone are presented starting from o-alkynylhaloarenes. These transformations proceed via a palladium- or a copper-catalyzed amination reaction and a subsequent cyclization reaction in good to excellent yields. Furthermore. a multicatalytic one-pot indole synthesis starting from o-chloroiodobenzene is viable using a single catalyst consisting of an N-heterocyclic carbene palladium complex and Cul.

  DOI：

  10.1021/ol047649j

文献信息

• Novel materials for use as electrolytic solutes
  申请人：——

  公开号：US20020009635A1

  公开（公告）日：2002-01-24

  The invention relates to ionic compositions having a high ionic conductivity comprising a salt with a delocalized anionic charge. An ionic composition comprises a salt in solution in a solvent and has a conductivity of greater than 10 −5 S.cm −1 between −30° C. and 150° C. The cation is a proton, a hydronium, a hydroxonium, a nitrosonium NO + , an ammonium NH 4 + or a metal, organic or organometallic cation. The anion is a carbanion carrying a perfluorinated substituent or a substituent carrying at least one F on the carbon &agr; to the carbanion and two nonperfluorinated electron-withdrawing substituents. Use as electrolyte in electrochemical devices, as catalyst of chemical reactions, or as photochemical or thermochemical initiator for polymerization or crosslinking reactions.

  本发明涉及具有高离子导电性的离子组成物，包括具有去定域阴离子电荷的盐。离子组成物包括在溶剂中溶解的盐，并且在-30°C至150°C之间具有大于10^-5S.cm^-1的电导率。阳离子可以是质子、氢氧根离子、水合氢离子、亚硝基离子NO+、铵离子NH4+或金属、有机或有机金属阳离子。阴离子是携带有全氟取代基的碳负离子或携带至少一个F的取代基的碳α到碳负离子和两个非全氟电子吸引取代基的取代基。可用作电化学装置的电解质、化学反应的催化剂，或用作光化学或热化学引发剂，用于聚合或交联反应。
• Scale removal
  申请人：——

  公开号：US20020055439A1

  公开（公告）日：2002-05-09

  A method for treating a wellbore (or well casing) and the contiguous wellbore area to remove scale (mineral deposits comprised of, e.g., BaSO4, CaCO3, etc.) in the context of hydrocarbon recovery and other applications is disclosed, said method including contacting the scale with a fluid comprised of an ionic liquid or liquids.

  本发明涉及一种用于处理井孔（或井套管）及其相邻井孔区域以去除水垢（由 BaSO4、CaCO3 等矿物沉积物组成）的方法，适用于烃类回收和其他应用，所述方法包括将含有离子液体或液体的流体与水垢接触。
• Mixtures of ionic liquids with lewis acids
  申请人：Wasserscheid Peter

  公开号：US20060264642A1

  公开（公告）日：2006-11-23

  Ionic liquids comprising a mixture of one or more triflate or bis(trifluoromethylsulfonyl)imide salt(s) with one or more Lewis acids(s), wherein the total of the molar contents of the Lewis acid(s) in the mixture is from about 0.01 - 98 %, are provided, that are useful as catalysts in Lewis acid catalyzed reactions.

  提供一种离子液体，其包括一种或多种三氟甲烷磺酰亚胺盐或双(三氟甲基磺酰)亚胺盐与一种或多种路易斯酸的混合物，其中混合物中路易斯酸的摩尔含量总计约为0.01-98％，这种离子液体可用作路易斯酸催化反应中的催化剂。
• Materials for use as electrolytic solutes
  申请人：ACEP Inc.

  公开号：US06620546B1

  公开（公告）日：2003-09-16

  The invention relates to ionic compositions having a high ionic conductivity comprising a salt with a delocalized anionic charge. An ionic composition comprises a salt in solution in a solvent and has a conductivity of greater than 10−5 S.cm−1 between −30° C. and 150° C. The cation is a proton, a hydronium, a hydroxonium, a nitrosonium NO+, an ammonium NH4+ or a metal, organic or organometallic cation. The anion is a carbanion carrying a perfluorinated substituent or a substituent carrying at least one F on the carbon &agr; to the carbanion and two nonperfluorinated electron-withdrawing substituents. Use as electrolyte in electrochemical devices, as catalyst of chemical reactions, or as photochemical or thermochemical initiator for polymerization or crosslinking reactions.

  本发明涉及具有高离子导电性的离子组成物，其包括具有离域阴离子电荷的盐。一种离子组成物包括在溶剂中溶解的盐，并且在-30℃至150℃之间具有大于10-5 S.cm-1的导电度。阳离子可以是质子、氢氧根离子、羟基氢根离子、亚硝酰阳离子NO+、铵离子NH4+或金属、有机或有机金属阳离子。阴离子是带有全氟取代基的碳负离子或带有至少一个F的取代基的碳a到碳负离子和两个非全氟电子吸引取代基。用作电化学装置的电解质、化学反应的催化剂，或作为光化学或热化学引发剂用于聚合或交联反应。
• Fluids and techniques for matrix acidizing
  申请人：Schlumberger Technology Corporation

  公开号：US06350721B1

  公开（公告）日：2002-02-26

  Liquids comprised solely of anions and cations (“ionic liquids”) are disclosed as novel components of fluids (and techniques relying upon those fluids) for stimulation of hydrocarbon wells. In particular, the fluids disclosed are useful in matrix acidizing. Formation of the ionic liquids of the present Invention is highly exothermic, hence the heat generated can be used, for instance, to melt de-watered drilling fluid in the near-wellbore region of the formation. Further, reaction of the ionic liquids with water results in acid generation; this acid can be used to, for instance, to stimulate a formation, either by conventional matrix acidizing or fracture acidizing. In addition, certain preferred species of the ionic liquids of the present Invention are highly stable solvents, hence they can be used as carrier fluids for highly reactive super acids (e.g., SbF5+HF) in connection with matrix acidizing.

  本发明揭示了仅由阴离子和阳离子组成的液体（“离子液体”）作为刺激烃类井的流体（以及依赖这些流体的技术）的新组分。特别是，所揭示的流体在基质酸化中非常有用。本发明的离子液体的形成是高度放热的，因此生成的热量可以用于在地层井口附近熔化除水钻井液。此外，离子液体与水的反应会产生酸；这种酸可以用于刺激地层，无论是通过传统的基质酸化还是裂缝酸化。此外，本发明的某些优选离子液体物种是高度稳定的溶剂，因此它们可以作为高反应性超级酸（例如SbF5+HF）的载体流体，用于基质酸化。