N,N-二乙基-4-(2-喹啉-4-基乙烯基)苯胺 | 5397-61-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 中文名称: N,N-二乙基-4-(2-喹啉-4-基乙烯基)苯胺
• 英文名称: N,N-diethyl-4-(2-quinolin-4-yl-vinyl)-aniline
• 英文别名: N,N-diethyl-4-(trans-2-[4]quinolyl-vinyl)-aniline；N,N-Diaethyl-4-(trans-2-[4]chinolyl-vinyl)-anilin；4-(4-Dimethylamino-styryl)-chinolin；4-(4-Diethylamino-styryl)-chinolin；Quinoline, 4-(p-diethylaminostyryl)-；N,N-diethyl-4-[(E)-2-quinolin-4-ylethenyl]aniline
• CAS: 5397-61-5
• 化学式: C₂₁H₂₂N₂
• 分子量: 302.419
• InChiKey: RHVPFAMWEKAIHJ-FMIVXFBMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  16.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-甲基喹啉 、 N,N-二乙基-4-氨基苯甲醛 在 zinc(II) chloride 作用下， 生成 N,N-二乙基-4-(2-喹啉-4-基乙烯基)苯胺
  参考文献：
  名称：

  喹啉系列研究；4-苯乙烯基喹啉的一些衍生物。

  摘要：

  DOI：

  10.1021/ja01211a072

文献信息

• Highly stable resin, hardenable resin composition, production method therefor, color filter and liquid crystal panel
  申请人：DAI NIPPON PRINTING CO., LTD.

  公开号：EP1076070A2

  公开（公告）日：2001-02-14

  The present invention is to prevent the rapid viscosity rise generated at the time of dissolving or dispersing in a solvent a polymer obtained by reacting a material polymer having an acidic functional group and a hydroxyl group in the principal chain part with an isocyanate compound, in particular, a photo-curing polymer obtained by reaction with a radical polymerizable group-containing isocyanate compound. A highly stable polymer can be obtained by reacting a material polymer having a principal chain including at least a component unit having an acidic functional group and a component unit having a hydroxyl group with an isocyanate compound, and further reacting the same with an alcohol. Moreover, by producing a material polymer using a non-nitrile azo-based or peroxide-based polymerization initiator and/or introducing an isocyanate compound using a polymerization inhibitor selected from the compounds represented by the above-mentioned formulae (10) and (16), the transparency can be improved. A photo-curing polymer obtained in the present invention is suited for forming a protection film of a color filter and a column-like spacer of a liquid crystal panel.

  本发明的目的是防止在溶剂中溶解或分散通过使主链部分具有酸性官能团和羟基的材料聚合物与异氰酸酯化合物反应而得到的聚合物，特别是通过与含自由基可聚合基团的异氰酸酯化合物反应而得到的光固化聚合物时产生的快速粘度上升。将一种主链至少包括一个具有酸性官能团的组成单元和一个具有羟基的组成单元的材料聚合物与异氰酸酯化合物反应，并进一步与醇反应，可以得到一种高度稳定的聚合物。此外，通过使用非腈偶氮基或过氧化物基聚合引发剂和/或使用从上述式（10）和（16）所代表的化合物中选出的聚合抑制剂引入异氰酸酯化合物来生产材料聚合物，可以提高透明度。本发明获得的光固化聚合物适用于形成彩色滤光片的保护膜和液晶面板的柱状间隔。
• Curable resin composition, photosensitive pattern-forming curable resin composition,color filter, substrate for liquid crystalline panel, and liquid crystalline panel
  申请人：Hayashi Shinji

  公开号：US20060229376A1

  公开（公告）日：2006-10-12

  There are provided: a curable resin composition having a high exposure sensitivity and a good developing property, and thereby capable of forming an accurate and precise pattern; a liquid crystal panel substrate on which a protective film for covering a color layer or spacers for a liquid crystal layer, by using the curable resin composition, hardly causing a color irregularity and contrast irregularity; and a liquid crystal panel using the liquid crystal panel substrate and having a superior display quality. The curable resin composition of the present invention comprises: a copolymer (a) having a molecular structure in which a constitutional unit including an acidic functional unit and a constitutional unit including a photocurable functional group are linked at least; a photopolymnerization initiator (b) having a tertiary amine structure; and a photocurable compound (c) having at least one acidic functional group and at least three photocurable functional groups.

  本发明提供了：一种可固化树脂组合物，它具有高曝光灵敏度和良好的显影性，从而能够形成准确和精确的图案；一种液晶面板基板，在该基板上使用该可固化树脂组合物，可在其上覆盖用于液晶层的颜色层或间隔层的保护膜，几乎不会造成颜色不规则和对比度不规则；以及一种使用该液晶面板基板的液晶面板，它具有优异的显示质量。本发明的可固化树脂组合物包括：共聚物 (a)，其分子结构中至少连接了包括酸性官能团的构型单元和包括光固化官能团的构型单元；具有叔胺结构的光聚合引发剂 (b)；以及具有至少一个酸性官能团和至少三个光固化官能团的光固化化合物 (c)。
• Notes- 4-(4-Aminostyryl)quinolines
  作者：Carl Bahner、Clarence Cook、John Dale、John Fain、Fred Hannan、Patricia Smith、Joan Wilson

  DOI：10.1021/jo01101a610

  日期：1958.7
• HIGH PHOTO-SENSITIVITY CURABLE RESIN, PHOTO-CURABLE RESIN COMPOSITION, PRODUCTION METHOD THEREOF, COLOR FILTER AND LIQUID CRYSTAL DISPLAY PANEL
  申请人：DAI NIPPON PRINTING CO., LTD.

  公开号：EP1141063A1

  公开（公告）日：2001-10-10
• US4987056A
  申请人：——

  公开号：US4987056A

  公开（公告）日：1991-01-22